17360 Groschke Road...17360 Groschke Road Houston, TX 77084 Phone: 281-578-7575 Fax: 281-578-7576...

17360 Groschke Road

Houston, TX 77084 Phone: 281-578-7575

Fax: 281-578-7576

Spectrum Quality Standards was established in 1994 with the sole business purpose of manufacturing hydrocarbon standards for the Petrochemical Industry. Since its inception, Spectrum has become a major supplier of standards to Refineries, Chemical Plants, Regulatory Authorities, and Independent laboratories. Spectrum is also the manufacturer of NIST Standard Reference Materials. Spectrum’s Calibration and Q.C. Standards have been formulated to meet the requirements of both ASTM and EPA Methods. All raw materials are checked for chemical purity and the prepared standards analyzed for composition. The results are then compared against the gravimetric figures and are NIST traceable by weight. The Standards are designed specifically for the Analytical Chemist to efficiently and economically analyze for the required properties. The advantages of using Spectrum’s Standards are:

• Increased confidence in analytical results by using Method Specific Calibration Standards;

• Minimum time spent preparing calibration curves, enabling greater productivity by laboratory staff;

• All Standards are ready to use and available with or without an Internal Standard; • Standards are made in large quantities and packaged in glass ampoules, thus ensuring

uniform composition and continuity of supply of Standards with the same composition; • Daily Calibration Checks and Reference Standards are available, conforming to ASTM

Methods; • Large quantities are available for the calibration of Process Analyzers.

Spectrum Quality Standards is committed to providing Certified, Verified and Analytically Traceable Standards to the Petrochemical Industry.

To order, Call 281-578-7575, Fax 281-578-7576 or visit our Web site: www.spectrumstandards.com

http://www.spectrumstandards.com/�

Oxygenate Standards for Gas Chromatography

Oxygenate Calibration Standards [ASTM D4815, D5599] 7 Alcohol Calibration Standards [Oxyalcohol, Oxytex] 8 Oxygenate Daily Check Standards [DCK 1 thru 10] 8 Low Level Oxygenate Standard [Low Ox] 9 MTBE Impurity Standards [ASTM D5441] 9 Gasoline Reference Standards [CALRR1, 2, 3, FIA] 10 Reference Blank Standards [BLK-] 10 Oxygenated Gasoline Standards [NIST] 11 Oxygenates in Water [OXY-W] 11 Fuel Ethanol Standards [ASTM D5501] 11 Calibration Standards for Infrared Analyzers [IRQC1 thru 10] 12 Octane Check Standards [OCT 1 thru 3] 12 Benzene Check Standards [IRQC 12 thru 15] 12

PONA and PIANO Standards / DHA Standards

Quantitative PIANO Mixture [PIANO-1, -10, ASTM D6729, D6730, D6733] 13 PIANO Paraffins Standard [PIANO-P] 14 PIANO Isoparaffins Standard [PIANO-I] 15 PIANO Aromatics Standard [PIANO-A] 16 PIANO Naphthalene Standard [PIANO-N] 17 PIANO Olefins Standard [PIANO-O] 18 Combined PIANO Standards [PIANO-5, PIANO-5-SET] 19 Quantitative PONA Mixture [PONA-1, -10, ASTM D5134] 19 PONA-7 [PONA-7-1, -10 ASTM D6730, D6733 19 SIMDIS Calibration Standards [ASTM D3710] 20 Boiling Range Distribution [ASTM D6352] 20 Polywax Calibration [ASTM D7169, D6352] 20 Engine Oil Volatized at 371 C [ASTM D6417] 21 Quantitative Alkylate Reference [ALK-1] 21 SIMDIS Calibration Standards [ASTM D2887, D7213] 22 GRS Reference Gas Oil #2 [ASTM D2887] 23

Benzene, Aromatic and Biodiesel Standards

Benzene Purity Standards [ASTM D5713] 23 Benzene Purity Standards [D4492] 24 Benzene Calibration Standards [ASTM D3606M, B, D, N, EM, EB, EN] 24 Benzene Check Standards [ASTM D3606DBE thru –DN] 25 Quality Control Reference Material [D5769 AR1000, 3000, 4000] 25 Aromatics in Finished Gasoline [ASTM D5769 - 3-Component Internal] 26 Aromatics in Finished Gasoline [ASTM D5769 – 4-Component Internal] 27 Deuterated Internal Standards [ASTM D5769 INT-1, -5, T-1, T-5] 28 D6550 Olefins in Finished Gasoline [6550CAL, CAL-S, -H, -X, CK, REF] 29 Total Aromatics in Finished Gasoline [ASTM D5580] 30 D1319 Aromatics and Olefins by FIA [FIA1000, CALFIA, FIA1000-CY] 30 Aromatics in Diesel & Aviation Fuels [ASTM D5186] 31 Aromatics for UOP Methods [UOP720, 744, 931, 831, 551] 32 Aromatics for UOP Methods [UOP798, 690, 868, 880] 33 Non-Aromatics for UOP Methods [UOP543, 621, 870] 34

CONTENTS

Biodiesel in Diesel Standards [ASTM D7371 Low Set A, B and C] 35 Biodiesel in Diesel Standards [ASTM D7371 High Set A, B and C] 36 Biodiesel in Diesel Standards [ASTM D7371 Ultra High Set A, B and C] 37 IP585 FAME Standards [IP585] Calibration and Check Standards 37

Total Sulfur by UV Fluorescence [ASTM D5453] 38 Sulfur by Oxidative Microcoulometry [ASTM D3120, D3246, and D3961] 38 Sulfur by Rateometric Colorimetry [ASTM D4045, D6313] 38 Sulfur by High Temp Combustion [ASTM D1552] 39 Sulfur by Combustion & Electrochemical Detection [ASTM D6428] 39 Trace Nitrogen by Combustion & Electrochemical Detection [ASTM D6069] 39 Trace Nitrogen by Chemiluminescence [ASTM D4629, D5762] 40 Sulfur and Nitrogen Standards [SNCAL, SNCK] 40 Sulfur by X-ray Spectrometry [ASTM D2622, D4294] 41 Calibration Set for Low Level Sulfur [CARB XRF1, 2] 42 Sulfur in Gasoline by X-ray [ASTM D6334] 42 Trace Sulfur in P-Xylene [PX-R1, R2, DCK, BLANK] 42 Sulfur Standards in Bulk Quantities 43 EPA ULSD Qualification Set [EPA PB, -PB-S] 44 Standards for Ultra Low Sulfur Diesel [ASTM D5453] 44 Standards for Ultra Low Sulfur Diesel [ASTM D7039] 44 D5623 Mercaptan Sulfur Standards [MSX-14, MSX-1] 45 D5623 Mercaptan Sulfur Standards [MSX-22] 46 D3227 Mercaptan Sulfide Standards [UOP163] 46 D5623 Multi-Component Sulfur Standards [MSX-41] 47 D5623 Mercaptan Sulfur & Thiophene [MSX-1, -M, -THIO] 48 Organic Chlorides in Crude Oil [ASTM D4929 (b)] 49 Organic Chloride in Hydrocarbons [ASTM D5808] 49 Organo Fluorine Standards [FC-1, FP-1, FB-2, FH-1, FT-1] 49 Chlorine in Mineral Oil Standards [OCR1, 2, CK, XOS-CL-M, CL-H2O, -DCK] 50 Chlorine & Sulfur in Mineral Oil [OCS-R1, R2, CK] 50

Physical Properties Standards

CONTENTS

Benzene, Aromatic and Biodiesel Standards

Nitrogen and Sulfur Standards

D2386 Freezing Point Standards [FPZ 50, 45] 51 D97 Pour Point Standards [PP5, 10, 15, 20, 40, 50] 51 D2500 Cloud Point Standards [CP5, 2, 10, 15, 20] 51 D6371/IP309 Cold Filter Plug Point [CFPP1, 2, 3] 51 D5949 Pour Point for Phase [PP67-PH, PP17-PH] 52 D5773 Cloud Point for Phase [CP55-PH, CP15-PH] 52 D5972 Freeze Point for Phase [FPZ51-PH, FPZ4-PH] 52 D92, D93, D56 Flash Point Standards [FP60, 75, 93] 52 D92, D93, D56 Flash Point Standards [FP200, 230, TCC40, 55, 60, 68] 52 IP33/IP170 Abel Flash Point [AB40] 53

Certified Flash Points [FP53ND, 65UD, 110TD, 134HEX, 115TD, 138HEX, 51ND, 67UD] 54 D445 Viscosity Standards [VIS4, 7, 20, 60, 180, 520] 54 D5188 Vapor–Liquid Ratio Temp [VL1, VL2] 54 D5482, D5191 Vapor Pressure Standards [VP1-7, 5191-20,-54G,-54G-S,-5G,-L 54 Determination of Silicon as Siloxane [SIL-CAL, -CK] 55 D6045, D848, D6258 Color Standards [SAY, ASTM, 848-03, 6258CAL –CK] 56 D86 Group 1, 2 & 4 Synthetic Distillation Standards [D86-1, -2, -3, 4-1, 4-2] 57 D850 Distillation Standards [D850-4-1, -2] 58 D3230 Salt in Crude Standards [3230CAL-QT, 3230DCK-16] 58

Physical Properties Standards

D611 Aniline Point Standards [AP611, AP611E] 59 D611 Pure Aniline [ANP] 59 D6304 Water for Coulometric Karl Fischer [KF40, 60, 100, 500, 1000, 5000] 60 D6304 Water for Volumetric Karl Fischer [KF100, 1000, 5000] 60 Wear Metal Standards in Oils [D5708, D4927, D5863 WM12, WM21] 61 D5059 Lead in Gasoline Standards [5059-A, 5059-ISTD] 62 D3237 Lead in Gasoline Standards [3237-02, -05, -10, X3] 62 Phosphorous in Gasoline by XRF [P-CAL, P-DCK] 62 Matrix Oils and Stabilizer Solutions [S20, S75, LS-D] 62 Standards for Underground Fuel Spills [BTEX / MTBE Mix - BTEX-M-200, -2000] 63 Standards for Underground Fuel Spills [BTEX / MTBE Cal Sets – BTEX-CAL-L, -H] 63 Standards for Underground Fuel Spills [GRO-MIX, GRO-CAL] 63 Ion Chromatography Standards [IC-11, IC-4] 64

Miscellaneous Standards

CONTENTS

The Clean Air Act of 1995 mandated the use of Reformulated Gasoline in designated areas of the country. The EPA designated two ASTM Methods for the analysis of Oxygenates in Gasoline and the use of a Five Point Calibration Set with DME as the Internal Standard. The following Oxygenate Calibration Sets are packaged in 2 ml ampoules and are certified to +/- 1% relative and are NIST traceable by weight.

D4815 Calibration Set D5599 Calibration Set

Nominal % Wt. 1-Butanol 0.25 – 5.0 Methanol 0.5 – 15.0 Ethanol 0.25 – 15.0 MTBE 1.0 – 16.0 ETBE 1.25 – 15.0 1-Propanol 0.25 – 5.0 2-Propanol 0.25 – 5.0 Iso-Butanol 0.25 – 5.0 DIPE 0.25 – 5.0 TAME 0.5 – 15.0 Sec-Butyl Alcohol 0.25- - 5.0 t-Amyl Alcohol 0.25 – 2.5 t-Butyl Alcohol 0.5 – 15.0 DME 5.0 RFA Balance 11 Mixtures 4815CAL – Calibration Set $260

Nominal % Wt. Methanol 0.25 – 12.5 Ethanol 0.25 – 13.0 t-Butanol 0.25 – 12.5 MTBE 0.25 – 15.0 ETBE 1.0 – 18.0 TAME 0.10 – 2.0 DIPE 0.25 – 5.0 RFA Balance +DME +5.0 1-Butanol 0.25 – 5.0

8 Mixtures 5599 – OXYCAL – Calibration Set $220

Low Calibration Set D4815 Calibration Set

Nominal, ppm Wt. MTBE 100, 250, 500, 750 1000 ppm wt. in RFA MTBE 1, 5, 10, 50, 100, 500, 1000 ppm wt. in Isooctane Standards are available in 2 ml or 10 ml ampoules. An internal standard, DME, can be added at 5 % wt. LOWCAL Calibration Set (2 ml) in RFA $160 Calibration Set (10 ml) in RFA $220 Calibration Set (2 ml) in ISO $160 Calibration Set (10 ml) in ISO $220

Nominal % Wt. Methanol 0.25 – 12.5 Ethanol 0.25 – 13.0 t-Butanol 0.25 – 12.5 MTBE 0.25 – 15.0 ETBE 1.0 – 18.0 TAME 0.10 – 2.0 DIPE 0.25 – 5.0 DME 5.0 RFA Balance 8 Mixtures 4815 – OXYCAL – Calibration Set $220

Standards can also be custom made to any specifications. Please call for details.


