Air Emissions Calculations EMISSIONS - Proposed Pipeline and Facility Emissions Equipment Category...

14
ERG Operating Company Foxen Petroleum Pipeline Volume 2: Appendices September 2014 Appendix 4 Air Quality Air Emissions Calculations

Transcript of Air Emissions Calculations EMISSIONS - Proposed Pipeline and Facility Emissions Equipment Category...

ERG Operating Company Foxen Petroleum Pipeline Volume 2: Appendices September 2014

Appendix 4

Air Quality

Air Emissions Calculations

FOXEN PETROLEUM PIPELINE PROJECT - ATC 14067 June 2013

OPERATIONAL EMISSIONS - Proposed Pipeline and Facility Emissions

Equipment Category Capacity ea. NOX ROC CO SOX PM10

Sales Oil Tanks (2) 10,000 BBL

lbs/day 10.38

tons/year 1.90

Reject Tank 3,000 BBL

lbs/day 0.75

tons/year 0.14

LCO Tank - Contingency Use 3,000 BBL

lbs/day 2400 BBL/day 3.64

tons/year 20 days/year 0.66

Pigging Operations

lbs/day 2 per day max 1.34

tons/year 4 per year max 0.001

Fugitive Component Emissions

lbs/day 8.63

tons/year 1.57

TOTAL

lbs/day 0.00 24.74 0.00 0.00 0.00

tons/year 0.00 4.276 0.00 0.00 0.00

Page 1 of 1

FOXEN PETROLEUM PIPELINE PROJECT

Gas Release Volume from Pigging Operation

Length (in) Length (ft) Diameter (in) Diameter (ft) Radius (ft) Volume (ft3)

391.2 32.6 12.75 1.0625 0.53125 28.904 pig receiver

TOTAL 28.904 per pigging event

Density of TOC in Vessel density = P x MW / R x T

Pressure (psig + 14.7 psi), Depressurize Launch to 5 psig 19.700 psig

Molecular Weight Gas 23.000 lb/lb-mole

R Universal Gas Constant 10.730

Temperature 560.000 R

Calculated Density 0.075 lb/ft3

ROC per Cubic Foot of Volume

ROC = density x 0.308 0.023

ROC Emissions from Pigging Events

lb ROC/ft3 = 0.02322507

Lb ROC Emissions per day 0.67 lb/day

TOTAL ROC Emissions from Pigging Events

Assume a pigging operation occurs in one day 1 0.67 lbs/day

Assume one pigging operation per year 1 0.000335654 tons/year

Page 1 of 12

FIXED ROOF TANK CALCULATION (AP-42: Chapter 7 Method)

10,000 BBL Sales Oil Tanks

Basic Input Data Attachment: A-1

Permit: Foxen Pipeline

liquid {1:G13, 2:G10, 3:G7, 4:C, 5:JP, 6:ker, 7:O2, 8:O6} = 4 Date: 08/30/12

liquid TVP = 3.9 lab data Tank: T-1

if TVP is entered, enter TVP temperature (°F) = 192 lab data Name: name

tank heated {yes, no} = yes Filename:

if tank is heated, enter temp (°F) = 180 Distrcit: Santa Barbara

vapor recovery system present? {yes, no} = yes Version: Tank-2b.xls

is this a wash tank? {yes, no} = no

will flashing losses occur in this tank? {yes, no} = no

breather vent pressure setting range (psi) (def = 0.06): 0.06

Tank Data

diameter (feet) = 55

capacity (enter barrels in first col, gals will compute) = 10,000 420,000

conical or dome roof? {c, d} = c

shell height (feet) = 24

roof height (def = 1): 1

ave liq height (feet): 12 Paint Factor Matrix Molecular Weight Matrix

color {1:Spec Al, 2:Diff Al, 3:Lite, 4:Med, 5:Rd, 6:Wh} = 4 paint condition liquid mol wt

condition {1: Good, 2: Poor} = 1 paint color good poor gas rvp 13 62

upstream pressure (psig) (def = 0 when no flashing occurs): 0 spec alum 0.39 0.49 gas rvp 10 66

diff alum 0.60 0.68 gas rvp 7 68

Liquid Data lite grey 0.54 0.63 crude oil 50

A B med grey 0.68 0.74 JP -4 80

maximum daily throughput (bopd) = 12,500 red 0.89 0.91 jet kerosene 130

Ann thruput (gal): (enter value in Column A if not max PTE) 1.916E+08 white 0.17 0.34 fuel oil 2 130

