Air Separation toAir Separation to Applications · Who is Air Products? zGlobal atmospheric,...

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Air Separation to Air Separation to Applications Steve Baron Advanced Technology Cryogenic Applications, Basingstoke UK 28 September 2011

Transcript of Air Separation toAir Separation to Applications · Who is Air Products? zGlobal atmospheric,...

Air Separation toAir Separation to Applications

Steve Baron – Advanced Technology Cryogenic Applications, Basingstoke UK28 September 2011

Who Who is is Air Products?Air Products?Who Who is is Air Products?Air Products?Global atmospheric, process andspecialty gases performance materialsspecialty gases, performance materials,equipment and services providerServing industrial, energy, technology and healthcare markets worldwideOperations in over 40 countries~19,000 employees worldwideWorld HQ in Allentown, PA, USA.

European HQ in Hersham Surrey– European HQ in Hersham, Surrey– Asia HQ in Shanghai

$9 billion company in FY10

Air Products Public Information2

$9 billion company in FY10– Diverse markets and geographies

Modes of Supply Modes of Supply Modes of Supply Modes of Supply Gases can be supplied in three main waysmain ways– Cylinders– Bulk gases (transported as

C i Li id)Cryogenic Liquid)– On Site generation

MembranesAir Separation Units (ASU)

Air Products Public Information3

Cryogenics at Air ProductsCryogenics at Air ProductsCryogenics at Air ProductsCryogenics at Air Products

0oC Water Freezes

-18oC (0oF)

HouseholdRefrigeration> -12oC

Low TemperatureRefrigeration< -40oC

-78oC CO2 Sublimation (Dry Ice)

-42oC Liquid propane

Cryogenics< -100oC

2

-196oC N2 Boils-183oC O2 Boils

< -100 C 196 C N2 Boils

-273oC Absolute Zero-269oC He Boils

Air Products Public Information

Air Separation Air Separation –– How is it done?How is it done?Air Separation Air Separation –– How is it done?How is it done?

1 Air Feed2 Cleaning3 Compressing4 Cooling5 Separation6 Crude argon7 Vaporizer8 Gas Filling9 Liquid Filling10 Pipeline Supply

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Air Separation Air Separation –– How is it done?How is it done?Air Separation Air Separation –– How is it done?How is it done?

LP (c. 1 bara)

Ar

78% N2LNLOX ( 183°C)21% O2

1 % ArPlus H2OCO2 etc

LN2 LOX (-183°C)

CO2 etc

HP (5 -7 bara)

Air (c. -175°C)

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( )Crude LOX (c. 40%)

Cryogenic y gApplications –Liquid Nitrogenq g

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Cryogenic Cryogenic ApplicationsApplicationsApplicationsApplications

Cryogenic Applications R&D Facilities:– Laboratories in Basingstoke (UK)Laboratories in Basingstoke (UK),

Allentown (USA) and Bangkok (Thailand)– Analytical capabilities– Customer demonstrations– Development of processes and

equipment – Ideal for testing new products, processes

d t h l iand technologiesExperienced R&D team :– App. 140 years of combined R&D

iexperience– Frequent experience exchange and

training from research to prod ct de elopment from research to prod ct de elopment

Air Products Public Information

. . . from research to product development. . . from research to product developmentand implementation in the market placeand implementation in the market place

Typical Cryogenic Tunnel Typical Cryogenic Tunnel FreezerFreezerFreezerFreezer

LNLN22ExhaustExhaust

FanFan T b l FT b l F 22FanFan Turbulence FansTurbulence Fans

INFEEDINFEED OUTFEEDOUTFEED

Air Products Public Information

Food Processing Food Processing –– Cryogenic Cryogenic AdvantagesAdvantagesAdvantagesAdvantages

Size of iceSize of ice crystal

Freezing speed

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Other Cryogenic AdvantagesOther Cryogenic AdvantagesOther Cryogenic AdvantagesOther Cryogenic AdvantagesCryogenic rapid freezing helps to produceto produce– Individually Quick Frozen

(IQF) products– Pellets– Coated or enrobed products

Formed products (e g– Formed products (e.g. patties)

Air Products Public Information

Industrial CryogenicsIndustrial CryogenicsIndustrial CryogenicsIndustrial CryogenicsUltra-fine Grinding

Rubber and plasticsParticle sizes from 50 to 300 μmCryogenic temperatures to cause embrittlement

Air Products Public Information

Industrial CryogenicsIndustrial CryogenicsIndustrial CryogenicsIndustrial CryogenicsSolvent Recovery

Cryogenic Condensation of Volatile Organic Compounds (VOCs) to meet stringent emission standardsstandards

160

180

200

Dichloromethane

80

100

120

140

mis

sion

s (p

pm)

Freeze Point

0

20

40

60

-140 -130 -120 -110 -100 -90 -80

Em Freeze Point

Air Products Public Information

-140 -130 -120 -110 -100 -90 -80

Temperature (°C)

Other ApplicationsOther ApplicationsOther ApplicationsOther ApplicationsProcess CoolingD fl hiDe-flashingFridge recyclingReaction CoolinggHigh Temperature Superconductivity (67 to 90K)

Air Products Public Information

Thank you

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