7

OXYGENATE STANDARDS



OXYGENATE STANDARDS

Alcohol Calibration Standards

Alcohol/Ether Nominal % Wt. Alcohol/Ether Nominal % Wt. Isopropanol 0.25 – 12.0 Isopropanol 0.25 – 12.0 N-Propanol 0.25 – 12.0 N-Propanol 0.25 – 12.0 Iso-Butanol 0.25 – 12.0 Iso-Butanol 0.25 – 12.0 Sec-Butanol 0.25 – 12.0 Sec-Butanol 0.25 – 12.0 N-Butanol 0.25 – 12.0 N-Butanol 0.25 – 12.0 DIPE 0.25 – 12.0 DIPE 0.25 – 20.0 t-Amyl Alcohol 0.25 – 12.0 t-Amyl Alcohol 0.25 – 12.0 RFA Balance RFA Balance +DME 5.0 +DME 5.0 Oxyalcohol Calibration Set $220 Oxytex Calibration Set $220

Check Standards

The EPA requires calibrations be checked using a Calibration Check Standard at least once per analysis batch or once per 10 samples; and an Independent Reference Standard at least once per analysis batch or at least once per 100 samples. Additionally, the Calibration Check Standard and the Reference Standard must be made from different lots of raw materials and by different persons. Spectrum manufactures Check Standards in compliance with EPA regulations. They consist of a Calibration Check Standard, a Reference Standard and a Reference Blank. Catalog # Product Price (Set of 10) / (Set of 60) DCK-1-(# of days) 14.9% wt. MTBE/RFA $130 $700 DCK-2-(# of days) 11.0% wt. MTBE/RFA $130 $700 DCK-3-(# of days) 5.77% wt. ETOH/RFA $130 $700 DCK-4-(# of days) 7.77% wt. ETOH/RFA $130 $700 DCK-5-(# of days) 12.80% wt. TAME/RFA $130 $700 DCK-6-(# of days) 17.30% wt. TAME/RFA $130 $700 DCK-7-(# of days) 12.80% wt. ETBE/RFA $130 $700 DCK-8-(# of days) 17.30% wt. ETBE/RFA $130 $700 DCK-10-(# of days) 10% wt. ETOH/RFA $130 $700

8



Spectrum offers standards for analyzers used for determination of trace level oxygenates and impurities in hydrocarbon matrices. We supply a comprehensive range of standards in an n-Hexane matrix at concentrations ranging from 1 – 500 ppm wt. Standards can be supplied either in 2 ml glass ampoules, 0.8 Liter cylinders or mini-inert vials. Component Nominal Component Nominal Concentration Concentration ppm wt. ppm wt. Dimethyl Ether 1.0 n-Butanol 1.0 Acetaldehyde 1.0 iso-Butanol 1.0 Methanol 1.0 iso-Butanal 1.0 Ethanol 1.0 Butyraldehyde 1.0 Propyl Ether 1.0 tert-Ethyl butyl Ether 1.0 Propionaldehyde 1.0 Di-Iso Propyl Ether 1.0 Isopropanol 1.0 tert-Butyl Methyl Ether 1.0 tert-Butanol 1.0 tert-Amyl Ether 1.0 Propanol 1.0 Acetone 1.0 Methyl Ethyl Ketone 1.0 Valderaldehyde 1.0 Diethyl Ether 1.0 n-Hexane Balance Catalog # Product Price LOW-OX 10 2 ml glass ampoules $135 LOW-OX CYL 0.8 Liter Cylinder $1,000* * Includes the cost of the cylinder. Refills of the same cylinder cost $550 The standards can be custom made to any specified concentration. Components can be added to suit your needs.

ASTM D5441 MTBE Impurity Standard

Standards are supplied in 2 ml flame sealed ampoules under a nitrogen atmosphere at the listed concentrations. tert-Amyl Methyl Ether 0.5 % wt. n-Pentane 0.25% wt. tert-Butanol 0.5 % wt. cis-2-Pentene 0.25% wt. sec-Butyl Methyl Ether 0.25 % wt. trans-2-Pentene 0.25% wt. Methanol 0.5 % wt. Di-Isobutylene 0.5 % wt. n-Heptane 0.5% wt. C12+ as Triisobutylene 0.5 % wt. Iso-Pentane 0.25 % wt. MTBE Balance Catalog # Product Price MTBE MTBE Impurity Standard $140 (Set of 10)

LOW LEVEL OXYGENATE STANDARDS

9



In early 1996 we conducted an Inter-Laboratory study on a California Phase II Gasoline. The object of the study was to provide a well analyzed standard for checking calibrations and for use in SQC Programs. A total of 25 refinery laboratories participated and the results were statistically analyzed and the mean reported. The Gasoline is packaged in 25 ml glass ampoules under an argon atmosphere. Average results are tabulated below: ASTM Number Test Results D4052 Density @ 60 F 0.7389 D2622 Sulfur by XRF 31 ppm D5453 Sulfur by Chemiluminescence 28 ppm D1319 Aromatics by FIA 22.2 % LV D1319 Olefins by FIA 5.7 % LV D5769 Total Aromatics by GC/MS 21.60 % LV D5580 Total Aromatics 22.43 % LV D5580 Benzene 0.79 % LV D3606 Benzene 0.80 % LV D5769 Benzene by GC/MS 0.81 % LV D5769 Aromatics by GC/MS 21.81 % LV D5599 MTBE by OFID 11.22 % wt. D4815 MTBE 11.15 % wt. D5191 RVP 6.87 psi Evap. Rec. D86 Distillation IBP - 98.1 98.1 10% - 142.9 145.3 50% - 207.2 209.1 90% - 295.0 300.1 EP - 381.3 380.2 Catalog # Product Price CALRR1 1 x 25 ml ampoule $25 CALRR2 5 x 25 ml ampoule $95 CALRR3 Set of 10 x 2 ml ampoules $120 CALFIA Set of 10 for FIA D1319 $120

Gasoline Reference Blank

The Gasoline contains less than 10 ppm wt. oxygenates as MTBE. It is packaged in 10x2ml flame sealed ampoules per set. Larger quantities are available in ampoules or bottles. Catalog # Product Price BLK-GAS Gasoline Reference Blank $40 *We also offer the following sets of Blanks: Catalog # Product Price ISO-BLANK Nitrogen in Isooctane Blank $40 BLK-DIESEL Diesel Blank $45 BLK-OIL DRACOL 10 Oil Blank $35 BLK-PX P-Xylene Blank $90 BLK-TOL Toluene Blank $40 BLK Reference Blank for ASTM D3606 $40

GASOLINE REFERENCE STANDARDS

10



Oxygenated Gasoline Standards are packaged in 20 ml ampoules. Use of this Standard determines validation of the Oxygen content of fuels. These Standards can be used with ASTM Methods D4815 and D5599. Each set contains one each of the following Oxygenates or can be supplied in custom configurations. Catalog # Product Price / Set of 5 NIST 577 5.77% wt. Ethanol in RFA Gasoline $140 NIST 128 12.8% wt. TAME in RFA Gasoline $140 NIST 173 17.3% wt. TAME in RFA Gasoline $140 NIST 129 12.8% wt. ETBE in RFA Gasoline $140 NIST 174 17.3% wt. ETBE in RFA Gasoline $140

Oxygenates in Water

Calibration Sets are available containing Methanol, MTBE, Acetone and tert-Butyl Alcohol in Water at 1, 10, 20, 50, 100, 250 and 500 ppm wt. Calibration Sets can also be custom made to any specification. Catalog # Product Price OXY-W Seven Point Calibration Set $130

ASTM D5501 Fuel Ethanol Standards

The increasing use of fuel Ethanol as an Oxygenate Additive in Gasoline has made its composition important to ensure blended fuel complies with Federal and State laws. Our Standards meet the requirements of ASTM D5501. Concentrations below are in mass %:

Components [mass %]

Mix 1 Mix 2 Mix 3 Mix 4 Mix 5

Methanol 0.6 0.5 0.3 0.2 0.1 Ethanol 20.0 50.0 75.0 90.0 99.4

Heptane 10.0 10.0 10.0 4.0 0.5 Hydrocarbon

Diluent 69.4 39.5 14.8 5.8 0.0

Catalog # Product Price ETOH5501CK Fuel Ethanol Check Std. [Specify Mix 1-5] (10x2ml) $100 5501CAL-5 Fuel Ethanol Calibration Set (5x2ml) $140

11

GASOLINE REFERENCE STANDARDS



Infrared Analyzers provide rapid and accurate analysis that can replace the expense and time delay of laboratory analysis. They are used to determine the Gasoline Oxygenate content to ensure product quality and compliance with regulatory authorities. Spectrum offers Calibration Standards for Portable and On-line Infrared Analyzers for the determination of Oxygenates, Benzene and Octane numbers in Gasoline. The standards are either single or multi-component blends of Oxygenates in a Gasoline Matrix and are supplied in 20 ml ampoules. Infrared Calibration Standards

Catalog # Product Price (Set of 5) IRQC 1 14.9% wt. MTBE / RFA Gasoline $100 IRQC 2 11.0% wt. MTBE / RFA Gasoline $100 IRQC 3 5.77% wt. ETOH / RFA Gasoline $100 IRQC 4 7.77% wt. ETOH / RFA Gasoline $100 IRQC 5 12.80% wt. TAME / RFA Gasoline $100 IRQC 6 17.30% wt. TAME / RFA Gasoline $100 IRQC 7 12.80% wt. ETBE / RFA Gasoline $100 IRQC 8 17.30% wt. ETBE / RFA Gasoline $100 IRQC10-M 10.0% wt. MTBE / RFA Gasoline $100 IRQC10-E 10.0% wt. ETOH / RFA Gasoline $100 IRQC B Instrument Blank / RFA Gasoline $80 *Concentrations can be reported in either liquid volume or weight %. Benzene and Oxygen contents are also reported. Octane Check Standards

Standards are packaged in 20 ml ampoules and the RON, MON and (R+M)/2 are reported. Catalog # Product Price (Set of 5) OCT1 11.0% wt. MTBE / RFA Gasoline $135 OCT2 7.77% wt. ETOH / RFA Gasoline $135 OCT3 RFA Gasoline $135

Benzene Check Standards

Standards are packaged in 20 ml ampoules and can be custom made to any specification. Catalog # Product Price (Set of 5) IRQC 12 1.0% LV Benzene, 5% LV Toluene / Isooctane $100 IRQC 13 1.3% LV Benzene / Isooctane $100 IRQC 14 0.8% LV Benzene, 8% LV Ethanol / Isooctane $100 IRQC 15 1.3% LV Benzene, 10% LV Ethanol / Isooctane $100

