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    Radioactive decay is the process by which unstable

    atoms transform themselves into new chemical

    elements

    Introduction

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    1 Bq = 1 disintegration per second

    Activity

    The amount of a radionuclide present

    SI unit is the becquerel (Bq)

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    Multiples & Prefixes (Activity)

    Multiple Prefix Abbreviation1 ------- Bq

    1 x 106 Mega (M) MBq

    1 x 109 Giga (G) GBq

    1 x 1012 Tera (T) TBq

    1 x 1015 Peta (P) PBq

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    UnitsCurie (Ci) = 3.7 x 1010 dps

    Becquerel (Bq) = 1 dps (SI)

    1 Ci = 3.7 x 1010 Bq

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    The Decay Constant is denoted by

    NOTE:  Units on are

    Typically or sec-1 or “per second” 

    Decay Constant

    1

    time

    1sec

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     A = N

    where “A = activity” has units of

    disintegrations per second(dps or Bq)

    Activity

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    The half-life is the time required for an amount of any

    radionuclide to decay to one-half of its initial value.

    The relationship between half-life and decay constantis:

    Half-Life and Decay Constant

    T½ =0.693

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    Half-Life

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    Radioactive Decay

    The amount of activity decayed away after“n” half -lives is given by

    A

    Ao

    1 -

    represents the fraction of the initial

    activity that still exists at time t

    A

    Ao

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    Half-Life

    Radionuclide Half-Life

    Phosphorus-32 14.3 days

    Iridium-192 74 days

    Cobalt-60 5.25 years

    Caesium-137 30 years

    Carbon-14 5760 years

    Uranium-238 4.5 x 109 years

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    Exercise 1

    A criticality accident occurs in a Uranium processing facility.

    1019 fissions occur over a 17 hour period. Given that the fissionyield for 131I is 0.03 and its half-life is 8 days, calculate the 131I

    activity at the end of the accident. Neglect 131I decay during the

    accident.

    Activity = N = x

    x ( 1019  x 0.03) = 3 x 1011  Bq 131I

    0.693

    8 days

    1

    86,400 sec day-1

    3 x 1011 Bq

    3.7 x 1010 Bq/Ci= 8.1 Ci 131I

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    Radioactive Decay Equation

    N(t) = No e- 

    = - 

    N(t)dNdt

    Expressing the equation in terms of activity:

    N(t) = No e- t

    A(t) = Ao e- t

    where A(t) = activity at any time t

    and Ao  = the initial activity at time t = 0

    or

    Integrated

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    Mean Life and Half-Life

    However, when t = T½, the activity decreases to ½ of the

    original value:

    A = Ao e- t

     or

     

    A

    Ao  = e- t

    A

    Ao =

    ½Ao 

    Ao = ½ 

    ½ = e  -  T½ 

    Take the natural logarithm of both sides 

    ln (½) = -T½ ln (½) = ln (e )  -  T½ 

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    1=

    ln (½) 

    -T½ Regrouping terms yields

    But ln (½) = - ln (2) so: 

    1=

    - ln (2)

    -T½ 

    ln (2)

    T½ =

     but ln(2) = 0.693 

    1=

    ln (2)

    T½ 

    Mean Life

    = 1.44 T½  = Tm  1 =

    0.693T½ 

    where Tm , mean life,,

    Mean Life and Half-Life

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    A radionuclide has a half life of 10 days. What is the

    mean life? 

    Exercise 2

    Mean Life = 1.44 T1/2 

    = 1.44 x 10 days

    = 14.4 days

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    M = molecular weight of sample

    Av= Avogadro's number(= 6.02 x 1023 nuclei/mole)

    = r =ioisotope decay constant ( = ln 2 /half-life)

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    The specific activity of a radioactive source is defined as the

    activity per unit mass of the radioisotope sample.

    Activity can be calculated from

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    Calculate the specific activity of pure tritium (3H) with a half-

    life of 12.26 years.

    Substitute T1/2 =12.26 years and M=3 grams/mole to get the

    specific activity in disintegrations/(gram – year).

    Exercise 3

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    ENERGY 

    • It defined as the kinetic energy gained by an electron

    which its acceleration through a potential differenceof 1 volt.

    The unit for energy is the electron volt or eV 

    • The electron volt is a convenient unit because the

    energy gained from an electric field can be easily

    obtained by multiplying the potential difference by

    the number of electronic charges carried by the

    particle.

    21

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    • For example, an alpha particle that carries an

    electronic charge of +2 will gain an energy of 2 ke Vwhen accelerated by a potential difference of 1000

    volts.

    • SI unit of energy

    1eV=1.602 x 10-19 J

    1fJ(=10-15 J) = 6.241 x 103 eV

    femtojoule (fJ)

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    • The energy of an X-or gamma-ray photon is related to

    the radiation frequency by

    where h  = Planck's constant

    (6.626 x 10-34

     J · s, or 4.135 x 10-15

     eV · s)v  = frequency

    The wavelength λ . is related to the photon energy by

    where λ  is in meters and E is in e V.23

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    What is the lowest wavelength limit of the X-rays emitted by a

    tube operating at a potential of 195 kV?

