A Cyclic Porphyrin Tetramer Linked by Azo and Butadiyne Bridges (Eur. J. Org. Chem. 23/2010)
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Transcript of A Cyclic Porphyrin Tetramer Linked by Azo and Butadiyne Bridges (Eur. J. Org. Chem. 23/2010)
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EJOCFK (23) 4329–4512 (2010) · ISSN 1434-193X · No. 23/2010
[23]Eur. J. O
rg. Chem. 22001100, 4329–4512
Cover PictureDennis P. Arnold et al.A Cyclic Porphyrin Tetramer
MicroreviewMichael G. Organ et al.Pd-PEPPSI Complexes and the Negishi Reaction
EurJOCEuropean Journal ofOrganic Chemistry
23/20102nd August Issue
D 6093
www.eurj0c.org
AA JJoouurrnnaall ooff
ejoc_u1_23.qxd 28.07.2010 07:21 Seite 1
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EurJOC is co-owned by 11 societies of ChemPubSoc Europe, a union of European chemical societies for the purpose of publishing high- quality science. All owners merged their national journals to form two leading chemistry journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry. Three further members of ChemPubSoc Europe (Austria, Czech Republic and Sweden) are Associates of the two journals.
COVER PICTURE
The cover picture shows the tetranickel complex ofa rectangular porphyrin array with novel connec-tivity. Conjugating azo and butadiyne bridges linkthe opposite sides of the rectangle, and the absorp-tion spectrum demonstrates strong electronic com-munication between the chromophores. The syn-thesis and characterisation of this tetramer aredescribed in the article by D. P. Arnold et al. onp. 4381ff. The molecule is set against a back-ground of a sunset on the Great Barrier Reef,emphasising the role of porphyrinoid pigmentsin solar energy capture.
Eur. J. Org. Chem. 2010, 4331�4337 www.eurjoc.org 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 4331