CALIBRATION STANDARDS FOR INFRARED ANALYZERS

12



This mixture for ASTM Methods D6729, D6730, D6733 and D5134, can be used to determine retention times, indices and response factors for components of complex mixtures. Nominal values of each component are listed. Mixtures are supplied in 2 ml flame sealed ampoules under a nitrogen blanket. Weights are reported as percentages and in grams. PIANO Standard

N-Pentane 2.3% Benzene 2.3% N-Hexane 2.4% Toluene 2.4% N-Heptane 2.4% Ethylbenzene 2.4% N-Octane 2.4% p-Xylene 3.3% N-Nonane 2.4% Propylbenzene 3.3% N-Decane 2.4% Cumene 1.8% N-Undecane 2.4% 3-Ethyltoluene 1.9% N-Dodecane 2.4% 1,2,4 Trimethylbenzene 1.7% 1,3,5 Trimethylbenzene 1.4% Isopentane 1.9% n-Butyl Benzene 2.4% 2-Methyl Pentane 1.7% Iso-Butylbenzene 2.2% 3-Methylpentane 1.7% 1,2,4,5 Tetramethylbenzene 1.2% 2,2 Dimethylpentane 1.6% n-Pentylbenzene 2.4% 2,3 Dimethylpentane 1.8% 2,4 Dimethylpentane 1.8% 1-Pentene 2.2% 2,2,4 Trimethylpentane 2.2% 1-Hexene 2.4% 2,3 Dimethyl-2-Butene 2.4% Cyclohexane 2.4% 1-Heptene 2.0% Methylcyclohexane 2.4% 2,3,3 Trimethyl-1-Butene 1.1% Ethylcyclohexane 2.4% 1-Octene 2.4% Propylcyclohexane 2.4% 2-Methyl-1-Heptene 1.3% N-Butylcyclohexane 2.4% 1-Nonene 2.4% N-Pentylcyclohexane 2.4% 1-Decene 2.4% Decalin 1.9% 1-Undecene 2.4% 1-Dodecene 2.4% Catalog # Product Price PIANO-1 1 x 1ml $130 PIANO-10 10 x 1ml $1,100 *This material will be sealed with 1ml of material inside a 2ml ampoule.

PIANO STANDARD

13



PIANO Paraffins Standard

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Paraffins Standard: Component CAS Number Concentration Wt. % N-Pentane 109-66-0 9.3805 N-Hexane 110-54-3 9.5081 N-Heptane 142-82-5 9.7762 N-Octane 111-65-9 9.5445 N-Nonane 111-84-2 9.0422 N-Decane 124-18-5 9.2452 N-Undecane 1120-21-4 9.3129 N-Dodecane 112-40-3 9.4040 N-Tridecane 629-50-5 8.9068 N-Tetradecane 629-59-4 8.7923 N-Pentadecane 629-62-9 7.0875 Catalog # Product Price PIANO-P PIANO Paraffins Standard - 1ml $220 *This material will be sealed with 1ml of material inside a 2ml ampoule.

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Paraffins Standard: Component CAS Number Concentration Wt. % N-Pentane 109-66-0 9.3805 N-Hexane 110-54-3 9.5081 N-Heptane 142-82-5 9.7762 N-Octane 111-65-9 9.5445 N-Nonane 111-84-2 9.0422 N-Decane 124-18-5 9.2452 N-Undecane 1120-21-4 9.3129 N-Dodecane 112-40-3 9.4040 N-Tridecane 629-50-5 8.9068 N-Tetradecane 629-59-4 8.7923 N-Pentadecane 629-62-9 7.0875 Catalog # Product Price PIANO-P PIANO Paraffins Standard - 1ml $200

14

PIANO STANDARDS


To order, Call 281-578-7575, Fax 281-578-7576 or visit our

Web site: www.spectrumstandards.com

PIANO Isoparaffins Standard

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Isoparaffins Standard: Component CAS Number Concentration Wt. % Isopentane 78-78-4 2.1598 2,3-Dimethylbutane 79-29-8 0.4426 2-Methylpentane 107-83-5 3.2231 3-Methylpentane 96-14-0 5.2986 2,2-Dimethylpentane 590-35-2 1.7590 2,4-Dimethylpentane 108-08-7 3.6384 2,2,3-Trimethylbutane 464-06-2 3.8709 3,3-Dimethylpentane 562-49-2 1.8405 2-Methylhexane 591-76-4 2.3337 2,3-Dimethylpentane 565-59-3 1.7623 3-Methylhexane 589-34-4 1.5852 3-Ethylpentane 617-78-7 0.5205 2,2-Dimethylhexane ND 1.2986 2,5-Dimethylhexane 592-13-2 3.6687 2,2,3-Trimethylpentane 564-02-3 1.7026 2,4-Dimethylhexane 589-43-5 1.6285 2,3-Dimethylhexane 584-94-1 1.5967 2-Methylheptane 592-27-8 4.3203 4-Methylheptane 589-53-7 3.1640 3-Methylheptane 589-81-1 5.3850 3-Ethylhexane 589-34-4 0.7031 3,3-Dimethylheptane ND 1.6595 2,5-Dimethylheptane ND 5.5593 3,5-Dimethylheptane ND 0.7489 2,3-Dimethylheptane 3074-71-3 1.4660 3,4-Dimethylheptane ND 3.6314 2-Methyloctane ND 3.7096 3-Methyloctane ND 5.5379 3,3-Diethylpentane ND 1.5530 2,2-Dimethyloctane ND 3.2185 3,3-Dimethyloctane ND 3.1402 2,3-Dimethyloctane ND 3.7968 3-Ethyloctane ND 3.6480 2-Methylnonane 871-83-0 3.6687 3-Methylnonane ND 5.6948 Catalog # Product Price PIANO-I PIANO Isoparaffins Standard - 0.1ml $230 *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

PIANO STANDARDS

15




PIANO Aromatics Standard

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Aromatics Standard: Component CAS Number Concentration Wt. % Benzene 71-43-2 7.03127 Toluene 108-88-3 4.5064 EthylBenzene 100-41-4 6.6590 m-Xylene 108-38-3 2.2344 p-Xylene 106-42-3 4.7388 o-Xylene 95-47-6 2.2236 Isopropylbenzene 98-82-8 2.1898 n-Propylbenzene 103-65-1 4.4891 1-Methyl-3-ethylbenzene 620-14-4 2.1676 1-Methyl-4-ethylbenzene 622-96-8 2.1352 1,3,5-Trimethylbenzene 108-67-8 1.1092 1-Methyl-2-ethylbenzene 611-14-3 2.2158 1,2,4-Trimethylbenzene 95-63-6 2.4987 tert-Butylbenzene 98-06-6 4.5264 Isobutylbenzene 538-93-2 4.3482 sec-Butylbenzene 135-98-8 2.2168 1-Methyl-3-isopropylbenzene 535-77-3 1.0917 1-Methyl-4-isopropylbenzene 99-87-6 1.0547 1-Methyl-2-isopropylbenzene 527-84-4 1.1096 1-Methyl-3-n-propylbenzene 1074-43-7 2.0801 1-Methyl-4-n-propylbenzene 1074-55-1 2.1910 n-Butylbenzene 104-51-8 2.1747 1,2-Diethylbenzene 135-01-3 1.0781 1-Methyl-2-n-propylbenzene 1074-17-5 2.2098 1,4-Dimethyl-2-ethylbenzene 1758-88-9 2.2502 1,3-Dimethyl-5-ethylbenzene 934-74-7 2.1652 1,2-Dimethyl-4-ethylbenzene 934-80-5 2.2212 1,3-Dimethyl-2-ethylbenzene 2870-04-4 1.1274 1,2-Dimethyl-3-ethylbenzene 933-98-2 2.1549 1,2,4,5-Tetramethylbenzene 95-93-2 0.2359 2-Methylbutylbenzene ND 1.1258 trans-1-Butyl-1-2-methylbenzene ND 0.7571 n-Pentylbenzene 538-68-1 4.4008 t-1-Butyl-1,3,5-dimethylbenzene ND 2.1295 t-1-butyl-ethylbenzene ND 2.2036 1,3,5-Triethylbenzene 102-25-0 4.4823 1,2,4-Triethylbenzene 877-44-1 1.0960 n-Hexylbenzene 1077-16-3 4.4206 Catalog # Product Price PIANO-A PIANO Aromatics Standard - 0.1ml $230 *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

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PIANO STANDARDS



PIANO STANDARDS

PIANO Naphthalene Standard

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Napthalene Standard: Component CAS Number Concentration Wt. % Cyclopentane 287-92-3 4.8876 Methylcyclopentane 96-37-7 3.2154 Cyclohexane 110-82-7 5.3106 1,1-Dimethylcyclopentane 1638-26-2 3.4257 cis-1,3-Dimethylcyclopentane 2532-58-3 0.5945 trans-1,2-Dimethylcyclopentane 2452-99-5 1.4437 trans-1,3-Dimethylcyclopentane 2453-00-1 2.7038 Methylcyclohexane 108-87-2 5.6166 Ethylcyclopentane 1640-89-7 3.5158 ctc-1,2,3-Trimethylcyclopentane 19374-46-0 1.5596 cct-1,2,4-Trimethylcyclopentane ND 3.6982 ctc-1,2,4-Trimethylcyclopentane 16883-48-0 1.6450 trans-1,4-Dimethylcyclohexane 27195-67-1 3.4980 1-Ethyl-1-methylcyclopentane ND 1.0582 trans-1,2-Dimethylcyclohexane 27195-67-1 1.6415 ccc-1,2,3-Trimethylcyclopentane 2613-69-6 0.7945 Isopropylcyclopentane 3875-51-2 3.4532 cis-1,2-Dimethylcyclohexane 27195-67-1 3.6636 n-Propylcyclopentane 2040-96-2 3.6166 ccc-1,3,5-Trimethylcyclohexane 1795-27-3 3.4996 1,1,4-Trimethylcyclohexane ND 3.6194 ctt-1,2,4-Trimethylcyclohexane 7667-60-9 3.5740 ctc-1,2,4-Trimethylcyclohexane 7667-59-6 3.4826 1,1,2-Trimethylcyclohexane ND 3.3152 Isobutylcyclopentane 3788-32-7 3.6658 Isopropylcyclohexane 696-29-7 5.6751 n-Butylcyclopentane 2040-95-1 3.6624 Isobutylcyclohexane 1678-98-4 5.5462 t-1-Methyl-2-propylcyclohexane ND 3.8141 t-1-Methyl-2-(4MP)cyclopentane ND 3.7326 Catalog # Product Price PIANO-N PIANO Napthalene Standard - 0.1ml $230 *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

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To order, Call 281-578-7575, Fax 281-578-7576 or visit our Web site: www.spectrumstandards.com 18

PIANO STANDARDS

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Olefins Standard: Component CAS Number Concentration Wt.% 3-Methyl-1-butene 563-45-1 1.9608% 1-Pentene 109-67-1 4.0999% 2-Methyl-1-butene 563-46-2 1.4268% 2-Methyl-1, 3-butadiene 78-79-5 2.4036% trans-2-Pentene 646-04-8 1.7990% cis-2-Pentene 627-20-3 1.9683% 4-Methylpentene-1 691-37-2 3.3837% 1-Hexene 592-41-6 6.9484% trans-2-Hexene 4050-45-7 1.7285% 2-Methylpentene-2 625-27-4 3.3104% cis-2-Hexene 7688-21-3 3.8552% 1-Heptene 592-76-7 7.4930% trans-3-Heptene ND 3.6247% cis-3-Heptene ND 5.7577% trans-2-Heptene ND 3.6684% cis-2-Heptene ND 5.6638% 1-Octene 111-66-0 7.5936% trans-2-Octene ND 1.9463% cis-2-Octene 7642-04-8 3.8744% 1-Nonene 124-11-8 7.5680% trans-3-Nonene ND 1.8292% cis-3-Nonene ND 3.9639% trans-2-Nonene ND 1.8292% cis-2-Nonene ND 2.7013% 1-Decene 872-05-9 8.0821% Catalog # Product Price PIANO-O PIANO Olefins Standard - 0.1ml $230 *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

