A Cyclic Porphyrin Tetramer Linked by Azo and Butadiyne Bridges (Eur. J. Org. Chem. 23/2010)

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EJOCFK (23) 4329–4512 (2010) · ISSN 1434-193X · No. 23/2010 [23] Eur. J. Org. Chem. 2010 , 4329–4512 Cover Picture Dennis P. Arnold et al. A Cyclic Porphyrin Tetramer Microreview Michael G. Organ et al. Pd-PEPPSI Complexes and the Negishi Reaction EurJOC European Journal of Organic Chemistry 23/2010 2nd August Issue D 6093 www.eurj0c.org A Journal of

Transcript of A Cyclic Porphyrin Tetramer Linked by Azo and Butadiyne Bridges (Eur. J. Org. Chem. 23/2010)

Page 1: A Cyclic Porphyrin Tetramer Linked by Azo and Butadiyne Bridges (Eur. J. Org. Chem. 23/2010)

EJOCFK (23) 4329–4512 (2010) · ISSN 1434-193X · No. 23/2010

[23]Eur. J. O

rg. Chem. 22001100, 4329–4512

Cover PictureDennis P. Arnold et al.A Cyclic Porphyrin Tetramer

MicroreviewMichael G. Organ et al.Pd-PEPPSI Complexes and the Negishi Reaction

EurJOCEuropean Journal ofOrganic Chemistry

23/20102nd August Issue

D 6093

www.eurj0c.org

AA JJoouurrnnaall ooff

ejoc_u1_23.qxd 28.07.2010 07:21 Seite 1

Page 2: A Cyclic Porphyrin Tetramer Linked by Azo and Butadiyne Bridges (Eur. J. Org. Chem. 23/2010)

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COVER PICTURE

The cover picture shows the tetranickel complex ofa rectangular porphyrin array with novel connec-tivity. Conjugating azo and butadiyne bridges linkthe opposite sides of the rectangle, and the absorp-tion spectrum demonstrates strong electronic com-munication between the chromophores. The syn-thesis and characterisation of this tetramer aredescribed in the article by D. P. Arnold et al. onp. 4381ff. The molecule is set against a back-ground of a sunset on the Great Barrier Reef,emphasising the role of porphyrinoid pigmentsin solar energy capture.

Eur. J. Org. Chem. 2010, 4331�4337 www.eurjoc.org 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 4331