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1
Triennial Review
of
Water Quality Standards
Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
ReviewProposed Revisions, Purpose & Timeline
Agricultural Advisory Board August 22, 2007
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Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
The Clean Water Act requires states to periodically, but at least once every three years, review and revise as necessary their water quality standards - Triennial Review of Water Quality Standards
Pennsylvania’s WQS are contained in 25 Pa Code Ch. 93 and portions of Ch. 92 (relating to NPDES Permitting, Monitoring and Compliance)
Other WQS provisions and criteria are also contained in Chapters 16 (Toxics Mgmt Strategy - Statement of Policy) and 96 (WQS Implementation)
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Revise and update water quality criteria:
• Revise and update water quality criteria found in Chapters 93 and 16 to reflect the latest scientific information and new Federal guidelines for criteria development.
• Revisions based in part on the most recent complete compilation of nationally recommended WQ criteria, as published in November 2002 (EPA-822-R-02-047), and as updated in December 2002 (67 FR 79094).
Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
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• EPA’s 2002 compilation includes recommended WQ criteria for 126 priority pollutants and 17 other compounds or chemicals.
• New methods for deriving human health WQ criteria includes change in the national recommended fish consumption rate to17.5 g/day, which is currently 6.5 g/day
Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
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• Move revised, updated and other criteria currently contained in Chapter 16 (Statement of Policy) into new criteria tables in Chapter 93 WQS (regulation), which include the following agriculture-related chemicals
• Also propose to add new statewide ambient water quality criteria to new Chapter 93 Table 5 for Molybdenum, Metolachlor, and Diazinon.
Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
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PPNO CHEMICAL NAME
Fish and Aquatic Life Criteria
DEP HHC
ug/L - 3/06 TR08 Proposed HH
Criteria (ug/L) CCC (ug/L) CMC (ug/L)
1P ALDRIN 0.1 3 0.00013 0.000049
2P alpha-BHC N/A N/A 0.0039 0.0026
3P beta-BHC N/A N/A 0.014 .0091
4P gamma-BHC (LINDANE) N/A 0.95 0.019 0.098
5P delta-BHC N/A N/A N/A N/A
6P CHLORDANE 0.0043 2.4 0.0021 0.00080
7P 4,4’-DDT 0.001 1.1 0.00059 .00022
8P 4,4’-DDE 0.001 1.1 0.00059 .00022
9P 4,4’-DDD 0.001 1.1 0.00083 .00031
10P DIELDRIN 0.056 0.24 0.00014 .000052
11P & 12P alpha- & beta-ENDOSULFAN 0.056 0.22 110 62 for endosulfan
13P ENDOSULFAN SULFATE N/A N/A N/A N/A
14P ENDRIN 0.036 0.086 0.76 .059
15P ENDRIN ALDEHYDE N/A N/A 0.76 0.29
16P HEPTACHLOR 0.0038 0.52 0.00021 .000079
17P HEPTACHLOR EPOXIDE 0.0038 0.5 0.00010 .000039
-- DIAZINON 0.17 0.17 -- N/A
-- METOLACHLOR N/A N/A -- 69.4
2M ARSENIC 150 (As3+) 340 (As3+) 50 10
-- MOLYBDENUM N/A N/A -- 208
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Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
• Clarify definition of “conventional treatment” for Potable Water Supply (PWS) use protection.
Conventional treatment - includes conventional filtration in a treatment process that uses separate, sequential units for coagulation/flocculation, clarification, and granular media filtration to produce finished water for drinking.
• Adding that other intervening, more sensitive uses may apply if the specified critical use does not afford adequate protection.
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• Add reference to Drainage List X to indicate the US EPA’s 2004 Beach Act federal promulgation at 40 CFR 131.41* for bacteriological water quality criteria apply to these Lake Erie coastal recreational waters within Pennsylvania. (* as published on Nov. 16, 2004 at 69 FR 67218)
Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
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Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
• Add migratory fishes (MF) use to the mid-Atlantic slope drainage basins – the Delaware, Susquehanna & Potomac Rivers.
• Reconfirm the removal of water contact (WC) protected use on selected waters within Pennsylvania’s WQS for portions of the Delaware Estuary and for the outer Erie Harbor and Presque Isle Bay.
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Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
Updates and Corrections forMissing items, typos or errors:
• Updates, revisions, and corrections for typos, translation errors and missed references associated with prior rulemaking and/or publication activities.
• Describe that notations will need to be added to the stream drainage lists to identify where previously approved site-specific water quality criteria apply.
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Revise / Update Portions Retained in Ch. 16:
• The Department proposes to rename Chapter 16 Appendix A, Table 1 , “SITE-SPECIFIC WATER QUALITY CRITERIA FOR TOXIC SUBSTANCES”. Specific criteria that are developed or approved by the Department will be housed in Appendix A, Table 1 until there is a need or opportunity for proposal by the Board to be incorporated into Chapter 93, Table 5.
Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
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• Update approved analytical methods and detection limits in Tables 2A and 2B to reflect the EPA approved methods that were recently updated and published as final in the Federal Register (72 FR 11199) on March 12, 2007, which were effective on April 11, 2007.
Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
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Timeline for Triennial Review of
Water Quality Standards - 2008M
ay 1
0, 2
006
= Pr
esen
t upd
ate
to W
RA
C
rega
rdin
g st
atus
and
scop
e
Oct
ober
200
6 =
Pres
ent U
pdat
e on
pro
pose
d
rule
-mak
ing
to W
RA
C
Sum
mer
/Fal
l 20
07 =
Pre
sent
the
prop
osed
rule
-mak
ing
to th
e EQ
B
TB
D b
y L
egis
lativ
e R
ef. B
ur. =
Pub
lishe
d in
Pa
Bul
letin
acc
ompa
nied
by
a 45
day
com
men
t per
iod.
At l
east
one
Pub
lic M
eetin
g / H
earin
g w
ill b
e he
ld in
the
Har
risbu
rg a
rea
durin
g th
e pu
blic
com
men
t per
iod.
Febr
uary
200
8 =
Pres
ent d
raft
com
men
t &
resp
onse
doc
umen
t and
sta
tus
on fi
nal r
ule-
mak
ing
to W
RA
C.
Apr
il 20
08 =
Pre
sent
fina
l rul
e-
mak
ing
to E
QB
July
200
8 =
Subm
it fin
al ru
le-m
akin
g
to E
PA fo
r rev
iew
& a
ppro
val
Pennsylvania Department of Environmental ProtectionPennsylvania Department of Environmental ProtectionBureau of Water Standards and Facility RegulationBureau of Water Standards and Facility Regulation
Spri
ng 2
006
= M
et w
ith E
PA R
egio
n 3
and
WR
AC
to se
ek in
put o
n sc
ope
of T
R08
May
200
7 =
Pres
ent U
pdat
e on
dra
ft pr
opos
ed
rule
-mak
ing
to W
RA
C; r
ecom
men
d D
EP m
ove
fwd
as p
ropo
sed
rlmkg
Aug
ust 2
007
= Pr
esen
t Ove
rvie
w o
f dra
ft
prop
osed
rule
-mak
ing
to A
g A
dvis
ory
Boa
rd