PIANO Olefins Standard


1-Butene 2.6% Methanol 2.7% 1-Pentene 2.5% Ethanol 2.7% 1-Hexene 2.7% tert-Butyl Methyl Ether 2.7% 1-Heptene 2.7% tert-Amyl Methyl Ether 2.7% 1-Octene 2.7% tert-Butanol 2.7% 1-Nonene 2.7% tert-Butyl Ethyl Ether 2.7% 1-Decene 2.7% 1-Undecene 2.7% Cyclopentane 2.8% 1-Dodecene 2.7% Cyclohexane 2.7% Methylcyclohexane 2.7% N-Propane 0.5% Ethylcyclohexane 2.7% N-Butane 2.5% Propylcyclohexane 2.7% N-Pentane 2.7% n-Butylcyclohexane 2.7% N-Hexane 2.7% N-Heptane 2.7% Benzene 2.7% N-Octane 2.7% Toluene 2.8% N-Nonane 2.7% Ethylbenzene 2.7% N-Decane 2.7% Propylbenzene 2.7% N-Undecane 2.7% N-Butylbenzene 2.7% N-Dodecane 2.7% N-Pentylbenzene 2.7% PONA-1 1 x 1 ml ampoule $120

Catalog # Product Price

PONA-10 10 x 1 ml ampoules $1,100 PONA-7 *Call for more information – Pricing upon request*



All 5 of the PIANO Standards, the PIANO-P, PIANO-I, PIANO-A, PIANO-N and PIANO-O can be combined as well in the following ways. *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

Combined PIANO Standards

Catalog # Product Price PIANO-5 All 5 PIANO Standards combined into 0.1 ml $630 In addition, all 5 individual PIANO Standards can be combined with the PIANO-5 Standard: Catalog # Product Price PIANO-5-SET The PIANO-5 Combined Standard with 5 Individual PIANO Stds $1,320

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PONA STANDARD This mixture can be used to determine retention times, indices and response factors for components of complex mixtures. Nominal values of each component are listed. Mixtures are supplied in 1 ml flame sealed ampoules under a Nitrogen blanket. Weights are reported as percentages and in grams.

PIANO STANDARDS



ASTM D3710 Calibration Mix – Volume / Volume

Spectrum offers Standards covering the Boiling Range Distribution of Gasoline and Gasoline components. Calibration mixes are either in weight / weight or volume / volume. 2-Methylbutane 10.5% p-Xylene 14.0% N-Pentane 8.1% n-Propylbenzene 4.7% 2-Methylpentane 5.8% n-Decane 3.5% N-Hexane 5.8% n-Butylbenzene 3.5% 2,4-Dimethylpentane 5.8% n-Dodecane 3.5% N-Heptane 10.5% n-Tridecane 2.3% Toluene 11.6% n-Tetradecane 2.3% N-Octane 5.8% n-Pentadecane 2.3% Catalog # Product Price / Set of 10 x 1 ml 3710-1 ASTM D3710 Calibration Set $130

ASTM D6352 Calibration Mixture

Spectrum offers Standards covering the Boiling Range Distribution of Petroleum Distillate Fractions. They are applicable to fractions having an initial boiling point greater than 174 C to a final boiling point of less than 700 C. Calibration Mixes are Polywax 655 or 1000 dissolved in Carbon Disulfide at a concentration of 1 part to 200 parts. Lower Boiling Point n-Paraffins (nominally C10 to C40) are added. The Calibration Mixture covers the range of n-Paraffins from C10 to C100. Catalog # Product Price 6352REF Reference Oil per 4 oz bottle $135

ASTM 7169 Calibration Mixture

Catalog # Product Price_____ POLY655/1000 Polywax 655/1000 per 1.1 ml $110

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SIMDIS ANALYSIS



High Temperature SIMDIS

This Standard can be used to estimate the amount of engine oil volatilized at 371 C in accordance with ASTM D6417. Standards are packaged in 2 ml ampoules, concentrations are weight / weight. N-Octane 0.042% Eicosane 0.043% N-Nonane 0.042% N-Tricosane 0.043% N-Decane 0.043% N-Octacosane 0.042% N-Undecane 0.043% N-Dotriacontane 0.043% N-Dodecane 0.042% N-Tetratriacontane 0.042% N-Tridecane 0.043% N-Hexatriacontane 0.043% N-Tetradecane 0.042% N-Tetracontane 0.041% N-Pentadecane 0.042% N-Tetratetracontane 0.022% N-Hexadecane 0.043% N-Pentacontane 0.022% N-Heptadecane 0.043% N-Dopentacontane 0.020% N-Octadecane 0.042% N-Hexacontane 0.021% N-Nonadecane 0.043% In Carbon Disulfide / Cyclohexane Catalog # Product Price / Set of 10 x 1 ml 6417-1 ASTM D6417 Calibration Set $175

Quantitative Alkylate Reference Sample

The Standard is a well characterized sample of an actual refinery Alkylation Stream. It can be used to determine retention times, indices and monitor response factors of complex hydrocarbon mixtures. The Standard includes a data sheet listing individual components by weight %, mole % and liquid volume %; retention times and indices for each component; composition by carbon; a calculated boiling point and octane report. A summary of the group types is listed below: GROUP TYPE % Weight % Volume %Mole Aromatics 1.85 1.47 1.51 I-Paraffins 90.23 90.04 87.07 Napthalenes 0.68 0.60 0.59 Olefins 0.013 0.013 0.014 Paraffin 5.02 6.02 9.16 Oxygenates 0.0 0.0 0.0 Unidentified 2.22 1.86 1.65 Catalog # Product Price / 10 x 1 ml ALK-1 Alkylate Reference Standard $70

SIMDIS ANALYSIS

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ASTM D2887 Calibration Mix – Weight/Weight

n-Hexane 6.0% n-Octadecane 5.0% n-Heptane 6.0% n-Eicosane 2.0% n-Octane 8.0% n-Tetracosane 2.0% n-Nonane 8.0% n-Octacosane 1.0% n-Decane 12.0% n-Dotriacontane 1.0% n-Undecane 12.0% n-Hexatriacontane 1.0% n-Dodecane 12.0% n-Tetracontane 1.0% n-Tetradecane 12.0% n-Tetrateteracontane 1.0% n-Hexadecane 10.0% Catalog # Product Price / Set of 10 x 1 ml 2887-1 ASTM D2887 Calibration Set C6-C44 $140 n-Pentane 4.03% n-Hexadecane 8.92% n-Hexane 4.94% Eicosane 1.99% n-Heptane 4.93% n-Tetracosane 1.96% n-Octane 7.87% n-Octacosane 0.998% n-Nonane 8.14% n-Dotriacontane 1.01% n-Decane 11.90% n-Hexatricontane 0.969% n-Undecane 11.88% n-Tetracontane 0.979% n-Dodecane 11.88% n-Tetratetracontane 0.983% n-Tetradecane 11.91% n-Octadecane 3.93% Other Impurities 0.80% Catalog # Product Price / Set of 10 x 1 ml 2887-1P ASTM D2887 Calibration Set C5-C44 $140 n-Pentane 5.22% n-Octadecane 3.99% n-Hexane 4.97% n-Tetracosane 0.981% n-Heptane 5.96% n-Octacosane 0.990% n-Octane 7.89% n-Dotriacontane 0.989% n-Nonane 8.05% n-Hexatricontane 0.970% n-Decane 11.88% n-Tetracontane 0.982% n-Undecane 11.75% n-Tetratetracontane 0.979% n-Dodecane 11.89% n-Pentacontane 0.492% n-Tetradecane 11.82% n-Hexacontane 0.491% n-Hexadecane 7.88% Eicosane 1.05% Other Impurities 0.78% Catalog # Product Price / Set of 10 x 1 ml 2887-EXT-1 ASTM D2887 Calibration Set - Extended $140

SIMDIS ANALYSIS

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REFERENCE GAS OIL

Reference Gas Oil for ASTM D2887

Spectrum now offers Reference Gas Oil for D2887 from Global Reference Standards. Reference Gas Oil #2 Lot #1 has been approved by ASTM and is now available for purchase. Catalog # Product Price / per bottle GRS-RGO-QT REFERENCE GAS OIL #2 LOT #1 MADE BY GRS - QT $4,800 GRS-RGO2-2 REFERENCE GAS OIL #2 LOT #1 MADE BY GRS - 2 OZ $420

BENZENE PURITY STANDARD

Spectrum offers two Standards meeting ASTM D5713 and D4492 requirements. Calibration mixtures have the appropriate internal standard added and are also available without internal standard.

ASTM D5713 Calibration Mix – Weight / Weight

Iso-Pentane 100 ppm cis 1,3 Dimethylcyclopentane 100 ppm N-Pentane 100 ppm trans 1,3 Dimethylcyclopentane 100 ppm 2,2 Dimethylbutane 100 ppm Heptane 200 ppm Cyclopentane 100 ppm Methylcyclohexane 100 ppm 2,3 Dimethylbutane 100 ppm Ethylcyclopentane 50 ppm 2 Methylpentane 200 ppm 2,4 Dimethylhexane 100 ppm 3 Methylpentane 200 ppm 1,2,3 Trimethylcyclopentane 50 ppm n-Hexane 300 ppm 2,3,4 Trimethylpentane 50 ppm 2,2 Dimethylpentane 100 ppm Methylcyclopentane 200 ppm Toluene 50 ppm 2,4 Dimethylpentane 100 ppm Ethylbenzene 100 ppm 2,2,3 Trimethylbutane 100 ppm p-Xylene 100 ppm 3,3 Dimethylpentane 50 ppm m-Xylene 100 ppm Cyclohexane 100 ppm Cumene 100 ppm 2-Methylhexane 100 ppm o-Xylene 100 ppm 2,3 Dimethylpentane 100 ppm Benzene Balance 1,1 Dimethylcyclopentane 100 ppm 3 Methylhexane 100 ppm Internal Standard - n-Octane 10,000 ppm wt. Catalog # Product Price per 1 ml 5713-WISTD D5713 Calibration with Internal Standard $90 5713-noISTD D5713 Calibration without Internal Standard $90

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ASTM D4492 Calibration Mix – Weight / Weight

The Calibration Mixture has the same composition as the D5713 Mixture; however, n-Nonane has been added as the Internal Standard at 1000 ppm wt. Catalog # Product Price per 1 ml 4492-WISTD D4492 Calibration with Internal Standard $90 4492-noISTD D4492 Calibration without Internal Standard $90 *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

BENZENE STANDARDS – ASTM D3606

The EPA has identified Benzene as a major pollutant in Reformulated Gasoline and has designated ASTM Method D3606 for its determination. We offer a set of Calibration Standards meeting all ASTM requirements and are composed of seven individual standards in an Isooctane Matrix. The Standards are packaged in 2ml ampoules and are available with either MEK, 2-Butanol or DME as the Internal Standard. The Standards are NIST Traceable by weight.

