Unexpected High Absorption of Atmospheric Aerosols Over a ...
Aerosols and climate Rob Wood, Atmospheric Sciences.
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Transcript of Aerosols and climate Rob Wood, Atmospheric Sciences.
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Aerosols and climateRob Wood, Atmospheric Sciences
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What are aerosols?
• Solid or liquid particles suspended in air
• Sizes range from a few nm to a few thousand nm Huge range of masses
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Where do aerosols come from?
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Present flux
Source Low High Best
NaturalPrimary
Soil dust (mineral aerosol)
1,000 3,000 1,500
Sea salt 1,000 10,000
1,300
Volcanic dust 4 10,000
33
Biological debris 26 80 50
Secondary
Sulfates from biogenic gases
60 110 90
Sulfates from volcanic SO2
4 45 12
Organic matter from biogenic NMHC*
10 200 55
Nitrates from NOx 10 40 22
Present flux
Source Low High Best
AnthropogenicPrimary
Industrial dust etc. 40 130 100
Black carbon (soot and charcoal)
10 30 20
Secondary
Sulphates from SO2 120 180 140Biomass burning (w/o black carbon)
50 140 80
Nitrates from NOx 20 50 36Organics from anthropogenic NMHC*
5 25 10
Estimate of Present-Day Global Emission of Major Aerosol Types (in
Tg/year)
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1 10 100 103 104 105 106 [nm]
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Aerosols and light scattering• Scattering of solar radiation per unit mass is
maximum when particle size is close to solar wavelengths ( ~ 400-800 nm)
• Particles in the size range 200-2000 nm are most efficient scatterers
• Particle surface area more important than mass
10 100 1000 10000
Particle diameter [nm]
Sca
tteri
ng e
ffici
ency
per
mass
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Surface area and mass
• M = (4/3) r3
• A = 4 r2
• A/M 1/r
• when r « scattering efficiency increases with r4
r<100 nm particles don’t matter
10 100 1000 10000
Particle diameter [nm]
Sca
tteri
ng e
ffici
ency
per
mass
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Aerosols and light scattering
• If aerosol particle is soluble then size will depend upon water uptake
• Water uptake depends upon relative humidity (RH)
• For given number of particles, scattering will increase with RH
• But with no particles there is no scattering despite what the RH is
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Size as a function of RH
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Chemical composition affects growth
RH
gro
wth
fact
or
r/r d
ry
3
2
1
marine airmass
polluted airmass
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What determines scattering?
• For particles of size > 200 nm, surface area determines scattering from one particle
• Multiply this by the number concentration of particles to get overall scattering per unit volume of air
• Atot N r2, Mtot N r3
Atot N1/3 M2/3
• Need to know both total aerosol mass and the number concentration
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Importance of sulfate
• Sulfate aerosols dominate the scattering over continental regions
• Anthropogenic sources comparable to natural sources
• Regionally, this scattering can seriously degrade visibility
• Globally, this scattering reduces solar radiation entering the climate system by 2 W m-2
• Studies suggest that about 0.3-0.8 W m-2 of this scattering are from anthropogenic aerosols, mostly sulfate (“direct” effect of aerosols)
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Beijing after rain Beijing during dry period
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Solar radiation reaching the surface
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Global Sulfur Budget
Phytoplankton
(CH3)2S
SO2
1.3d
(DMS)1.0d
OHNO3
Volcanoes Combustion/Smelters
SO42-
3.9d
22
10 64
OH
cloud42
8184
dep27 dry20 wet
dep6 dry44 wet
H2SO4(g)
Rates in Tg S yr-1
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Global Sulfur Emission Patterns
Chin et al. [2000]
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SO2 sources by type
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Direct effect of aerosols upon solar radiation
• Aerosols scatter solar radiation
• More particles more scattering
• Some scattered radiation returns to space
• Reduction in amount entering climate system
Cooling effect
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Aerosol optical depth (measure of scattering)
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How well do we
understand human
influence?
• Direct radiative forcing (effect of anthropogenic emissions on aerosol scattering) from different models
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Trends in U.S. NOx AND SO2
Emissions
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Aerosol-cloud-climate interactions
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More aerosol-Climate effects
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Cloud droplets form on aerosol particles
• For soluble aerosols, particle size increases with RH
• When a parcel of air rises, it cools and the RH increases
• When RH>1, the soluble aerosols can “activate” (grow unstably into much larger cloud droplets)
• The RH at which an aerosol activates is strongly dependent upon its size
• Larger aerosols activate first and can consume vapor, preventing the smaller ones from activating
• The number of cloud droplets is strongly controlled by the number of soluble aerosols
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What determines N in warm clouds?
Aerosol concentration (r>0.1 micron) [cm-3]
Clo
ud
dro
ple
t con
cen
trati
on
[cm
-3]
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Link between number of cloud droplets and cloud albedo
• Similar arguments as for light scattering due to aerosols
• For given amount of liquid water, increased N gives smaller average size of droplets
• Smaller droplets have larger surface area• More reflective cloud, more albedo
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• Most well-understood aerosol-cloud-climate effects (indirect effects)
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Global Sulfur Emission Patterns
Chin et al. [2000]
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MODIS, data courtesy of NASA
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IPCC, 2007
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Putting it all together