RVP (psia): 0.69822 fuel oil 6 190

°API gravity = 18

Computed Values

roof outage 1 (feet): 0.3

vapor space volume 2 (cubic feet): 29,223

turnovers 3 : 456.25

turnover factor 4 : 0.23

paint factor 5 : 0.68 Adjusted TVP Matrix RVP Matrix

surface temperatures (°R, °F) liquid TVP value liquid RVP value

average 6 : 640 180 gas rvp 13 23.7 gas rvp 13 13

maximum 7 : 641.25 181.25 gas rvp 10 11.2 gas rvp 10 10

minimum 8 : 638.75 178.75 gas rvp 7 10.7 gas rvp 7 7

product factor 9 : 0.75 crude oil 3.12554 crude oil 0.6982194

diurnal vapor ranges JP -4 4.9 JP -4 2.7

temperature 10

(fahrenheit degrees): 5 jet kerosene 0.0385 jet kerosene 0.029

vapor pressure 11 (psia): 0.146849 fuel oil 2 0.0422 fuel oil 2 0.022

molecular weight 12 (lb/lb-mol): 50 fuel oil 6 0.00016 fuel oil 6 0.00019

TVP 13 (psia) [adjusted for ave liquid surface temp]: 3.12554

vapor density 14 (lb/cubic foot): 0.022755

vapor expansion factor 15 : 0.015 Long-Term

vapor saturation factor 16 : 0.329214 VRU_Eff = 99.00%

vented vapor volume (scf/bbl): 8

fraction ROG - flashing losses: 0.308 Short-Term

fraction ROG - evaporative losses: 0.885 VRU_Eff = 99.00%

Emissions Uncontrolled ROC emissions Controlled ROC emissionslb/hr lb/day ton/year lb/hr lb/day ton/year

breathing loss 17 = 0.12 2.91 0.53 0.00 0.03 0.01

working loss 18 = 12.43 298.22 54.43 0.12 2.98 0.54

flashing loss 19 = 0.00 0.00 0.00 0.00 0.00 0.00

TOTALS = 12.55 301.13 54.96 0.13 3.01 0.55

25.1 602.26 109.92 0.26 6.02 1.1

NOTES: see attachment for explanation of notes (1 through 19)

For Two (2) 10,000 BBL Tanks

Page 2 of 12

FIXED ROOF TANK CALCULATION (AP-42: Chapter 7 Method)

3000 BBL Reject Tank

Basic Input Data Attachment: A-1

Permit: Foxen Pipeline

liquid {1:G13, 2:G10, 3:G7, 4:C, 5:JP, 6:ker, 7:O2, 8:O6} = 4 Date: 08/30/12

liquid TVP = 3.9 Tank: T-1

if TVP is entered, enter TVP temperature (°F) = 192 Name: name

tank heated {yes, no} = yes Filename:

if tank is heated, enter temp (°F) = 180 Distrcit: Santa Barbara

vapor recovery system present? {yes, no} = yes Version: Tank-2b.xls

is this a wash tank? {yes, no} = no

will flashing losses occur in this tank? {yes, no} = no

breather vent pressure setting range (psi) (def = 0.06): 0.06

Tank Data

diameter (feet) = 30

capacity (enter barrels in first col, gals will compute) = 3,000 126,000

conical or dome roof? {c, d} = c

shell height (feet) = 24

roof height (def = 1): 1

ave liq height (feet): 12 Paint Factor Matrix Molecular Weight Matrix

color {1:Spec Al, 2:Diff Al, 3:Lite, 4:Med, 5:Rd, 6:Wh} = 4 paint condition liquid mol wt

condition {1: Good, 2: Poor} = 1 paint color good poor gas rvp 13 62

upstream pressure (psig) (def = 0 when no flashing occurs): 0 spec alum 0.39 0.49 gas rvp 10 66

diff alum 0.60 0.68 gas rvp 7 68

Liquid Data lite grey 0.54 0.63 crude oil 50

A B med grey 0.68 0.74 JP -4 80

maximum daily throughput (bopd) = 1,000 red 0.89 0.91 jet kerosene 130

Ann thruput (gal): (enter value in Column A if not max PTE) 1.533E+07 white 0.17 0.34 fuel oil 2 130

