3-5 Foul Condensate · PDF fileFoul Condensate Stripping Ben Lin, ... 2008 Kraft Recovery...
Transcript of 3-5 Foul Condensate · PDF fileFoul Condensate Stripping Ben Lin, ... 2008 Kraft Recovery...
1
Foul Condensate Stripping
Ben Lin, P.Eng.A. H. Lundberg Systems Limited
Vancouver, B.C., Canada
2008 Kraft Recovery Short Course
2
Agenda
1. Introduction2. Stripping Basics3. Stripping Equipment4. Stripper Integration5. Stripper Operation
2
1. Introduction
4
Introduction
Most Kraft mills have Foul Condensate Strippers in order to reduce Hazardous Air Pollutants under the Cluster Rule
3
5
Stripping System Objectives
1. Meet environmental regulations
2. Reduce TRS emissions in effluent treatment systems
3. Produce a gas stream suitable for incineration
4. Produce relatively clean condensate suitable for reuse in the mill
6
Pollution Control
1 to 22 to 4Odour(TRS)
1 to 22 to 4Toxicity(turpenes and red oils)
7 to 1014 to 20BOD(Kg/tonne)(Lb/ton)
4
7
Cluster RuleReduce HAP by 92%Bleached mill– 10.2 lb HAP per ODTP– 330 ppm HAP in stripped condensateUnbleached mill– 6.6 lb HAP per ODTP– 210 ppm HAP in stripped condensateMethanol can be used as a surrogate for total HAPs
2. Stripping Basics
5
9
Benefits of FC Stripping
Reduced effluent and air pollutants– Remove 98+% of TRS and 95+% of methanol from foul
condensate
Reduced mill water usage– Stripped condensate is relatively clean and can be reused
elsewhere in the mill
Reduced fossil fuel usage– Concentrate SOG to 50 wt% methanol and deliver to
incineration point for thermal destruction
10
Alternatives
Hard piping to biological treatmentRe-using the condensates in a process where the vents are collected and incineratedAny other process that can meet the required removal efficiencies
6
11
Typical Condensate Sources
Condensed batch blow steamCondensed batch digester relief steamCondensed continuous digester liquor flash steamTurpentine decanter underflowEvaporator combined condensatesNCG system condensates
12
Foul condensate stripping
Contaminants are removed from foul condensate by the process of steam distillation
Most abundant and most difficult to remove is methanol, thus process is modelled as binary distillation process between methanol and water
7
13
3. Stripping Equipment
8
15
Stripping System Equipment
Foul condensate tankCondensate fiber filterCondensate pre-heatersStripping columnReboiler (optional)Reflux condenserSOG RD, ME, FA, firing nozzle
16
Stripper Feed TankThe bigger the better30 minutes retention time minimumSeveral hours better300 series stainless steelMust be vented to CNCG
9
17
Foul Condensate Pump
18
Condensate Fiber Filter
Used to prevent plugging in downstream process equipment
10
19
Condensate Preheater
20
Condensate PreheaterStandard is shell and tube, with 300 series stainless steel tubesClean condensate on tube side, foul on the shell sideSpirals may be betterPlate type plugs quickly unless designed for white water serviceMust heat condensate to within 20 °F (10 °C) of column temperature
11
21
Foul Condensate Preheater
Foul condensate is fed through preheaters counter-current to stripped condensate to recover heat
22
Spiral Preheater
12
23
Condensate Preheater
24
Stripping Column
13
25
Stripping ColumnStripping column has two sections of trays, the bottom “stripping” and top “enriching” section
26
Stripping Column
Foul condensate is introduced between the enriching and stripping sectionsSteam is introduced below the bottom sectionSteam flows countercurrent to condensate flow down, thus “stripping”of methanol and other volatile contaminants