ASTM D3606 Calibration Set

Std # Benzene % LV Toluene % LV Internal Standard 1 5.0 20 +4%LV 2 2.5 15 +4%LV 3 1.25 10 +4%LV 4 0.65 5 +4%LV 5 0.33 2.5 +4%LV 6 0.12 1.0 +4%LV 7 0.06 0.5 +4%LV Calibration Standards with the following Internal Standards are available: Catalog # Product Internal Standard Price 3606M Calibration Set +4% LV MEK $220 3606B Calibration Set +4% LV 2-Butanol $220 3606D Calibration Set +4% LV DME $220 3606N Calibration Set No Internal Standard $220 Additionally, as Ethanol elutes with Benzene, we offer a Calibration Set containing Ethanol. Catalog # Product Internal Standard Price 3606EM10 Calibration Set - 10% Ethanol +4% LV MEK $240 3606EB10 Calibration Set – 10% Ethanol +4% LV 2-Butanol $240 3606EB6 Calibration Set – 6% Ethanol +4% LV 2-Butanol $240 3606EN5 Calibration Set – 5.77% Ethanol No Internal Standard $240 3606EN7 Calibration Set – 7.77% Ethanol No Internal Standard $240 3606EN10 Calibration Set – 10.0% Ethanol No Internal Standard $240

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BENZENE PURITY STANDARD



D3606 Check Standards

Accuracy of the Calibration can be monitored daily by the use of Check Standards. We offer the following mixtures: Catalog # Benzene Toluene Ethanol Internal Std. Price/Set of 10 3606DBE-(#of days) 1.0 5.0 10.0 +4% 2-Butanol $130 3606D2B-(#of days) 0.50 3.0 ------- +4% 2-Butanol $130 3606D3B-(#of days) 1.0 5.0 ------- +4% 2-Butanol $130 3606DME-(#of days) 1.0 5.0 10.0 +4% MEK $130 3606D5M-(#of days) 1.0 5.0 ------- +4% MEK $130 3606D6M-(#of days) 0.50 3.0 ------- +4% MEK $130 3606DM-(#of days) 1.0 5.0 ------- +4% DME $130 3606DN-(#of days) 1.0 5.0 ------- No Internal Std. $130 *We also offer Check Standards in 30, 60, 90 and 180 day supplies at the following prices: Product Price: D3606 Daily Check Standard – 60 day set $700 D3606 Daily Check Standard – 180 day set $1,710 *Custom Calibration Standard sets and Check Standards are available. Call for details.

AROMATIC STANDARDS

ASTM D5769 Quality Control Reference Material

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Check Standards are available with or without Deuterated Internal Standard mixtures. All concentrations are in weight %. Hexane -12% Toluene -9% Heptane -17% 1,3 Dimethylbenzene -3% Octane -17% 1,2 Dimethylbenzene -3% Decane -12% Ethylbenzene -3% Dodecane -5% 1,2,4 – Trimethylbenzene -3% Isooctane -12% 1,2,4,5 – Trimethylbenzene -2% Benzene -1% Naphthalene -1% Catalog # Product Price AR1000 Quality Control Reference Material - 3 component – with ISTD $175 [10x2ml] AR3000 Quality Control Reference Material - no Internal Std. $175 [5x10ml] AR4000 Quality Control Reference Material – 4 component – with ISTD $175 [10x2ml]

BENZENE STANDARDS – ASTM D3606




ASTM D5769 Aromatics in Finished Gasolines

Multi-component Calibration Standards are available for the current version of this Method with or without the 3-Component Deuterated Internal Standard mixture. The Internal Standard mixture is in the ratio Benzene-d6 – 2ml, Ethylbenzene-d10 – 2ml and Naphthalene-d8 – 1 gram. The Standards have the following nominal compositions:

Component Std 1 Std 2 Std 3 Std 4 Std 5 Std 6 Wt% Wt% Wt% Wt% Wt% Wt%

Benzene 5.2 4.2 2.9 1.6 0.8 0.40 Toluene 19.6 16.0 11.0 6.0 3.0 1.60 Ethylbenzene 5.2 4.0 2.9 1.6 0.8 0.40 m-Xylene 6.2 5.0 3.5 1.9 0.9 0.40 p-Xylene 6.2 5.0 3.5 1.9 0.9 0.40 o-Xylene 6.3 5.0 3.5 1.9 0.9 0.40 Isopropylbenzene 3.0 2.5 1.7 0.9 0.5 0.40 n-Propylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 3-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 4-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 1,3,5-Trimethylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 2-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 1,2,4-Trimethylbenzene 5.2 4.0 2.9 1.6 0.8 0.25 1,2,3-Trimethylbenzene 3.2 2.5 1.8 1.0 0.5 0.40 Indan 3.5 2.7 1.9 1.0 0.5 0.25 1,4-Diethylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 n-Butylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 1,2-Diethylbenzene 3.0 2.5 1.8 0.9 0.5 0.25 1,2,4,5-Tetramethylbenzene 2.0 1.7 1.2 0.6 0.3 0.25 1,2,3,5-Tetramethylbenzene 2.0 1.7 1.2 0.6 0.3 0.15 Naphthalene 2.5 2.0 1.3 0.7 0.4 0.15 1-Methylnaphthalene 2.5 2.0 1.3 0.7 0.4 0.2 2-Methylnaphthalene 2.4 2.0 1.4 0.7 0.4 0.2 Isooctane Balance

The 3-Component Internal Standard mixture – [Benzene-d6, Ethylbenzene-d10 and Naphthalene-d8] is added to the Calibration Standards in the ratio of 5 parts Internal Standard mixture to 100 parts weight Calibration Standard. Catalog # Product Price 5769CAL-3ISTD Calibration Set with 3 Internal Standards $520 (6x1ml) 5769CAL-5noISTD Calibration Set without Internal Standard $1750 (6x5ml) 5769CAL-10noISTD Calibration Set without Internal Standard $3400 (6x10ml)

AROMATIC STANDARDS

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ASTM D5769 Aromatics in Finished Gasolines

Multi-Component Calibration Standards are available for the current version of this Method with the 4-Component Deuterated Internal Standard Mixture. The Internal Standard mixture is in the ratio Benzene-d6 - 2ml, Ethylbenzene-d10 - 2ml, Naphthalene-d8 – 1 gram and Toluene-d8 – 7ml. The Standards have the following nominal compositions:

Component Std 1 Std 2 Std 3 Std 4 Std 5 Std 6 Wt% Wt% Wt% Wt% Wt% Wt%

Benzene 5.2 4.2 2.9 1.6 0.8 0.40 Toluene 19.6 16.0 11.0 6.0 3.0 1.60 Ethylbenzene 5.2 4.0 2.9 1.6 0.8 0.40 m-Xylene 6.2 5.0 3.5 1.9 0.9 0.40 p-Xylene 6.2 5.0 3.5 1.9 0.9 0.40 o-Xylene 6.3 5.0 3.5 1.9 0.9 0.40 Isopropylbenzene 3.0 2.5 1.7 0.9 0.5 0.40 n-Propylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 3-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 4-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 1,3,5-Trimethylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 2-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 1,2,4-Trimethylbenzene 5.2 4.0 2.9 1.6 0.8 0.25 1,2,3-Trimethylbenzene 3.2 2.5 1.8 1.0 0.5 0.40 Indan 3.5 2.7 1.9 1.0 0.5 0.25 1,4-Diethylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 n-Butylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 1,2-Diethylbenzene 3.0 2.5 1.8 0.9 0.5 0.25 1,2,4,5-Tetramethylbenzene 2.0 1.7 1.2 0.6 0.3 0.25 1,2,3,5-Tetramethylbenzene 2.0 1.7 1.2 0.6 0.3 0.15 Naphthalene 2.5 2.0 1.3 0.7 0.4 0.15 1-Methylnaphthalene 2.5 2.0 1.3 0.7 0.4 0.2 2-Methylnaphthalene 2.4 2.0 1.4 0.7 0.4 0.2 Isooctane Balance

The 4-Component Internal Standard mixture, [Benzene-d6, Ethylbenzene-d10, Toluene-d8 and Naphthalene-d8] is added to the Calibration Standards in the ratio of 12 parts Internal Standard mixture to 100 parts weight Calibration Standard. Catalog # Product Price 5769CAL-4ISTD Calibration Set with 4 Internal Standards $580 (6x1ml) 5769CAL-5noISTD Calibration Set without Internal Standard $1,750 (6x5ml) 5769CAL-10noISTD Calibration Set without Internal Standard $3,400 (6x10ml)

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AROMATIC STANDARDS



ASTM D5769 Internal Standards for GC/MS

Internal Standards are available containing Deuterated Ethylbenzene-d10, Naphthalene-d8 and Benzene-d6 as specified in the ASTM Method for the determination of Benzene, Toluene and Total Aromatics in Finished Gasoline by GC/MS. The Internal Standard, used for the sample preparation, is packaged in 5ml flame sealed ampoules and has the following composition:

Benzene-d6 2ml Ethylbenzene-d10 2ml

Naphthalene-d8 1 gram

Catalog # Product Price 5769INT-1 Internal Standard 1x5ml ampoules $155 5769INT-5 Internal Standard 5x5ml ampoules $600 The Internal Standard can also be custom packaged to your specifications. ASTM D5769 Internal Standards for GC/MS with Toluene d8

Internal Standard containing Deuterated Ethylbenzene-d10, Naphthalene-d8, Benzene-d6 and Toluene-d8 as specified in the ASTM Method. The Internal Standard used for the sample preparation is packaged in 10ml flame sealed ampoules and has the following composition:

Benzene-d6 2ml Ethylbenzene-d10 2ml

Naphthalene-d8 1 gram Toluene-d8 7ml

Catalog # Product Price 5769INT-T-1 Internal Standard including Toluene-d8 1x10ml ampoule $240 5769INT-T-5 Internal Standard including Toluene-d8 5x10ml ampoules $1100 The Internal Standard can also be custom packaged to your specifications.

AROMATIC STANDARDS

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ASTM D6550 Olefins in Gasoline by SFC

The Method Covers the determination of the total Olefin content of Gasolines by Super-Critical Chromatography (SFC). The application range is 1 to 25% weight total Olefins. We offer two sets of Standards; one is a set of Synthetic Olefins mixtures and the other a set of Gasoline Standards analyzed by consensus analysis. The following Standards are available packaged in 2 ml flame sealed ampoules. Catalog # Product Price 6550CAL-S Calibration Set 1.0, 3.5, 6.0, 8.5, 12.0 % wt. $155 6550CAL-H Calibration Set 12.0, 17.0, 25.0 % wt. $155 6550CAL-X Calibration Set 1.0, 3.5, 6.0, 8.5, 12.0, 17.0, 25.0 % wt. $290 6550CK Check Standard 4.0% wt. Total Olefins [set of 10] $120 The Olefin Standards are made in a Matrix of 75% wt. Isooctane and 25% wt. Toluene [75/25 ISO/TOL]. Catalog # Product Price 6550REF Reference Check Standard 10.0% wt. Total Olefins $120 The Reference Standards are made in a Gasoline Matrix and analyzed by consensus analysis. Standards can also be made to your specifications.

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OLEFINS STANDARDS



The Air Resources Board of California requires Finished Gasoline to be tested for Total Aromatics using ASTM Method D5580. This Method covers the determination of Benzene, Toluene, Ethylbenzene, Xylenes, C9 and heavier Aromatics, and Total Aromatics. The Internal Standard is 2-Hexanone. The Standards conform to ASTM D5580 and are NIST traceable by weight. We offer a Multi-Component Calibration Standard, Selectivity, Valve Timing and a Daily Check Standard with the following composition.