    Since an x-ray must essentially be created by the de-excitation 

    of a single electron, the maximum energy of an x-ray emitted in

    a tube operating at a potential of 195 kV must be 195 keV.

    E=hv E=hc/  

    Exercise 4

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    RADIATION UNITS AND DOSEQUANTITIES

    IAEA Post Graduate Educational Course Radiation Protection and Safe Use of Radiation Sources

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    Exposure : X 

    •Exposure is a dosimetric quantity for ionizingelectromagnetic radiation, based on the ability

    of the radiation to produce ionization in air .

    • This quantity  is only defined for

    electromagnetic radiation  producing

    interactions in air.

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    •Exposure is the absolute value of the total chargeof the ions of one sign produced in air when all

    the electrons liberated  by  photons per unit mass

    of air are completely stopped in air.

    Exposure : X

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    X = dQ/dm 

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    Exposure : X

    •The SI unit of exposure is Coulomb per kilogram[Ckg-1]

    • The former special unit of exposure was

    Roentgen [R]

    • 1 R = 2.58 x 10-4 Ckg-1

    • 1 Ckg-1 = 3876 R  

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    /

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    Exposure rate: X/t  Exposure rate (and later, dose rate) is the exposure

     produced per unit of time.

    The SI unit of exposure rate is the [C/kg] per second

    or (in old units) [R/s].

    In radiation protection it is common to indicate these

    rate values “per hour” (e.g. R/h). 

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    Ab b d d D

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    Absorbed dose, D

    • The absorbed dose D, is the energy absorbed per unit

    mass.• This quantity is defined for all ionizing radiation (not

    only for electromagnetic radiation, as in the case of

    the “exposure”), and for any material. 

    • D = dE/dm. The SI unit of D is the Gray [Gy].

    • 1 Gy = J/kg.

    • The former unit was the “rad”. 1 Gy = 100 rad.

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    Relation between absorbed dose and exposure

    It is possible to calculate the absorbed dose in amaterial if the exposure is known

    • D [Gy]. = f . X [Ckg-1]

     –

     f = conversion coefficient depending on medium

    • The absorbed energy in 1 gram of air exposed

    to 1 [Ckg-1] of X-rays is 0.869 [Gy]

    f (air) = 0.869

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    Example of conversion coefficient: f  

    f values (([[GGyy]] / [[CCk k gg--11]])) 

    Photon

    energy

    Water Bone Muscle

    10 keV 0.91 3.5 0.93

    100 keV 0.95 1.5 0.95

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    Mean absorbed dose in a tissue or organ

    • The mean absorbed dose in a tissue or

    organ DT  is the energy deposited in the

    organ divided by the mass of that organ.

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    • The equivalent dose H  is the absorbed dosemultiplied by a dimensionless radiation weighting

    factor, wR   which expresses the biological

    effectiveness of a given type of radiation

    • To avoid confusion with the absorbed dose, the SI

    unit of equivalent dose is called the Sievert (Sv). The

    old unit was the “rem” 

    1 Sv = 100 rem 

    Equivalent dose: H

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    Radiation weighting factor, wR  

    For most of the radiation used in medicine(X-rays, , e-) wR  is = 1, so the absorbed

    dose and the equivalent dose are

    numerically equal

    • The exceptions are:

     – alpha particles (wR  = 20)

     – neutrons (wR  = 5 - 20).

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    Radiation weighting factor, wR  

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    Ti i h i f

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    Tissue weighting factors, wT 

    ORGAN /

    TISSUE

    WT  ORGAN /

    TISSUE

    WT 

    Bone marrow 0.12 Lung 0.12

    Bladder 0.05 Oesophagus 0.05

    Bone surface 0.01 Skin 0.01

    Breast 0.05 Stomach 0.12

    Colon 0.12 Thyroid 0.05

    Gonads 0.20 Remainder 0.05

    Liver 0.05

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    Eff i d E

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    Effective dose, E 

    E = T wT.HT

    E : effective dose

    wT : weighting factor for organ or tissue T 

    HT : equivalent dose in organ or tissue T 

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    Non-SI Units

    Quantity Old Unit SI Unit Conversion

    Activity curie (Ci) becquerel (Bq) 1 Ci=3.7 x 1010Bq

    Absorbed

    Dose rad gray (Gy) 1 rad = 0.01 Gy

    Equivalent

    Dose rem sievert (Sv) 1 rem = 0.01 Sv

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    In a mixed radiation environment, a person receives 20 mGy of

    γ-ray dose and 2 mGy of slow neutron dose.

    Calculate the total equivalent dose received by the person.