RVP (psia): 0.69822 fuel oil 6 190

°API gravity = 18

Computed Values

roof outage 1 (feet): 0.3

vapor space volume 2 (cubic feet): 8,694

turnovers 3 : 121.67

turnover factor 4 : 0.41

paint factor 5 : 0.68 Adjusted TVP Matrix RVP Matrix

surface temperatures (°R, °F) liquid TVP value liquid RVP value

average 6 : 640 180 gas rvp 13 23.7 gas rvp 13 13

maximum 7 : 641.25 181.25 gas rvp 10 11.2 gas rvp 10 10

minimum 8 : 638.75 178.75 gas rvp 7 10.7 gas rvp 7 7

product factor 9 : 0.75 crude oil 3.12554 crude oil 0.6982194

diurnal vapor ranges JP -4 4.9 JP -4 2.7

temperature 10 (fahrenheit degrees): 5 jet kerosene 0.0385 jet kerosene 0.029

vapor pressure 11 (psia): 0.146849 fuel oil 2 0.0422 fuel oil 2 0.022

molecular weight 12

(lb/lb-mol): 50 fuel oil 6 0.00016 fuel oil 6 0.00019

TVP 13 (psia) [adjusted for ave liquid surface temp]: 3.12554

vapor density 14 (lb/cubic foot): 0.022755

vapor expansion factor 15 : 0.015 Long-Term

vapor saturation factor 16 : 0.329214 VRU_Eff = 99.00%

vented vapor volume (scf/bbl): 8

fraction ROG - flashing losses: 0.308 Short-Term

fraction ROG - evaporative losses: 0.885 VRU_Eff = 99.00%

Emissions Uncontrolled ROC emissions Controlled ROC emissionslb/hr lb/day ton/year lb/hr lb/day ton/year

breathing loss 17 = 0.04 0.86 0.16 0.00 0.01 0.00

working loss 18 = 1.77 42.53 7.76 0.02 0.43 0.08

flashing loss 19 = 0.00 0.00 0.00 0.00 0.00 0.00

TOTALS = 1.81 43.39 7.92 0.02 0.43 0.08

Page 3 of 12

FIXED ROOF TANK CALCULATION (AP-42: Chapter 7 Method)

10,000 BBL Emergency Storage Oil Tanks

Basic Input Data Attachment: A-1

Permit: Foxen Pipeline

liquid {1:G13, 2:G10, 3:G7, 4:C, 5:JP, 6:ker, 7:O2, 8:O6} = 4 Date: 08/30/12

liquid TVP = 3.9 lab data Tank: T-1

if TVP is entered, enter TVP temperature (°F) = 192 lab data Name: name

tank heated {yes, no} = yes Filename:

if tank is heated, enter temp (°F) = 180 Distrcit: Santa Barbara

vapor recovery system present? {yes, no} = yes Version: Tank-2b.xls

is this a wash tank? {yes, no} = no

will flashing losses occur in this tank? {yes, no} = no

breather vent pressure setting range (psi) (def = 0.06): 0.06

Tank Data

diameter (feet) = 55

capacity (enter barrels in first col, gals will compute) = 10,000 420,000

conical or dome roof? {c, d} = c

shell height (feet) = 24

roof height (def = 1): 1

ave liq height (feet): 12 Paint Factor Matrix Molecular Weight Matrix

color {1:Spec Al, 2:Diff Al, 3:Lite, 4:Med, 5:Rd, 6:Wh} = 4 paint condition liquid mol wt

condition {1: Good, 2: Poor} = 1 paint color good poor gas rvp 13 62

upstream pressure (psig) (def = 0 when no flashing occurs): 0 spec alum 0.39 0.49 gas rvp 10 66

diff alum 0.60 0.68 gas rvp 7 68

Liquid Data lite grey 0.54 0.63 crude oil 50

A B med grey 0.68 0.74 JP -4 80

maximum daily throughput (bopd) = 3,333.33 red 0.89 0.91 jet kerosene 130

Ann thruput (gal): (enter value in Column A if not max PTE) 5.110E+07 white 0.17 0.34 fuel oil 2 130