14
27
Stripping Column
Steam passes up through “valves”in the trays, partially reboiling the liquid as it passes downBoiling the liquid will preferentially vapourize methanol and other volatiles
28
Stripping Column
For 1000 tpd mill, (300 gpm, 1150 Lpm)
– Column 6’ diameter (2 m)– Column 60’ tall (18 m)– Operates at 10 psig (170 kPag)– Uses 20 valve trays– 5 trays in top section– 15 trays in bottom section– 300 series stainless steel
15
29
Stripping Column
30
16
31
Reboiler
32
SOV line from stripper
17
33
SOV line from stripper
34
Reflux CondenserOverhead vapour is condensed in the reflux condenser and returned to the top of the column for “enriching” of the methanol contentA small amount of product, Stripper Off Gas, SOG, is bled off at the reflux condenserA reflux condensate temperature 30 °F less than the underflow temperature will give 50 wt%
18
35
Reflux CondenserShell and tube heat exchangerAll 300 series stainless steelInstalled horizontally or verticallyCoolant through tubesUses water or weak black liquor for cooling
36
Reflux Condenser
19
37
Steam RequirementNormally use steam ratio of 0.2 pounds of steam per pound of condensateFor 300 gpm (1150 l/m),this is 30,000 lb/hr (13,600 kg/hr) steamRequire effective steam ratio of 0.16 to 0.18 for good efficiency
Steam Requirement
Some steam is condensed to bring the incoming condensate up to the column operating temperature
What is left is the EFFECTIVE STEAM
20
39
Effective Steam
0 20 40 60 80 100Temperature Difference (°F)
.20
0
.04
.08
.12
.16%
Met
hano
l Rem
oval
Steam / Condensate Ratio(Effective)
.05 .10 .15 .20
20
40
60
80
100
Stripper Efficiency
0
21
41
Compliance MonitoringMust show that the stripper is
operating with enough effective steam to ensure adequate methanol removal
For each stripper, develop a curve for desired efficiency at various steam ratios and delta T
Operate below the curve
42
Compliance Monitoring
T
Steam / Condensate Ratio
010203040506070
.14 .16 .18 .20 .22 .24 .26
Must operate below the curve
22
43
Compliance Monitoring
Simple alternate method
Always operate with enough steamthat you are in compliance
regardless of the heat exchanger
4. Stripper Integration
23
45
Integrated Columns
AdvantagesAdvantages
DisadvantagesDisadvantages
Loss of EvaporatorEfficiency
Lower Capital CostLower Operating Cost
46
Integrated Columns
For every K Cal lost due to integration, two or more K Cal are returned asusable fuel
24
47
Fully Integrated Column
#1 #2
48
Fully Integrated Column
#1 #2
25
49
Fully Integrated Column
#1 #2
50
Fully Integrated Column
#1 #2
SOG
26
Evaporator Steam
Main Section
Reflux
Partially Integrated Column
Dedicated Section
Column
No. 1 Effect
SOG
52
Operating ProblemsFoamingUnstable OperationSteam CollapseReflux ControlFiberPlugged Heat ExchangerTurpentine in Storage Tank
27
5. Stripper Operation
54
Stripper
Condenser
RefluxT
P
To Incineration
Cooling Water
Reflux ControlSimple
28
55
Reflux ControlBetter
Stripper
To incineration
Cooling Water
T
P
Reflux
Reflux Tank
Liquid
Vapor
Condenser
56
Stripper Gas System
PC
FCRefluxCondenser
Make upSteam
InsulatedLine
Vent
PurgeSteam
FA
ToIncineration
29
57
Liquid Methanol
Cluster Rule now approvesMany AdvantagesHigher Stripper uptime– Store MeOH as a liquid fuel– Measure MeOH flow for
compliance monitoring
58
Operating Procedures
Start up on steamAdd condensate slowlyMake small step changes
30
59
Emergency Shutdown
Close pressure control valveStop condensate flowLeave steam on
60
Conclusion
Stripping is a good method of meeting the
Cluster Rules