4 Qz Pods Presentation 2004

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    QuartzQuartz PodsPods--AnAn ExplorationExploration GuideGuide toto IronIron

    OxideOxide--CopperCopper--GoldGoldMineralisationMineralisation??

    Prepared by:Prepared by:

    Alberto LoboAlberto Lobo--Guerrero S.Guerrero S.

    GeologistGeologist,, M.ScM.Sc.,., MinExMinEx

    EconomicEconomic GeologyGeology ResearchResearch InstituteInstitute

    UniversityUniversity ofofthethe WitwatersrandWitwatersrand

    J ohannesburgJ ohannesburg,, SeptemberSeptember, 2004, 2004

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    Quartz Pods - Exploration Guide to IOCG?

    Contents

    1. Description2. Environment and Extension

    3. QP and Mineralization

    4. Studies to be Done5. Practical Applications

    6. Hypothesis on Origin

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    -Goats-

    common sight

    during field work

    in arid regions

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    Goats with testicles

    hanging from their neck

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    That man is crazy!

    Hes definitely nuts!

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    Ive seen them.

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    Now youve seen themtoo.

    I discovered they are associatedto specific mineral enrichment in soils.

    Mapping goats appendiceshelps explore for mineral deposits

    Its a bitof animal geochemistry

    Quartz pods are another strange feature that I noticed during

    field work for doctoral research in Zambia & Namibia.

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    Quartz pods = particular feature identifiedin most of Lufilian Arc study region

    quartz pod= informal namefor massive or sugary QP of varying dimensions

    Features differ fromvein qtz & pegmatitic qz bodies

    most different = geometry

    shape appears roughly cylindricaloutcrops of undeformed bodies = round to ellipticaldiameter varies fromfew to several hundred meters

    some mapped bodies exceed 4 kmgeophysical evidence of even larger bodies

    Quartz Pods 1

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    Quartz Pods 2

    Occur near intrusive bodies (at times just small apophysis)around iron oxide-copper-gold (IOCG) mineralized systems

    Mostpods made of white qz, but color may vary greatlyExamples show changefrommilky white to dark gray smokey tonesand to light pink or yellow tints

    colors probablydue to:abundant gassalt

    micro-inclusions of:Fe oxideSulfides

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    Quartz Pods 3

    Both translucent + milky qz varieties occur togetherDifferent portions of single body

    may be saccaroidal and/or massive

    QP seldommapped in published geological maps

    Field identification& particularphysico-chemicalfeaturesmay aid inexploration

    of IOCG mnzn 1km

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    QP surface expression E Solwesi, Zambia.Areal extension = few hundred m diameter

    3.5 m

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    Typical QP outcrop in Zambia.

    Areal extension = 200 meters diameter

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    Typical QP outcrop in Zambia.

    Areal extension = 200 meters diameter

    QP Outcrop

    Host rock

    = Katangan

    carbonates

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    Surface expression of very large QP.

    Way to Oas farm, Khorixas inlier, Namibia.

    Ground exclusively made of quartz.

    Suface extends for tens of km.

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    Interpreted airborne magnetometry + radiometrics, east of Kitwe, Zambia.

    Expression of

    quartz pods

    10 km

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    QP Environment and ExtensionQP Environment and Extension

    QP = particular characteristicof Lufilian Arc

    -may be related to rift environments-occur in many rk types:ls, dol, gtds,various schists & gneisses

    NAMIBIA

    ZAMBIA

    500 km

    NQP

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    Quartz podoutcrop

    500 km

    QP outcrops in the Greater Lufilian Arc, Africa

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    QP Environment and ExtensionQP Environment and Extension

    NAMIBIA

    ZAMBIA

    500 km

    N

    QP occur in an extense regionroughly 2000 kmby 300 km

    QP expected to be found in:SE Angola, Katanga provinceD.R. Congo, NW Botswana

    QP

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    500 km

    IOCG deposits and prospects in the Greater Lufilian Arc, Africa

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    Sometimes country rock is deformed upward around QPin a fashion similar to diapirs

    -differential compaction?-disolution?