ASTM D5580 Aromatic Calibration Set

Nominal Liquid Volume % Std # Benzene Toluene Ethylbenzene O-Xylene 1,2,4-TMB 2-Hexanone Isooctane 1 0.10 15.0 0.50 5.0 0.50 10.0 Balance 2 0.50 5.0 1.0 1.0 10.0 10.0 Balance 3 1.0 10.0 2.5 2.5 2.5 10.0 Balance 4 2.0 2.5 5.0 10.0 1.0 10.0 Balance 5 5.0 1.0 10.0 0.50 5.0 10.0 Balance Daily Ck 1.0 10.0 4.0 4.0 4.0 10.0 Balance Valve Ck 5.0 5.0 5.0 5.0 5.0 10.0 Balance Catalog # Product Price 5580CAL Calibration set includes Selectivity and Valve Timing $150 5580CAL-E Calibration set includes Ethanol $165 5580CAL-Px Calibration set includes 0.5 – 10% LV p-Xylene $160 5580CAL-N Calibration set without Internal Standard – 20ml ampoules $170 5580DCK Daily Check Standard Set of 10 $120 5580DCK-60 Daily Check Standard 60 day set $630 5580DCK-D Daily Check Standard includes Dodecane $160 5580SEL Selectivity Standard Set of 10 $120 5580VT Valve Timing Standard Set of 10 $120

ASTM D1319 Aromatics and Olefins by FIA

Difficulties with the precision and accuracy of this important test have led to the introduction of a Standard providing a baseline for comparison when used on a regular basis. The Standards are supplied in 2ml ampoules and have the following composition:

Toluene 30% LV 1-Hexene 10% LV

Isooctane Balance Catalog # Product Price FIA 1000 FIA Daily Check Standard 10x2ml ampoules $130 CALFIA California Phase II Gasoline 10x2ml ampoules $130 FIA1000-CY FIA 1000 Standard in 800 CC Cylinder $630/each

AROMATIC STANDARDS

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ASTM D5186 Aromatics in Diesel and Aviation Fuels

The analysis of Motor Diesel and Aviation Fuels by Supercritical Fluid Chromatography (ASTM D5186) requires the use of a performance mixture. We supply two such mixtures meeting high and low specifications. The mixtures are supplied in 2ml flame sealed ampoules under a Nitrogen atmosphere.

ASTM D5186 Performance Mixture

Component % Weight (HIGH) % Weight (LOW) Tetralin 3.0 1.0 Naphthalene 2.0 1.0 Toluene 20.0 8.0 Hexadecane 75.0 90.0 Catalog # Product Price / Set of 10 5186-10 Low Concentration $130 5186-25 High Concentration $130 ASTM D5186 Calibration Set

An Inter-Laboratory study was conducted using Diesel Fuel. A total of 11 Refinery and Independent Laboratories analyzed the Standards for both Total Aromatics and Poly-Nuclear Aromatics and the results were statistically analyzed. The standards are packaged in 2ml glass ampoules under a Nitrogen atmosphere. The means are tabulated below:

LOW RANGE

Standard # Total Aromatics Poly-Nuclear Aromatics 1 2.06 % wt 0.23 % wt 2 5.64 % wt 0.89 % wt 3 11.0 % wt 2.06 % wt 4 14.6 % wt 2.50 % wt 5 21.6 % wt 4.31 % wt

HIGH RANGE

Standard # Total Aromatics Poly-Nuclear Aromatics 1 14.6 % wt 2.50 % wt 2 21.6 % wt 4.44 % wt 3 26.6 % wt 6.00 % wt 4 32.6 % wt 7.50 % wt 5 38.6 % wt 11.8 % wt

Catalog # Product Price/ per set 5186CAL HI 5186 Calibration Set – Hi Range $130 5186CAL LO 5186 Calibration Set – Lo Range $130

AROMATIC STANDARDS

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Aromatic Standards for UOP Methods

The following standards for UOP Methods for Trace Impurities in Aromatic Hydrocarbons and are packaged in 2 ml flame sealed ampoules: UOP 720 Impurities in High Purity P-Xylene

UOP 744 Aromatics in Hydrocarbons

The Standard contains n-Heptane, Benzene, Toluene, Mixed Xylene, 1-Methyl-2-Ethylbenzene and 1,2,3,4,-Tetramethylbenzene at concentrations 10 – 25 % wt. Catalog # Product Price / Set of 10 UOP744 Aromatics in Hydrocarbons $120

UOP 931 Impurities in Mixed Xylenes

UOP 831 Hydrocarbons in Sulfolane

The Standard contains Benzene, Toluene, Ethylbenzene, Cumene and n-Nonane in a Sulfolane Matrix at concentrations of 10 ppm wt. Catalog # Product Price / Set of 10 UOP831 Hydrocarbons in Sulfolane $120

UOP 551 Hexanes in Olefin-Free Gasoline

The Standard contains Benzene, Toluene, 1-Methyl-2-Ethylbenzene, n-Undecane in an n-Heptane Matrix at concentrations of 2 % wt. Catalog # Product Price / Set of 10 UOP931 Mixed Xylenes Impurity Standard $120

The Standard contains n-Hexane, Benzene, Toluene, Ethylbenzene, o-Xylene, m-Xylene, p-Xylene at concentrations of approximately 14% wt. Catalog # Product Price / Set of 10 UOP551 Hexanes in Gasoline $120

AROMATIC STANDARDS

The Standards contain o-Xylene, m-Xylene, Ethylbenzene, n-Undecane (ISTD) at concentrations of 0.1 % wt in a p-Xylene Matrix. Catalog # Product Price / Set of 10 UOP720 Xylene Impurity Standard $120

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Aromatic Standards for UOP Methods

UOP 798 Trace p-Diethylbenzene in C8 Aromatics

The Standard contains p-Diethylbenzene and Indane in a p-Xylene Matrix at a concentration of 5 ppm wt. Catalog # Product Price / Set 10 UOP798 Trace p-Diethylbenzene $120

UOP 690 Octanes in Olefin-Free Gasoline

The Standard contains n-Octane, Benzene, Toluene, Ethylbenzene, o-Xylene, m-Xylene and p-Xylene at concentrations of approximately 14% wt. Catalog # Product Price / Set of 10 UOP690 Octanes in Gasoline $110

UOP 868 Trace Saturates in High Purity Aromatics

The Standard contains Cyclohexane, n-Hexane, Methylcyclohexane, N-Heptane, Ethylcyclohexane, n-Octane, Propylcyclohexane, n-Nonane, Butylcyclohexane, n-Decane in a Toluene Matrix at a concentration of 500 ppm wt. Catalog # Product Price / Set of 10 UOP868 Saturates in Gasoline $110 UOP 880 Distillate Reformer and Reformate Standards

Catalog # Product __ Price____ UOP880-RFRMR Reformer Standard - 10 x 2 ml ampoules $290 UOP880-RFRMR-4 Reformer Standard – 4 oz. bottle $450 UOP880-RFRMT Reformate Standard – 10 x 2 ml $220 UOP880-RFRMT-4 Reformate Standard – 4 oz. bottle $400

AROMATIC STANDARDS

33



UOP 621 Non-Aromatic Hydrocarbons in High-Purity Aromatics by Gas Chromatography


The Standard contains Pentane; N-Hexane; Heptane; Methylcyclohexane; N-Octane; Ethylcyclohexane; Nonane; Indan; N-Decane; Benzene; Toluene; P-xylene and Cumene in a concentration ranging from 0.3 %WT to 18.848 %WT.

Catalog # Product Price / Set of 10 UOP 870 Carbon Distribution of Paraffins/Naphthenes Aromatics Std $500

Catalog # Product Price / Set of 10 UOP 621 Boiling Point of Hydrocarbons Standard $345

The Standard contains: Pentane; N-Hexane; Heptane; N-Octane; Nonane; N-Decane; Undecane; Dodecane; Tridecane; Tetradecane; Pentadecane; Hexadecane; Heptadecane; Octadecane; Nonadecane and Eicosane in a concentration of approximately 6 % WT.

The Standard contains N-Dodecane in a Toluene Matrix. Catalog # Product Price / Set of 10 UOP543-RF Non-Aromatic Hydrocarbons Response Factor Standard $110

UOP 543 Non-Aromatic Hydrocarbons Response Factor Standard


The Standard contains Undecane, Benzene and Toluene in a P-xylene matrix, in a concentration of approximately 100 PPM and packaged in 2ml flame sealed ampoules. Catalog # Product Price / Set of 10 UOP543-IMP Non-Aromatic Hydrocarbon Standard $110

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NON-AROMATIC HYDROCARBON STANDARDS



ASTM D7371 Biodiesel Standards

ASTM D7371 is used to determine the biodiesel content in Diesel fuel by Furrier Transfer Infrared (FTIR). We offer the following Calibration Standards and Daily Check Standards, packaged in 5ml ampoules.

D7371 Low Calibration Set A D7371 Low Calibration Set B

Biodiesel [vol%] Solvent Biodiesel [vol%] Solvent 0.00 DCCF-Low 10.00 DCCF-Low 0.25 DCCF-Low 12.50 DCCF-Low 0.50 DCCF-Low 15.00 DCCF-Low 1.00 DCCF-Low 17.50 DCCF-Low 2.50 DCCF-Low 20.00 DCCF-Low 5.00 DCCF-Low 25.00 DCCF-Low 7.50 DCCF-Low 30.00 DCCF-Low 10.00 DCCF-Low

Set A, Mixtures 1-8 Set B, Mixtures 8-14

Catalog # Product Price 7371CAL-L-A D7371 Low Calibration Standard – Set A [0.00-10.00] – 5ml ampoules $175 7371CAL-L-B D7371 Low Calibration Standard – Set B [10.00-30.00] – 5ml ampoules $175

D7371 Low Calibration Set C

Biodiesel [vol%] Solvent 30.00 DCCF-Low 50.00 DCCF-Low 70.00 DCCF-Low 80.00 DCCF-Low 90.00 DCCF-Low 95.00 DCCF-Low 97.00 DCCF-Low 99.00 DCCF-Low 99.80 DCCF-Low

Set C, Mixtures 14-22

Catalog # Product Price 7371CAL-L-C D7371 Low Calibration Standard – Set C [30.00-99.80] – 5ml ampoules $175 7371DCK-L D7371 Daily Check Standard – Low [*Biodiesel / Solvent] – 10x5ml set $110 7371DCK-H D7371 Daily Check Standard – High [*Biodiesel / Solvent] – 10x5ml set $110 7371DCK-UH D7371 Daily Check Standard – Ultra High [*Biodiesel/Solvent] -10x5ml set $110 *Upon ordering our Daily Check Standards, customer must specify the Biodiesel % and Solvent required.

35

BIODIESEL STANDARDS


To order, Call 281-578-7575, Fax 281-578-7576 or visit our Website: www.spectrumstandards.com


36

BIODIESEL STANDARDS


D7371 High Calibration Set A D7371 High Calibration Set B

Biodiesel [vol%] Solvent Biodiesel [vol%] Solvent 0.00 DCCF-High 10.00 DCCF-High 0.25 DCCF-High 12.50 DCCF-High 0.50 DCCF-High 15.00 DCCF-High 1.00 DCCF-High 17.50 DCCF-High 2.50 DCCF-High 20.00 DCCF-High 5.00 DCCF-High 25.00 DCCF-High 7.50 DCCF-High 30.00 DCCF-High 10.00 DCCF-High


Catalog # Product Price 7371CAL-H-A D7371 High Calibration Standard – Set A [0.00-10.00] – 5ml ampoules $175 7371CAL-H-B D7371 High Calibration Standard – Set B [10.00-30.00] – 5ml ampoules $175

D7371 High Calibration Set C

Biodiesel [vol%] Solvent 30.00 DCCF-High 50.00 DCCF-High 70.00 DCCF-High 80.00 DCCF-High 90.00 DCCF-High 95.00 DCCF-High 97.00 DCCF-High 99.00 DCCF-High 99.80 DCCF-High

Set C, Mixtures 36-44 Catalog # Product Price 7371CAL-H-C D7371 High Calibration Standard – Set C [30.00-99.80] – 5ml ampoules $175


To order, Call 281-578-7575, Fax 281-578-7576 or visit our Website: www.spectrumstandards.com


IP585 Calibration Standards

Catalog # Product Price IP585 IP585 Calibration Standard [2, 4, 6, 8, 10, 20, 40, 60, 80, 100 mg/kg + d33] $700 IP585CAL IP585 Calibration Standard [Up to 5 concentrations][*Background] $525 *Please specify the concentrations and background upon ordering this product.

