34 Alcohols & Ethers - Problems for Practice - Level 1

7/30/2019 34 Alcohols & Ethers - Problems for Practice - Level 1

1/14

EXERCISE-I(A)

Q. Whch of th foowg rcto s cd s BouvutBc rducto

ducto of cy hd wth PdB

B ducto of str wth

ducto of hydrd wth

D ducto of crboy compouds wth g

Q. Gyco o trtmt wth Pmy gvs

Ethy B Ethy odd Ethy odd D Eth

Q. cro s formd wh gycro s htd wth

cdfd

B Br

wtr

D

Q. Gycro o trtmt wth oxc cd t forms

y coho B Formc cd

d D Gycrc cd

Q. f th strtg mtr s mthypoxy cycopt of bsout cofgurto dcd whch

o compoud corrcty rprst th product of ts rcto wth sodum mthoxd mtho.

B

D

Q.6 Wh pho s trtd wth P th yd of chorobz s gry poor bcus of th formto

of

Bzoy chord B pchoropho ochoropho D Trphy phospht

Q.7 th foowg rcto f product s

/O

\HCCHClCH

2

14

2 52

HNaOC

OH|

HOCHCCHClCH522

14

2B

52

2

14

2

HOC|

ONaHCCHClCH

/

O\

HOCCHCHHC5222

14

D/

O\

HOCHCCHCH522

14

2


2/14

Q.8 osdr th rcto of wth th foowg:

I II

Whch forms d-odd o rcto wth xcss?

d both B oy oy D o

Q.9 Etho o rcto wth ctc hydrd gvs

ctc str B Formc str

Ethoc cd D ctc str d Ethoc cd both

Q. Etho cot b drd by hydrous

du to formto of th foowg sovtd product

B

D

Q. t of hydrto of

w b ordr:

< < B < < < < D < <

Q. Th rcto of

wth gvs

B

+

D

+

Q. Th umbr of mthoxy groups compoud c b dtrmd by trtg t wth

d g

B odum crbot odum hydroxd D ctc cd

Q. ost cdc coho out of foowg compouds s

B

D Ph

Q. cto of

o

gvs foowg s mjor product

B

= D

Q.6 compoud X wth mocur formu

8 c b oxdsd to compoud Y wth th mocur

formu

6

X s most y to b

Prmry coho B codry coho dhyd D to

Q.7 Dthy thr d r gvs thr hydroproxd. Th mchsm of th rcto s

ucophc substtuto B Fr rdc ddto

Fr rdc substtuto D o of th bov

Q.8 Ethr o crboyto gvs

oc cd B o y ot D

Q.9

H|

'RORI

+ tru bout ths mchsm

gs phs B

quous phs

both of th bov D o

Q. Pho wth sbrgs rgt gvs upho B uphc cd uphoc str D upho


3/14

Q. ct th odd structur out

B

D

Q. Gycro 4KHSO

4LiAlH

B

d B r:

cro y coho B Gycry supht cryc cd y coho cro D y cro B s ot formd

Q. thr s htd wth phosphorous pt suphd to gv

tho B Dy suphd ydrog suphd D Thostr

Q. PhoC140/CO)ii(

NaOH)i(

2

+ OH/H 2 B

,COOHCH

OAl

3

32

ths rcto th d product s:

scydhyd B scyc cd phy ctt D spr

Q. th brms troso rcto chgs th coour of pho occurs s:

Brow or rd-grsh rd-dp bu B rd-dp bu-gr

rd-gr-wht D wht-rd-gr

Q.6 OH3 . s

B D

Q.74KMnOalkaline

cold

AcOH

CrO3 B

d B r:

B

D o formto of d B


4/14

Q.8 B 4NaBH

= Pt/H

2

d B r:

=

B

=

= both css

D

both css

Q.9 B ONaCH

OHCH

3

3 + H

OH 18

2

d B r

OHOH||CHCCH

|CH

18

23

3

3

23

3

OCHOH||CHCCH

|CH

B

OHOH||CHCCH

|CH

18

23

3

3

23

3

OCHOH||CHCCH

|CH

OHOH||CHCCH

|CH

18

23

3

OHOH

||CHCCH

|CH

1818

23

3

D

OHOH

||CHCCH

|CH

1818

23

3

OHOCH||CHCCH

|CH

3

23

3

Q. xc cd +

hc 42

SOH.conc

B B s:

B

OHOH||CHOCH

22 D o


5/14

Q.

ct schms B out of

I cd ctysd hydrto II B III oxymrcurto-dmrcurto

css B D

Q. Dhydrto of th cohos

w b ordr

V > > > B > > > V V > > > D > V > >

Q. gBr +

+OH3 HBr

B ether/Mg

+

OH

HCHO

3

D HI E

E s

B D

Q. +H ? Product s:

B D

Q. KOH.Alc jor product s

B

D


7/14

Q. ? Product s:

B

D o rcto

Q.NaOHICH)ii(

KOHCHCl)i(

22

3

+

+ [X] hr X s:

B

D

Q. . ths do

t

s mor bsc th tht of t

B t

s mor cdc th t .

both hv sm bscty D both hv sm cdc strgth

Q. =

OH

X

2

2 OH

B

B

ClOH||

)CH(CC)CH(2323

OHOH ||

)CH(CC)CH(2323

D o

Q.HCl

NaNO2

s

B D


8/14

Q.

OH|

OHCHCHCHCHCH222

=

2MnO

. s

O||

OHCHCHCCHCH222

= B

OH|

CHOCHCHCHCH22

=

O||

CHOCHCCHCH22

=

D

O||

COHCHCCHCH ||

O

22 =

Q.6 ctopho HHCO3

+OH3 B + +

H

AnhydridePthalicdctor D

& D r

& B Ph &

Ph & D &

Q.7 m-mopho o trtmt wth d

gvs whch of th foowg s mjor product?

B D

Question No 48 to 50 (3 questions)

Q.8 ompoud B s?

B D


9/14

Q.9 rgc compoud dos ot udrgo d crboxyto rcto bcus?

trmdt dos ot foow ytzff ru

B trmdt dos ot foow ofms ru

trmdt dos ot foow Brdcts ru

D trmdt dos ot foow rwooffs ru

Q. Tot o. of strosomrs of B r?

B D 6

EXERCISE-I(B)Q. ompoud whch gvs coho o rducto sr

O||

ClCMe B

O||

NHCMe2

/O\

CHCHMe2

D

MeOCCMe ||||

OO

Q. Pho d tho r dstgushd by th rcto wth

d tmus B

F

D

Q. th rcto squc

OH2 2

42

Hg

SOH.dil

+ B

Ni

H2 tru bout th product s

gv yow ppt. wth B ts f oxdto product s crboy compoud

ts f oxdto product s

d D ts f oxdto product s

Q. Whch c b cvd by ?

3223 CCHCCHCHCH

||||OO

B 323 CHCHCCHCH

|||OOH

D

OH|

CCHCHCHCCHCH||||OO

3223

Q. B oxymrcurto-dmrcurto d cd ctysd hydrto w ot gv sm product

B D

Q.6 Dthy thr rcts wth P

to form

Ethy chord B Phosphorous oxy trchord

Etho D Eth


10/14

Q.7 ct th corrct sythss products

NaOHOH,OHTHFBH 223

B NaOHNaBH

OH

)OAc(Hg 4

2

2

22ClCH

mCPBA

D

Q.8 Th mocus of thr dhydrts th prsc of

B

P

7D q.

Q.9 hydrd of coho s Ethr B dhyd

y hydrog suphr D

Q. ucs tst s usd to m dstcto btw d cohos

+.conc

HCl 2ZnClanhydrous

turbidityWhite

RCl +

Ths shows tht

bhvs s bs

B grtr th vu of pcoho grtr th rctvty wth coc. d thus soor th formto

of wht turbdty.

coho whch rcts fstst wth mt w gv turbdty t fstst rt

D coho whch gvs rd coour durg Vctor yor tst w gv turbdty t sowr rt th thos

gvg bu or wht coour durg Vctor yor tst.