RVP (psia): 0.69822 fuel oil 6 190

°API gravity = 18

Computed Values

roof outage 1 (feet): 0.3

vapor space volume 2 (cubic feet): 29,223

turnovers 3 : 121.67

turnover factor 4 : 0.41

paint factor 5 : 0.68 Adjusted TVP Matrix RVP Matrix

surface temperatures (°R, °F) liquid TVP value liquid RVP value

average 6 : 640 180 gas rvp 13 23.7 gas rvp 13 13

maximum 7 : 641.25 181.25 gas rvp 10 11.2 gas rvp 10 10

minimum 8 : 638.75 178.75 gas rvp 7 10.7 gas rvp 7 7

product factor 9 : 0.75 crude oil 3.12554 crude oil 0.6982194

diurnal vapor ranges JP -4 4.9 JP -4 2.7

temperature 10

(fahrenheit degrees): 5 jet kerosene 0.0385 jet kerosene 0.029

vapor pressure 11 (psia): 0.146849 fuel oil 2 0.0422 fuel oil 2 0.022

molecular weight 12 (lb/lb-mol): 50 fuel oil 6 0.00016 fuel oil 6 0.00019

TVP 13 (psia) [adjusted for ave liquid surface temp]: 3.12554

vapor density 14 (lb/cubic foot): 0.022755

vapor expansion factor 15 : 0.015 Long-Term

vapor saturation factor 16 : 0.329214 VRU_Eff = 99.00%

vented vapor volume (scf/bbl): 8

fraction ROG - flashing losses: 0.308 Short-Term

fraction ROG - evaporative losses: 0.885 VRU_Eff = 99.00%

Emissions Uncontrolled ROC emissions Controlled ROC emissionslb/hr lb/day ton/year lb/hr lb/day ton/year

breathing loss 17 = 0.12 2.91 0.53 0.00 0.03 0.01

working loss 18 = 5.91 141.76 25.87 0.06 1.42 0.26

flashing loss 19 = 0.00 0.00 0.00 0.00 0.00 0.00

TOTALS = 6.03 144.67 26.40 0.06 1.45 0.26

12.06 289.34 52.8 0.12 2.9 0.52For Two (2) 10,000 BBL Tanks

Page 4 of 12

FOXEN PETROLEUM PIPELINE PROJECT

Date: 06/14/12

HEATER CALCULATION WORKSHEET (ver. 6.0)

DATA

Permit No. ........................................................

Owner/Operator ..............................................ERG Operating Company

Facility/Lease .........................................................

Boiler Type ...................................................... NA

Boiler Mfg. ..................................................... NA

Boiler Model No. ................................................. NA

Boiler Serial/ID No. ............................................... NA

Boiler Horsepower ............................................no data Bhp

Burner Type .................................................. Gas

Burner Mfg. ................................................... Ame

Burner Model No. ................................................23ew

Max. Firing Rate of Burner .....................................5.000 MMBtu/hr

Max. Annual Heat Input ......................................43,800.000 MMBtu/yr

Daily Operating schedule .................................... 24 hrs/day

Yearly Load factor (%) .......................................... 100 %

Fuel Type ...........................................................Produced gas

High Heating Value ......................................... 1,050 Btu/scf

Sulfur Content of Fuel .................................... 80.00 ppmvd as H2S

Nitrogen Content of Fuel ........................................ - wt. % N

Boiler Classification ........................................Industrial

Firing Type ............................................ Other Type

PM Emission Factor ...........................................0.0075 lb/MMBtu

PM10 Emission Factor ...........................................0.0075 lb/MMBtu

NOx Emission Factor ...................................... 0.0360 lb/MMBtu

SOx Emission Factor ..................................... 0.0137 lb/MMBtu

CO Emission Factor ............................................0.2970 lb/MMBtu

ROC Emission Factor .................................. 0.0054 lb/MMBtu

RESULTS lb/hr lb/day TPY

Nitrogen Oxides (as NO2) ......................................0.18 4.3 0.79

Sulfur Oxides (as SO2) ........................................0.07 1.6 0.30

PM10 .....................................................................0.04 0.9 0.16

Total Suspended Particulate (PM) ..................................0.04 0.9 0.16

Carbon Monoxide ...............................................1.49 35.6 6.50

Reactive Organic Compounds (ROC) ..............................0.03 0.6 0.12

Page 5 of 12

FOXEN PETROLEUM PIPELINE PROJECT

Heater GHG Emission Calculations

Heater Parameters - Primary and Back Up GHG Emission Factors

Rated Capacity 5 MMBtu/hr 53.02 kg CO2/MMBtu

Load Factor 100 % 0.0009 kg CH4/MMBtu

CO2 Emissions 584.55 lbs/hr 0.0001 kg N₂O/MMBtu

14,029.08 lbs/day Emission Calculation Assumptions

2,560.31 tons/year 2.205 lbs/kg

2,322.27 metric tonnes/year 116.909 lbs in 53.02 kg

24 hours/day

Total GHG Emissions 365 days/year

14,029.08 lbs/day 2,205 lbs/metric tonne

2,322.27 MT/year 2,000 lbs/US short ton

0.238 lbs/day

0.0394 MT/year

0.026 lbs/day

0.0044 MT/year

Notes:

CO2 EF Source AB32: Appendix A, Table 4

CH4 EF Source AB32: App. A Table 6

Table: "Default Carbon Content, Heat Content, and Carbon Dioxide Emission Factors from