BIODIESEL STANDARDS


D7371 Ultra High Calibration Set A D7371 Ultra High Calibration Set B

Biodiesel [vol%] Solvent Biodiesel [vol%] Solvent 0.00 DCCF-Ultra High 10.00 DCCF-Ultra High 0.25 DCCF-Ultra High 12.50 DCCF-Ultra High 0.50 DCCF-Ultra High 15.00 DCCF-Ultra High 1.00 DCCF-Ultra High 17.50 DCCF-Ultra High 2.50 DCCF-Ultra High 20.00 DCCF-Ultra High 5.00 DCCF-Ultra High 25.00 DCCF-Ultra High 7.50 DCCF-Ultra High 30.00 DCCF-Ultra High 10.00 DCCF-Ultra High


Catalog # Product Price 7371CAL-UH-A D7371 Ultra High Calibration Standard – Set A [0.00-10.00] – 5ml ampoules $175 7371CAL-UH-B D7371 Ultra High Calibration Standard – Set B [10.00-30.00]– 5ml ampoules $175

D7371 Ultra High Calibration Set C

Biodiesel [vol%] Solvent 30.00 DCCF-Ultra High 50.00 DCCF-Ultra High 70.00 DCCF-Ultra High 80.00 DCCF-Ultra High 90.00 DCCF-Ultra High 95.00 DCCF-Ultra High 97.00 DCCF-Ultra High 99.00 DCCF-Ultra High 99.80 DCCF-Ultra High

Set C, Mixtures 36-44 Catalog # Product Price 7371CAL-H-C D7371 Ultra High Calibration Standard – Set C [30.00-99.80] – 5ml ampoules $175

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Calibration Standards conforming to ASTM D5453 and ASTM D4629 are available in several ranges in an Isooctane or Toluene Matrix. A Check Standard is also available to verify the calibration on a routine basis. All Standards are NIST traceable by weight.

ASTM D5453 Total Sulfur by UV Fluorescence

ASTM Method D5453 is the determination of Sulfur in Liquid Petroleum Hydrocarbons by Ultraviolet Fluorescence. In accordance with the Method, 3 ranges of Calibration Standards are offered in either a Toluene or an Isooctane Matrix and are packaged in 2 ml ampoules. Catalog # Product Price 5453R1 Calibration Set [1, 2.5, 5, 7.5, 10 ng/ul] $90 5453R2 Calibration Set [5, 25, 50, 100, 200 ng/ul] $90 5453R3 Calibration Set [100, 250, 500, 750, 1000 ng/ul] $90 5453X3 Calibration Set including all 3 Ranges $240 5453DCK D5453 Daily Check Standard (Specify Concentration) $85 (set of 10) ASTM D3120, D3246 and D3961 Sulfur by Oxidative Microcoulometry

ASTM D4045 & D6313 Sulfur by Rateometric Colorimetry

NITROGEN AND SULFUR STANDARDS

These Methods use Oxidative Microcoulometry to determine Sulfur. Calibration and Check Standards are available using n-Dibutyl Sulfide in Isooctane. Catalog # Product Price 3120CAL Calibration Set 1, 10, 25, 50, 100 ppm wt. $90 3246CAL Calibration Set 1, 10, 25, 50, 100 ppm wt. $90 3961CAL Calibration Set 1, 10, 25, 50, 100 ppm wt. $90

The Method is used to determine Sulfur in the range 0.1 to 10 ppm wt in Hydrocarbons by Hydrogenolysis and Rateometric Colorimetry. Standards are prepared using n-Dibutyl Sulfide in an Isooctane Matrix and packaged in 2ml flame sealed ampoules. Catalog # Product Price 4045CAL Calibration Set 0.1, 0.5, 1, 2.5, 5.0, 10 ppm wt $90/ per set 4045DCK Daily Check Standard (Specify Concentration) $90/set of 10 6313CAL Calibration Set 0.1, 0.5, 1, 2.5, 5.0, 10 ppm wt $90/ per set 6313DCK Daily Check Standard (Specify Concentration) $80/set of 10

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ASTM D1552 Sulfur by High Temperature Combustion

This Method is used to determine Total Sulfur in Petroleum products including Lubricating Oils. Standards are made with Di-butyl Sulfide in a Mineral Oil Matrix in concentrations from 0.06 to 10% wt Sulfur and packaged in 100 ml bottles. Catalog # Product Price 1552DCK [Specify Concentration] $90

ASTM D6428 Sulfur by Combustion and Electrochemical Detection

ASTM D6069 Trace Nitrogen by Combustion and Electrochemical Detection

This Method covers the determination of Total Nitrogen in Liquid Hydrocarbons and related chemicals. Standards are made with either Pyridine in an Isooctane Matrix or Carbazole in a Toluene Matrix and packaged in 2ml flame sealed ampoules. Catalog # Product Price 6069R1 Calibration Set 0.1, 0.5, 1, 2.5, 5, 10 ppm wt $90 6069R2 Calibration Set 10, 25, 50, 75, 100 ppm wt $90 6069DCK Daily Check Standard (Specify Concentration) $80/set of 10


This Method covers the determination of Total Sulfur in Liquid Hydrocarbons and related chemicals. Standards are made with either n-Dibutyl Sulfide or Benzothiophene in an Isooctane Matrix and packaged in 2ml flame sealed ampoules. Catalog # Product Price 6428R1 Calibration Set 0.1, 0.5, 1, 2.5, 5, 10 ppm wt $90 6428R2 Calibration Set 10, 25, 50, 75, 100 ppm wt $90 6428DCK Daily Check Standard (Specify Concentration) $80/set of 10

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ASTM D4629 Trace Nitrogen by Chemiluminescence

ASTM D5762 Trace Nitrogen by Chemiluminescence

This Method is used to determine Nitrogen in products with higher boiling points. Standards are made with Acridine as the Nitrogen species in a Toluene Matrix and are packaged in 2ml ampoules with a shelf life of approximately 3 months. Catalog # Product Price 5762CAL Calibration Set 1, 5, 10, 50, 100 ng/uL $100 5762DCK Daily Check Standard (Specify Concentration) $85/set of 10 Sulfur and Nitrogen Standards


ASTM Method D4629 is the determination of Trace Nitrogen in Liquid Petroleum Hydrocarbons by Chemiluminescence detection. Calibration sets and Check Standards are made with Pyridine as the Nitrogen species and are available in a Toluene or Isooctane Matrix. All Standards are sealed in 2ml ampoules under a Helium Headspace. Catalog # Product Price 4629CAL Calibration Set 1, 2, 10, 20, 50, 100, 200, 500, 1000 $100 4629DCK Calibration Check Standard (Specify Concentration) $85/set of 10 Standards can also be custom made in Matrices similar to the compound to be analyzed.

Calibration and Check Standards are also available for the calibration of instruments configured for the simultaneous determination of Nitrogen and Sulfur. Catalog # Product Price SNCAL Calibration Set [5 Concentrations + Blank][Background] $115 SNCK Daily Check Standard [Concentration][Background] $85/set of 10 *Please specify which concentrations for Sulfur and Nitrogen are needed, as well as the background matrix upon ordering.

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To Order, Call 281-578-7575, Fax 281-578-7576 or visit our Web site: www.spectrumstandards.com

ASTM D2622 Sulfur by X-Ray Fluorescence

ASTM D4294 Sulfur by Energy Dispersive Spectrometry

SULFUR BY X-RAY SPECTROMETRY

Calibration Standards are available for ASTM D2622-08 [2008 Method] covering a Total Sulfur content of 0.0010 to 5% wt in a White Oil Matrix or Isooctane/Toluene 75/25 mixture plus 10% ETOH. They are offered in three ranges and are packaged in 30ml amber bottles. D2622 Standards using Poly Sulfides are available upon request. Range 1 (0-1000 mg/kg) Range 2 (0.10 – 1.00 mass%) Range 3 (1.0 – 5.0 mass%) 0.0 0.100 1.0 5 0.250 2.0 10 0.500 3.0 100 1.000 4.0 250 5.0 500 750 1000 Catalog # Product Price 2622R1 D2622 Range 1 Calibration Set – 30ml Bottles $195 2622R2 D2622 Range 2 Calibration Set – 30ml Bottles $195 2622R3 D2622 Range 3 Calibration Set – 30ml Bottles $205 2622X3 D2622 Calibration in all 3 Ranges – 30ml Bottles $525 2622DCK-L D2622 Daily Check Standard [*Concentration] – Liter $500 *Please specify the concentration needed upon ordering our daily check standards.

Calibration Standards for ASTM D4294-08 [2008 Method] are available in three ranges from 0 to 5% wt Sulfur in a Mineral Oil, Isooctane or Diesel Fuel Matrix and packaged in 30ml amber bottles. D4294 Standards using Poly Sulfides are available upon request. Range 1 (0-1000 mg/kg) Range 2 (0.10 – 1.00 mass%) Range 3 (1.0 – 5.0 mass%) 0.0 0.100 1.0 5 0.250 2.0 10 0.500 3.0 100 1.000 4.0 250 5.0 500 750 1000 Catalog # Product Price 4294R1 D4294 Range 1 Calibration Set – 30ml Bottles $195 4294R2 D4294 Range 2 Calibration Set – 30ml Bottles $195 4294X3 D4294 Calibration in all 3 Ranges – 30 ml bottles $500 4294DCK-L D4294 Daily Check Standard [*Concentration] - Liter $525 *Please specify the concentration needed upon ordering our daily check standards.

41



Modified D2622 CARB Method for Low Level Sulfur

ASTM D6334 Sulfur in Gasoline by X-Ray Fluorescence

Trace Sulfur in P-Xylene

Calibration Standards are available in 30 ml bottles using Thiophene and 2-Methylthiophene in a 25% LV Toluene / 75% LV Isooctane Matrix. Range 1 Sulfur Concentration ppm wt. 1 0, 5, 10, 50, 100 2 0, 100, 200, 250, 500, 1000 Catalog # Product Price / Set Carb-XRF1 Range 1 Sulfur Calibration Set $225 Carb-XRF2 Range 2 Sulfur Calibration Set $225

This Method is used to quantitatively determine the Total Sulfur content of Gasoline and Gasoline Oxygenate Blends. The Standards are made with either a mixture of Thiophene and 2-Methylthiophene or n-Dibutyl Sulfide in a 20% LV Toluene / 80% LV Isooctane mixture. Standards are packaged in 30ml bottles and are available in two ranges. Range Sulfur Concentration ppm Wt. 1 0, 5, 10, 50, 100 2 0, 100, 250, 500, 1000 Catalog # Product Price / Set 6334R1 D6334 Range 1 Sulfur Calibration Set $225 6334R2 D6334 Range 2 Sulfur Calibration Set $225

A consensus analysis was performed under the supervision of the ASTM D16 Committee. A Calibration set and Check Standards are available, packaged in 2ml flame sealed ampoules. The Sulfur compound used was Dibenzothiophene and reported as Sulfur. Range Sulfur Concentration ppm Wt. 1 0.05, 0.25, 0.50, 0.75, 0.95 2 10, 25, 50, 75, 95 Catalog # Product Price / Set PX-R1 Range 1 Sulfur Calibration Set $100 PX-R2 Range 2 Sulfur Calibration Set $100 PX-DCK Check Standard (Specify Concentration) $85 / set of 10 PX-BLANK p-Xylene Blank [contains


Sulfur Standards for On-Line Analyzers

The need for real time data has resulted in an ever-increasing emphasis on testing petroleum products using On-line Analyzers. With this technology, it is possible to sample and test products during manufacture for quality assurance. Most instruments have electronic calibration but they also need to be calibrated using standards whose matrix closely resembles that of the product being tested. We produce a range of Standards with different matrices for accurate calibration of On-Line Analyzers.