Q. f tho dssovs wtr th whch of th foowg woud b do

bsorpto of ht B Emsso of ht

crs voum D otrcto voum

Q. Whch mthod s usfu for th sythss of thr?

NaOH.aq

B

+

+

D Br +

Q. Whch of th foowg c rct wth Ts

Gycro B xmocto

of wtrgr D dmthy m


11/14

Q. Whch sr corrct sttmts?

B

Ths s oy ffctd rducto to cohoOHCH

NaBH

3

4

D

Q. -mthy--hxo c b prprd by

g d -hxo foowd by hydroyss

B

g d -pto foowd by hydroyss

7g d -buto foowd by hydroyss

D 9g d propo foowd by hydroyss

Q.6 whch css product formd r ot ccordg to rcto?

+ 42

SOH

B + 42

SOH

= +

D +

Q.7 Dhydrto of cohos t pc mor rpdy wth P

th wth

. ct th corrct

sttmts bout th foowg dhydrto rcto.

pyridine

POCl3

t dos ot vov crbocto.

B t vovs P

wth P

s bttr vg group.

t vovs E mchsm s pyrd bs bstrcts proto from th djct crbo s th sm

tm t whch P s vg.D t s E rcto wthout formto of crbocto.


12/14

Q.8 Whch of th foowg w gt oxdsd by Br to crboxyc cd?

B

OH|

CHCH3

D

Q.9 ob-chmdt rcto o-hydroxy bzoc cd s prdomty formd. Ths s bcus

scyt o s strogr bs th phoxd o

B scyt o s wr bs th phoxd o

p-hydroxy bzot o s strogr bs th phoxd o

D p-hydroxy bzot o s strogr bs th scyt o

Q. tho c b dstgushd from tho by

tg wth

d B Trtg wth schffs rgt

Trtg wth r souto d. D Trtg wth ucs rgt

Q. Products form by foowg rctos r

+KOHCHCl3

B D

Q. For th rctos show bow dtfy th corrct sttmts wth rgrd to th products formd:

+H,MeOH

P MeOH/NaOMe

Q

P d Q r dtc

B P s rcmc d Q s optcy ctv

P d Q r posto somrsD both r optcy ctv

Q.

reagent

Tilden 3

NH

HCl

NaNO2 . Th product c b

coho B Ethr y chord D y trt


13/14

Q. Products form durg dhydrto of foowg cohos r

+H

B D

Q. osdr th foowg compoud bow

ct th corrct sttmts

t s mor cdc th B t s mor cdc th COHCH

||O

3 t rcts vry fst wth ucs rgt D t s dcd bs

Q.6 tch th foowg:

Reaction Mechanism

42SOH.Conc P chg umbr of crbo cyc

B 4HIO Q Pco rrrgmt

heat

H

xdtv bod cvg

Dheat

OH3

to s product

Q.7 tch th coum:

Column I Column II

dtfcto of & cohos P xymrcurto dmrcurto

B dtfcto of & tro s Q u ht

Formto of coho by t rovovs Vctor yrs tst

ddto of D Formto of coho by rovovs ydroborto oxdto

ddto

T ucs tst


14/14

Q.8 tch th coum:

Column I Column II

xdto of coho dhyd P

B r

. . Q os rgt

r

. Jos rgt

D xdto of to cd P..

Q.9 tch th products of foowg:

Column I Column II

HI

P

B Vot coor s obt by th Q

rcto of utr F

wth

cto of bzdhyd wth

gvs

D + ?

Q.

3

23

CH|

CHCHCHCH =

RagentRe

coho

whch s tru bout coho d ?

Alcohol Reagent

3

223

CH|

OHCHCHCHCH B6

B

OHCH ||

CHCHCHCH

3

33

Pd

3

323

CH|

CHCHCCH |

OH

gc

B

D

3

323

CH|

CHCHCCH|OH

d.

34 Alcohols & Ethers - Problems for Practice - Level 1

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Transcript of 34 Alcohols & Ethers - Problems for Practice - Level 1