Stationary Combustion by Fuel Type"

(unspecified weighted US avergae Natural Gas Higher Heating Value)

CO2

CH4

N2O

Page 6 of 12

FUGITIVE ROC EMISSIONS CALCULATION

ADMINISTRATIVE INFORMATION

Enhanced Fugitive I&M Program

Company: ERB

Facility: Foxen Petroleum Pipeline

Processed by: LMN

Date: 8/20/2012

Facility Type: (Choose one)

Production Field x

Gas Processing Plant ROC(2)

Uncontrolled Controlled Controlled Controlled Controlled

Refinery Emission ROC/THC ROC ROC ROC ROC ROC ROC

Offshore Platform Factor Ratio Emission Control Emission Emission Emission Emission

Component Count(1)

(lbs/day-clp) (lbs/day) Eff (lbs/hr) (lbs/day) (Tons/Qtr) (Tons/year)

Gas Condensate Service

Valves - Acc/Inacc 4 0.295 0.31 0.37 0.92 0.00 0.03 0.00 0.01

Valves - Bellows 0.295 0.31 0.00 1.00 0.00 0.00 0.00 0.00

Valves - Unsafe 0.295 0.31 0.00 0.00 0.00 0.00 0.00 0.00

Valves - Low Emitting 0.295 0.31 0.00 0.00 0.00 0.00 0.00 0.00

Valves - E-500 0.295 0.31 0.00 0.85 0.00 0.00 0.00 0.00

Valves - E-100 0.295 0.31 0.00 0.90 0.00 0.00 0.00 0.00

Flanges - Acc/Inacc 30 0.070 0.31 0.65 0.92 0.00 0.05 0.00 0.01

Flanges - Unsafe 0.070 0.31 0.00 0.00 0.00 0.00 0.00 0.00

Flanges - E-500 0.070 0.31 0.00 0.85 0.00 0.00 0.00 0.00

Flanges - E-100 0.070 0.31 0.00 0.90 0.00 0.00 0.00 0.00

Compressor Seals - To Atm 2.143 0.31 0.00 0.80 0.00 0.00 0.00 0.00

Compressor Seals - To VRS 4 2.143 0.31 2.66 1.00 0.00 0.00 0.00 0.00

Compressor Seals - E-500 2.143 0.31 0.00 0.85 0.00 0.00 0.00 0.00

Compressor seals - E-100 2.143 0.31 0.00 0.90 0.00 0.00 0.00 0.00

PSV - To Atm 6.670 0.31 0.00 0.80 0.00 0.00 0.00 0.00

PSV - To VRS 4 6.670 0.31 8.27 1.00 0.00 0.00 0.00 0.00

PSV - E-500 6.670 0.31 0.00 0.85 0.00 0.00 0.00 0.00

PSV - E-100 6.670 0.31 0.00 0.90 0.00 0.00 0.00 0.00

Pump Seals 1.123 0.31 0.00 0.80 0.00 0.00 0.00 0.00

Pump Seals - E-500 1.123 0.31 0.00 0.85 0.00 0.00 0.00 0.00

Pump Seals - E-100 1.123 0.31 0.00 0.90 0.00 0.00 0.00 0.00

Sub Total 42 11.94 0.00 0.08 0.00 0.01

Oil Service

Valves - Acc/Inacc 324 0.0041 0.56 0.74 0.92 0.00 0.06 0.00 0.01

Valves - Unsafe 0.0041 0.56 0.00 0.00 0.00 0.00 0.00 0.00

Valves - E-500 0.0041 0.56 0.00 0.85 0.00 0.00 0.00 0.00

Valves - E-100 0.0041 0.56 0.00 0.90 0.00 0.00 0.00 0.00

Flanges - Acc/Inacc 888 0.0020 0.56 0.99 0.92 0.00 0.08 0.00 0.01

Flanges - Unsafe 0.0020 0.56 0.00 0.00 0.00 0.00 0.00 0.00

Flanges - E-500 0.0020 0.56 0.00 0.85 0.00 0.00 0.00 0.00

Flanges - E-100 0.0020 0.56 0.00 0.90 0.00 0.00 0.00 0.00