Sulfur in a Toluene / Isooctane Matrix

Calibration Standards are available with Sulfur contents ranging FROM 0.001 TO 5% WT IN A 20% LV Toluene / 80% LV Isooctane. The specific gravity of the Standard is 0.75 grams/cc @ 60 F. They are available in 1, 2 and 4 Liter bottles and cylinders up to 20 Liters. Standards can be custom made to your specifications. Call for price and availability.

Calibration Standards are available with Sulfur contents ranging from 0.001 to 5% wt in a White Oil Matrix. They are available in 1, 2 and 4 Liter bottles and cylinders up to 20 Liters. Standards can be custom made to your specifications. Call for price and availability.

Sulfur in a Mineral Oil Matrix

Sulfur in a Decane Matrix

Calibration Standards are available with Sulfur contents ranging from 0.001 to 5% wt in a Decane Matrix. The specific gravity of the standard is 0.7341 grms/cc @ 60 F. They are available in 1, 2 and 4 Liter bottles and cylinders up to 20 Liters. Standards can be custom made to your specifications. Call for price and availability.

SULFUR STANDARDS IN BULK QUANTITIES

43



EPA ULSD Qualification Set

Calibration Standards for D5453 in Diesel Fuel packaged in 2ml ampoules: Catalog # Sulfur Concentration ppm wt Price / Set: 5453RD D5453 Custom Range Calibration Set [4.0, 8.0, 12.0, 16.0, 20.0 PPM $85 5453R3D D5453 Range 3 Calibration Set [0, 100, 200, 300, 400, 500, 600 PPM] $85 5453DCK-D D5453 Daily Check [Concentration][Background] - 10X2ml $77

Calibration Standards for ASTM D7039 in Diesel Fuel packaged in 10ml ampoules:

Catalog # Product (ppm wt) Price / Set: 7039CAL-LO D7039 Low Range Calibration Set [0, 2, 5, 10, 15, 20, 25 PPM Wt] $90 7039CAL-H D7039 High Range Calibration Set [5 High Concentrations + Blank] $90 7039CAL-BIO D7039 Calibration Set in Biodiesel [0, 2, 5, 10, 15, 20, 25 PPM] $90 7039CAL-XOS D7039 XOS Calibration Set [0-500 PPM] in Diesel – 6 x 10ml $90 7039DCK D7039 Daily Check [Concentration] in Diesel Fuel - 10 x 10ml $75 The Standards above may be packaged in varying quantities upon request. Please specify the concentrations or background matrices upon ordering, when applicable.

Sulfur Standards in Diesel Fuel

We have Standards meeting the requirements set forth in EPA Method 80.580 to 80.585. The EPA requires a series of standards to be run consecutively over a period of 20 days, using the same instrument, in order to qualify each instrument. The results are then submitted to the EPA for approval.

1. All sample sets are supplied in 10 ml glass ampoules; 2. 20 samples of Diesel Fuel with a Sulfur content between 5-15 ppm wt Sulfur; 3. 20 samples of Diesel Fuel with a Sulfur content between 200-500 ppm wt Sulfur; 4. 10 samples of a Gravimetric Standard in the range 1-10 ppm wt Sulfur; 5. 10 samples of a Gravimetric Standard in the range 10-20 ppm wt Sulfur; 6. 10 samples of a Gravimetric Standard in the range 100-200 ppm wt Sulfur; 7. 10 samples of a Gravimetric Standard in the range of 400-500 ppm wt Sulfur; 8. All samples are in Diesel Fuel;

Catalog # Product Price: EPA PB EPA ULSD Qualification Set [Contains: High, Low, Accuracy and Precision] - 80x10ml $550 EPAPB-S EPA Short (Low) Set [Contains: 5-15ppm Precision, 1-10, 1-20ppm Accuracy] -40x10ml $300

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SULFUR STANDARDS



ASTM D5623 Sulfur Compounds by Selective Detection

Standards for this Method are available either as Multi-Component Mixtures or as Individual Components in a Base Fuel. According to ASTM D5623, an Internal Standard – Bromothiophene, is added. Component Sulfur ppm wt As Compound ppm wt Methanethiol 100 151 Ethanethiol 100 194 Dimethylsulfide 100 194 2-Propanethiol 100 238 T-Butanethiol 100 282 1-Propanethiol 100 237 Thiophene 100 263 Diethylsulfide 100 289 1-Butanethiol 100 282 Diethyl Disulfide 100 193 Thiophenol 100 345 Benzothiophene 100 423 Bromothiophene (Internal) 100 512 Diphenyl Sulfide 100 588 *Base Fuel Balance Balance *The Base Fuel is a mixture of 40% LV Isooctane, 40% LV Hexanes and 20% LV Toluene.

All Standards are packaged in 2 ml ampoules under a Nitrogen atmosphere and are NIST traceable by weight. The concentrations above are also available packaged individually in 2 ml ampoules in the same base fuel at 1000 ppm wt or any specified concentration needed. Catalog # Product Price MSX-14 Multi-Component Standard at 100 ppm wt Sulfur – 10x2ml $1,200 MSX-14-1 Multi-Component Standard at 100 ppm wt Sulfur – 1x2ml $138 MSX-1 Single Component Standard at 1000 ppm wt Sulfur – 10x2ml $495 MSX-1-1 Single Component Standard at 1000 ppm wt Sulfur – 1x2ml $85 Additionally, Standards can be made to any specified concentration using varying combinations of Sulfur species or solvents.

45

SULFUR STANDARDS





UOP 163 ASTM D3227 Determination of Mercaptan Sulfur in Hydrocarbons

This Standard contains 22 Sulfur species in a Base Fuel matrix and packaged in 2ml ampoules.

Component as Compound ppm wt

2-Methyl 1 Propanethiol T-Butylsulfide 2-Methylthiophene 1-Heptanethiol 3-Methylthiophene 1,4 Butanedithiol 1,2 Ethane Dithiol Methyl Ethyl Sulfide 1-Pentanethiol Propyl Disulfide 2-Ethylthiophene 1-Octanethiol Propylsulfide Benzothiophene T-Butyldisulfide 1-Hexanethiol 1,5 Pentanedithiol Carbon Disulfide 1-Nonanethiol Methyl Sulfide 1-Decanethiol Propanethiol

*Base Fuel is 40% LV Isooctane, 40% LV Hexane and 20% LV Toluene

Catalog # Product Price MSX-22 Multi-Component Standard at 50 ppm wt as component – 10x2ml $1,375 MSX-22-1 Multi-Component Standard at 50 ppm wt as component – 1x2ml $160 Additionally, Standards can be made to any specified concentration using varying combinations of Sulfur species or solvents.

Standards are prepared in a mixture of Isooctane and Toluene to determine inflection points during the Potentiometric Titration of Mercaptan Sulfur in Hydrocarbon liquids. The Standards are prepared with Tert-Nonyl Mercaptan. They are packaged in 20ml flame sealed ampoules and offered in various concentrations, please specify at the time of order which concentration you require. Please call for pricing and availability. Catalog # Product Price UOP-163-(concentration) Tert-Nonyl Mercaptan as Sulfur $50 [6 x 20ml]* *Pricing per concentration specified at time of order.

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SULFUR STANDARDS




SULFUR STANDARDS

This Standard is a 41 Component 100 ppm Sulfur Standard in a Base Fuel Matrix. They are packaged in 2ml ampoules and are NIST Traceable by weight.

GRAVIMETRIC UNCERTAINTY +/- 2% COMPONENT PPM WT COMPOUND 2-Methyl-1-Propanethiol 101 2-Methyl Thiophene 99.5 3-Methyl Thiophene 101 1,2 Ethane Dithiol 99.5 1-Pentanethiol 100 2-Ethyl Thiophene 100 Propyl Sulfide 100 1,5 Pentanethiol 100 1-Nonanethiol 100 1-Decanethiol 100 Propanethiol 99.6 T-Butyl Sulfide 100 1-Heptanethiol 99.8 1,4 Butanethiol 102 Methyl Ethyl Sulfide 100 Propyl Disulfide 100 1-Octanethiol 100 T-Butyl Disulfide 99.6 Benzothiophene 101 1-Hexanethiol 99.9 Carbon Disulfide 105 Methyl Sulfide 101 Ethyl Sulfide 100 Thiophene 99.2 N-Butanethiol 99.8 Tetrahydrothiophene 99.8 Ethyl Disulfide 101 Thiophenol 100 Methanethiol 95.9 2-Methyl-1-Butanethiol 100 3-Methyl-1-Butanethiol 100 Ethyl Mercaptan 102 2-Propanethiol 100 2-Propyl Thiophene 101 2-Butyl Thiophene 100 3-Butyl Thiophene 101 Bromothiophene 104 Methylbenzothiophene 100 Phenyl Sulfide 100 T-Butyl Methyl Sulfide 100 T-Butanethiol 100 *Base Fuel *40% LV Isooctane, 40% LV Hexane, 20% LV Toluene Catalog # Product Price MSX-41 Multi-Component Standard at 100 ppm wt Sulfur – 10x2ml $4,620 MSX-41-1 Multi-Component Standard at 100 ppm – 1 x 2ml $550

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Mercaptan Sulfur Standards

Additional Sulfur compounds are available as Single Components packaged in 2ml ampoules at any specified concentration, up to 1% weight as the compound. They can also be packaged as Multi-Component mixtures. 2-Methyl-1-Propane Thiol Tert-Butyl Sulfide 2-Methyl Thiophene 1-Heptane Thiol 3-Methyl Thiophene 1,4 Butane Thiol 1,2 Ethane Dithiol Methyl Ethyl Sulfide 1-Pentane Thiol Propyl Disulfide 2-Ethyl Thiophene 1-Octane Thiol Propyl Sulfide Tert-Butyl Disulfide 1,5 Pentane Thiol Benzothiophene 1-Nonane Thiol Hexane Thiol 1-Decane Thiol Carbon Disulfide Propane Thiol Methyl Sulfide All Standards are made in a mixture of 40% LV Isooctane, 40% LV Hexanes and 20% LV Toluene. Please specify concentration upon ordering. Catalog # Product Price MSX-1-C Single Component [As Component] – 10x2ml $495 MSX1-1-C Single Component [As Component] – 1x2ml $85 MSX-M Multi-Component Custom Standard Call for Pricing

Thiophene Sulfur Standards Standards are prepared in an Isooctane / Hexane mixture, are packaged in 2 ml flame sealed ampoules and have the following composition: Component ppm wt Sulfur ppm wt Compound 2-Methylthiophene 100 309 3-Methylthiophene 100 303 Dibenzothiophene 100 574 Tetrahydrothiophene 100 272 Thiophene 100 263 Benzothiophene 100 418 *Base Fuel Balance *Base Fuel consists of 70% wt Isooctane / 30% wt n-Hexane. Catalog # Product Price MSX-THIO Thiophene Sulfur Standard [Specify Concentration/Background] $165 [10 x 2ml]

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SULFUR STANDARDS




ASTM D4929 (B) Organic Chloride in Crude Oil

Standards are made for ASTM Method D4929 (B) for the determination of chloride in Crude Oil. The Standards are made with Chlorobenzene in an Isooctane Matrix and packaged in 2ml ampoules. Catalog # Product Price 4929CAL Calibration Set 1, 5, 10, 25, 50, 100 ppm wt $90 4929DCK Daily Check Standard [specify concentration] $80 [10 x 2ml]

ASTM D5808 Organic Chloride in Hydrocarbons

Standards are available for the determination of Organic Chloride in Hydrocarbons and related chemicals. They are made with 2,4,6 Trichlorophenol in a Methanol matrix and packaged 2ml ampoules. Catalog # Product Price 5808CAL Calibration Set 1, 5, 10, 15, 25 ppm wt $90 5808DCK Daily Check Standard [specify concentration] $80

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