    Some published geological sheets map QP

    fewreferences describe QP

    Maybe theywere consideredto be just qz veins of minor importance

    QP

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    Four Rock Association

    Four-fold rk association observed in many parts of Lufilian Arcmade up by small bodies of:-massive Fe oxide bodies (mag and/or hem)

    -red-tinted felsic intrusive rocks-gabbro or diorite-qz pods

    1km

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    Four Rock Association

    Association seems to occur in rift environmentsTheir origin is not yet completely understood

    Explaining ubiquitous presence of these 4 rk types

    -ideas for origin ofLufilian Arc IOCG

    mineralization

    -more importantly,clues for

    mineralisationelsewhere

    1km

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    QP and Mineralisation

    QP host IOCG mnzn in many locations

    At times QP actas brittle rocks

    to hold massive mag and/or specular hemmnznw/ accompanying sulfs

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    B

    A

    Braided veinsw/ hem+ oxidized sulfides

    hosted by QP

    Several fracture generationsintersecteach other

    A = outcrop surfaceB = slabbed surface

    FromOas farmKhorixas inlier, Nm

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    Particles Enclosed in QP

    On some locations, large QP containisolated spherical FeOx (hemand/or mag) inclusions

    from10 cmto 1.5 cm.

    Also perfect cubic FeOx crystalsxenoliths of any rk typealso included within QP

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    Brittle character of qz allows it to hostbraided or sub-parallelsheeted veinletsystems filled by hem+sulfs.

    Numerous field examples:

    braided veinsstockworksvarious breccias

    qz is both host rk& single clast componentin Tevrede, NW Namibia

    rich Cu+Au IOCG prospect

    QP and IOCG 1

    Sheeted FeOx veins in QP

    Hydrothermal bx from Tevrede, Nm

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    Dense network of mag-py-cp veinlets in QP

    outcrop at least150m

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    Portion of cp-py rich,mag-filled stockwork in QP

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    Slab of Cu sulf-rich, mag stwkhosted in QP

    Brown stains = hemafter py

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    Surface expressionof bo-cp-mag enrichedstwk in QP.Secondary Cu sulfs (bk)

    Cu carbs (gn-bl)

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    Slab of mineralised QP.Massive hem+minor py

    overprintqz

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    QP and IOCG 2Large QP, NE of Otjiwarongo, Namibiain environs of Otjikoto Au deposit

    500m and over 350m deepcontains minor diss py & mag cubes

    associated to Otjiwarongo batholith

    KombatCu minealso related to batholith

    Both = IOCG deposits

    Quartz Pod

    Fig 2650 km

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    QP investigations might help to guideIOCG field exploration in southern Africa

    detailed macroscopic analysisradioactivity & fluorescence, various wavelengthscathodoluminiscence studies

    detailedspecific gravitychemical analysis (halogens, REE)

    H & O isotopesFluid inclusions: salinity & emplacement T

    3-D geometry of a fewsites using geophysical techniques

    QP Studies to be done

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    QP are related with Fe oxide-Cu-Au mineralized systems.

    May be major breakthrough in mineral exploration

    If QP detailed chemical signature

    from mnzd IOCG systems is characteristic

    = new exploration tool

    Abundant white qz float in circular area= detected easilyon arid regions

    QP outcrops offer good color contrast w/ country rockB/W air photos may help in location

    large outcrop areas identifiable in ASTER images

    Practical Applications of QP

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    1) type of silicification alteration, notwell documented

    2) hyper-alkaline fluids, disolve SiO2 & produce QP space problem

    3) HF-rich extremelyalkaline fluids disolve SiO2replacing itby Fe oxidesSiO2 migrates further out & precipitates QP

    space problemHow to detect F in qz?

    4) Intrusiveevidence of some QP

    Could QP be a qtz-only magma? (Quartzolites?)

    Hypotheses About QP Origin

    PregnantIOCG intrusive

    body

    Silica transported

    by alkaline fluidFeOx

    Silica

    displaced

    by FeOx

    Silica deposited

    as Quartz Pod

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    Call to Other Geologists

    Call attention of researcherswho might have come acrosssimilar QP

    in other parts of the world

    The author welcomes comments

    & contributions to solve questions

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    Now youve seen the quartz pods too.