Pump Seals - Single 13 0.0039 0.56 0.03 0.80 0.00 0.01 0.00 0.00

Pump Seals - E-500 0.0039 0.56 0.00 0.85 0.00 0.00 0.00 0.00

Pump Seals - E-100 0.0039 0.56 0.00 0.90 0.00 0.00 0.00 0.00

PSV - To Atm 8 0.2670 0.56 1.20 0.80 0.01 0.24 0.01 0.04

PSV - To VRS 0.2670 0.56 0.00 1.00 0.00 0.00 0.00 0.00

PSV - E-500 0.2670 0.56 0.00 0.85 0.00 0.00 0.00 0.00

PSV - E-100 0.2670 0.56 0.00 0.00 0.00 0.00 0.00 0.00

Sub Total 1233 2.963 0.02 0.38 0.02 0.07

Total 1275 14.91 0.02 0.47 0.02 0.08

TOTAL for (4) 10,000 BBL Tanks plus Other Equipment 24.85 0.03 0.78 0.04 0.14

Notes:

1. Source:

2. APCD P&P # 6100.060.1998.

3. APCD P&P # 6100.061.1998

4. A 80% efficiency is assigned to fugitive components Rule 331 implementation.

Page 7 of 12

LOADING RACK EMISSION CALCULATION (ver 3.0)

Attachment: A Reference: Loading Rack

Company: ERG Foxen Canyon Pipeline Rack Type: Enter X as Appropriate S Factor

Facility: Emergency Trucking ScenarioSubmerged loading of a clean cargo tank

0.50

File Name: Submerged loading: Dedicated normal servicex 0.60

Submerged loading: Dedicated vapor balance

service 1.00

Splash loading of a clean cargo tank1.45

Splash loading: Dedicated normal service1.45

Splash loading: Dedicated vapor balance

service 1.00

Input data Reference

S = Saturation Factor 0.60 See AP-42 Table 4.4-1 2

M = Molecular Weight 50 Crude Oil: Default = 50 lb/lb-mole 3

P = True Vapor Pressure (psia) 3.900 See AP-42 Table 12.3-5 1T = Liquid Temperature 0R 640 180

0F + 460 =

0R 5

R = Loading Rate (bbl/hr) 417.00 17,514 gallons (42 gallons = 1 bbl) 1

C = Storage Capacity (bbl) 25,000 1,050,000 gallons (42 gallons = 1 bbl) 1

D = Daily Production (bbl) 10,000 420,000 gallons (42 gallons = 1 bbl)

A = Annual Production (bbl) 100,000 4,200,000 gallons (42 gallons = 1 bbl) 1

eff = Vapor Recovery Efficiency 0.99 Default = 0.95 1

ROC/THC = Reactivity Crude Oil: Default = 0.885

HLPD = hours loading per day = (C/R) if < 24 = 24.00 hours/day

HLPY = hours loading per year = (A/R) = 239.81 hours/year

LL = Loading loss (lb/1000 gal) = 12.46 (S)(P)(M)/T = 2.2778 lb/1000 gal

Total Uncontrolled Hydrocarbon Losses:

Hourly

THLH = (R)(42 gal/bbl)(LL/1000) = 39.89 lbs/hr

Daily

THLD = (THLH)(HLPD) = 957.46 lbs/day

Annual

THLA = (HLPY)((THLH)(1/2000) = 4.78 TPY

Total Controlled Hydrocarbon Losses:

Hourly

THLHC = (THLH)(1-eff) = 0.40 lbs/hr

Daily

THLDC = (THLD)(1-eff) = 9.57 lbs/day

Annual

THLAC = (THLA)(1-eff) = 0.05 TPY

Processed by: Name Date: August 30, 2012

Notes:

1. Data provided by the applicant

2. AP-42, (Chapter 5, 5th Edition, January 1995), Table 5.2-1

3. If not otherwise provided, crude oil is assumed to be 50 lb/lb-mole.

4. If not otherwise provided, vapor pressure is calculated from CARB AB-2588 Guidelines, page 103, eq. 25

5. R is calculated by adding 460 to 0F.

Revised: October 8, 2007

Page 8 of 12

FOXEN PETROLEUM PIPELINE PROJECT

OPERATIONAL EMISSIONS - Proposed Pipeline and Facility Emissions

Equipment Category Capacity ea. NOX ROC CO SOX PM10 CO2 CH4 N2O CO2e*

Sales Oil Tanks (2) 10,000 BBL

lbs/day 6.02

tons/year 1.10

Reject Tank 3,000 BBL

lbs/day 0.43

tons/year 0.08

Heaters (Primary and Back Up) 5 MMBTU/hr

lbs/day 4.32 0.65 35.64 1.64 0.90 14,029 0.24 0.03 14,042

tons/year 0.79 0.12 6.50 0.30 0.16 2,322 0.04 0.004 2,324

Emergency Oil Tanks (2) 10,000 BBL

lbs/day 2.9

tons/year 0.52

Loading Rack - Emergency Trucking

lbs/day 9.57

tons/year (10 days loading per year) 0.05

Pigging Operations

lbs/day 0.67

tons/year 0.00

Fugitive Component Emissions

lbs/day 0.78

tons/year 0.14

TOTAL

lbs/day 4.32 21.02 35.64 1.64 0.90 14,029 0.24 0.03 14,042

tons/year or MT*/year 0.79 2.01 6.50 0.30 0.16 2,322 0.04 0.004 2,324

CEQA Thresholds (lbs/day) 55.00 55.00 240.00 55.00 80.00 - - - 10,000 MT/yr

*CO₂, CH4, and N2O annual emissions are in Metric Tonnes (MT)

CH4 and N2O emissions are converted to CO2 equivalents by multiplying their emissions by their global warming potential (21 for CH4, 310 for N2O)

SBCAPCD BACT and Offsets Thresholds Comparison

Threshold Units NOX ROC CO SOX PM10

BACTlbs/day per

project25 25 550 25 25

Offsetslbs/day per

project55 55 240 55 80

Page 9 of 12

FOXEN PETROLEUM PIPELINE PROJECT

Trucking Emissions

Baseline Increase New Proposed

Trucking Rate (BBL/day) 3,100 6,800 9,900

Trip Distance (Miles) 21 0 21

Daily Trips 19 42 61

Oil Storage Capacity per

Truck (BBL)160

Proposed Increase in Emissions

NOX ROC CO SOX PM10 CO2 CH4 CO2e (MT)

Emission Factor (lb/mile)* 0.027 0.002 0.009 0.00004 0.001 4.215 0.0001 -

Trip Emissions (lb/trip) 0.587 0.048 0.199 0.001 0.029 90.205 0.002 -Maximum Daily Emissions

(lbs/day)24.653 2.034 8.375 0.037 1.202 3,789 0.094 -

Annual Emissions**

(tons/year)0.370 0.031 0.126 0.001 0.018 51.555 0.001 51.582

*Emission factors taken from CARB 2007EMFAC model (2013 heavy-duty diesel truck)

**Calculated based on estimated annual trips needed to transport oil

Page 10 of 12

FOXEN PETROLEUM PIPELINE PROJECT

Stationary and Mobile Emissions Summary

NOX ROC CO SOX PM10 CO2* CH4* N2O* NOX ROC CO SOX PM10 CO2* CH4* N2O*

Stationary Emissions 4.320 21.019 35.640 1.644 0.900 14,029 0.238 0.026 0.788 2.008 6.504 0.300 0.164 2,322 0.039 0.004 2,324

Mobile Emissions 24.653 2.034 8.375 0.037 1.202 3,789 0.094 0.000 0.370 0.031 0.126 0.001 0.018 52 0.001 0.000 52

Total Emissions 28.973 23.054 44.015 1.681 2.102 17,818 0.332 0.026 1.158 2.038 6.630 0.301 0.182 2,374 0.041 0.004 2,376

CEQA Thresholds 55 55 240 55 80 - - - 10 10 25 15 10 - - - 10,000

Above Threshold? No No No No No No No No No No No No No No No No No

* CO2, CH4, and N2O annual emissions are in Metric Tonnes (MT)

CH4 and N2O emissions are converted to CO2 equivalents by multiplying their emissions by their global warming potential (21 for CH4, 310 for N2O)

Daily Emissions (lbs/day) Annual Emissions (tons/year)CO2e*

Page 11 of 12

FOXEN PETROLEUM PIPELINE PROJECT

Construction Emissions

ROC CO NOX SOX PM10 CO2 CH4 ROC CO NOX SOX PM10 CO2 CH4

Backhoe 1 40 101 0.069 0.353 0.457 0.001 0.038 51.700 0.006 5 35 0.139 0.706 0.913 0.001 0.077 103.400 0.013

Steel Drum Roll 1 60 150 0.147 0.735 1.119 0.001 0.063 124.000 0.013 4 35 0.352 1.763 2.686 0.003 0.151 297.600 0.032

Crane 1 40 250 0.104 0.295 0.995 0.001 0.035 112.000 0.009 1 5 0.042 0.118 0.398 0.001 0.014 44.800 0.004

Water Truck 1 40 190 0.144 0.758 1.031 0.001 0.060 125.000 0.013 2 35 0.115 0.606 0.824 0.001 0.048 100.000 0.010