    C

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    1. QP = massive/sugary qz body

    roughly cylindrical in shape

    round to elliptical outcropdiameter = few to 100s meterssome >4 square km

    2. occur on or around IOCG

    3. probably related to

    hyperalkaline, F-rich hydrothermal fluids

    4. may be new exploration tool

    for IOCG mineralization

    Conclusions

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    QuartzQuartz PodsPods--AnAn ExplorationExploration GuideGuide toto IronIron

    OxideOxide--CopperCopper--GoldGoldMineralisationMineralisation??

    Prepared by:Prepared by:

    Alberto LoboAlberto Lobo--Guerrero S.Guerrero S.

    GeologistGeologist,, M.ScM.Sc.,., MinExMinEx

    EconomicEconomic GeologyGeology ResearchResearch InstituteInstitute

    UniversityUniversity ofofthethe WitwatersrandWitwatersrand

    J ohannesburgJ ohannesburg,, SeptemberSeptember, 2004, 2004

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    IOCG = recently-identified type of ore deposits

    in zones of extensional tectonicsmainly along past rift zones or aulacogenssituated along major structural zones

    Most related to anorogenicintrusive rocksNo direct relationship w/ intrusive rocks

    -in small deposits-distalportions of mineralized systems

    Mineralized deposits containFe oxide nucleus (mag and/or hem)replaced by py and cpy

    IRON OXIDE-COPPER-GOLD MINERAL DEPOSITS

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    Simplified Geological Map

    Salobo Deposit, Brazil

    From Requia et al, 2000

    500 m

    N

    Ve ryalte redtyp eof minera lizationMediumaltered typeof minera lization

    Very altered typeof mineralization

    Medium altered type

    of mineralization

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    Mag might have been demagnetizedinto martite and/or hem

    and later, part or all of the FeOx replaced by sulphides

    May contain economic Au & light rare earth elements(LREE)

    U content might be significantother metals may be economic: Ag, Co, Mn

    Cu mnzn seems related to meteoric fluids & redoxreactions on/around FeOx

    LREEs may be associated with apatite

    IOCG MINERAL DEPOSITS, 2

    Th K U Au Cu Ag F

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    SimplifiedGeochemical Log

    drill hole ALM-FD09

    Alemao Deposit

    Carajas, Brazil

    From Ronze et al, 2000

    FeOx (stars)

    acts as nucleus for

    Cu, Au, Ag, U, F

    mineralization

    Th K U Au Cu Ag F

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    Uncertain issues:-origin of Au + LREEs

    -causes ofhydrothermal alterationsilicate dissolutionmetal transportation

    Source of halogens for highly alkaline and/or F-richsolutions

    -evaporites formed in sabkha, playa or saltlake environments-basinal brines and/or mixing with sea water

    IOCG MINERAL DEPOSITS, 3

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    IOCG MINERAL DEPOSITS, ALTERATION

    Zoned hydrothermal altn in mostmineralized IOCG depsAltn patterns depend on depth of emplacement & host rk chem

    Gral alteration (shallow to deep): -albitization-scapolitization-K-alteration-sericitization

    -silicification

    Widespread massive hematitization, so-called red-rockaltnLarge-scale Na altn around mnzd rocks

    Textural replacements of rock constituents are common

    Alkaline and/or F-rich fluids seemto play important role inhydrothermal altn, metal transportation & silicate disolution.

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    Common textural replacements of rock constituents

    General order of hydrothermal altn/mnzn:

    Country rock albitizationHigh T FeKCa altn

    (Biot-garnet-Kfelds-amphybolite-cpx-mag)Mnzn+low T altn

    (sulphsmaghem-carbser/chl) w/ CuAu

    Explosive bxn in most known depositsMultiple explosive fragmentation in largest orebodies

    IOCG MINERAL DEPOSITS, 5

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    Geometry of mineralized bodies varies substantially

    -Commonest deposits are veins-Some are massive replacements that grade

    into stockworks

    -Bx pipes or diatremes-Tabular bodies that run concordant w/ rock

    foliation or stratification

    Composite deposits comprising veins, bxs,stockworked zones & replacement mantosare common.

    IOCG MINERAL DEPOSITS, 6

    Major IOCG Deposits (from Pollard, 2000)

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    j p ( , )

    Major South American Deposits