Delivery Truck & Trailer 1 20 450 0.217 0.636 1.672 0.003 0.063 272.000 0.020 2 4 0.087 0.254 0.669 0.001 0.025 108.800 0.008

Pick-Ups 2 50 185 0.144 0.758 1.031 0.001 0.060 125.000 0.013 2 35 0.288 1.516 2.061 0.003 0.120 250.000 0.026

TOTAL 1.023 4.963 7.551 0.010 0.436 904.600 0.092

ROC CO NOX SOX PM10 CO2 CH4 ROC CO NOX SOX PM10 CO2 CH4

Dump Truck 1 40 487 0.217 0.636 1.787 0.003 0.063 272.000 0.020 3 60 0.260 0.763 2.144 0.003 0.076 326.400 0.024

Water Truck 1 40 190 0.144 0.758 1.031 0.001 0.060 125.000 0.013 2 60 0.115 0.606 0.824 0.001 0.048 100.000 0.010

Welding Machine 3 60 50 0.098 0.275 0.254 0.000 0.024 26.000 0.009 6 60 1.057 2.973 2.738 0.003 0.259 280.800 0.095

Compactor 1 40 240 0.149 0.433 1.418 0.002 0.049 172.000 0.014 7 60 0.418 1.213 3.972 0.005 0.138 481.600 0.038

Backhoe 1 40 101 0.069 0.353 0.457 0.001 0.038 51.700 0.006 6 60 0.167 0.847 1.096 0.001 0.092 124.080 0.015

Excavator 1 40 125 0.109 0.518 0.679 0.001 0.059 73.600 0.010 6 60 0.261 1.242 1.630 0.002 0.141 176.640 0.024

A-Frame 1 40 330 0.155 0.529 1.132 0.002 0.052 180.000 0.014 6 60 0.372 1.270 2.716 0.004 0.124 432.000 0.034

Pavement Saw 1 20 60 0.070 0.754 0.249 0.002 0.030 141.000 0.006 1 5 0.014 0.151 0.050 0.000 0.006 28.200 0.001

Road Boring Machine 1 80 30 0.012 0.063 0.125 0.000 0.003 10.300 0.001 1 10 0.010 0.051 0.100 0.000 0.002 8.240 0.001

Delivery Truck & Trailer 1 20 450 0.217 0.636 1.672 0.003 0.063 272.000 0.020 2 10 0.087 0.254 0.669 0.001 0.025 108.800 0.008

Pick-Ups 3 50 185 0.144 0.758 1.031 0.001 0.060 125.000 0.013 3 60 0.648 3.411 4.637 0.006 0.271 562.500 0.059

TOTAL 3.409 12.782 20.575 0.029 1.183 2,629.260 0.307

ROC CO NOX SOX PM10 CO2 CH4 ROC CO NOX SOX PM10 CO2 CH4

Backhoe 1 40 101 0.069 0.353 0.457 0.001 0.038 51.700 0.006 5 20 0.139 0.706 0.913 0.001 0.077 103.400 0.013

Crane 1 40 250 0.104 0.295 0.995 0.001 0.035 112.000 0.009 1 5 0.042 0.118 0.398 0.001 0.014 44.800 0.004

Dump Truck 1 40 487 0.217 0.636 1.787 0.003 0.063 272.000 0.020 2 20 0.174 0.509 1.429 0.002 0.051 217.600 0.016

Welding Machine 1 60 50 0.098 0.275 0.254 0.000 0.024 26.000 0.009 6 60 0.352 0.991 0.913 0.001 0.086 93.600 0.032

Pick-Ups 2 50 185 0.144 0.758 1.031 0.001 0.060 125.000 0.013 2 20 0.288 1.516 2.061 0.003 0.120 250.000 0.026

TOTAL 0.995 3.840 5.714 0.008 0.348 709.400 0.090

ROC CO NOX SOX PM10 CO2 CH4

5.43 21.59 33.84 0.05 1.97 4,243.26 0.49

Daily Emissions (lb/day)

Daily Emissions (lb/day)

ConocoPhillips Tie-In

Equipment No. Each Load % HP

AGGREGATE TOTALS

Emission Factors (lb/hr) Hours per

Peak Day

Days per

Project

Year

Hours per

Peak Day

Days per

Project

Year

Daily Emissions (lb/day)

Installation of Cantin Facility

Equipment No. Each Load % HPHours per

Peak Day

Days per

Project

Year

Daily Emissions (lb/day)

8" Pipeline Installation

Equipment No. Each Load % HPEmission Factors (lb/hr)

Emission Factors (lb/hr)