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第三章 醇酸树脂 第一节 概 述 第二节 醇酸树脂的分类 第三节 醇酸树脂的合成原料 第四节 合成醇酸树脂的反应原理 第五节 醇酸树脂的配方设计 第六节 合成工艺 第七节 醇酸树脂的合成实例 第八节 醇酸树脂的改性 第九节 醇酸树脂的应用. 第三章 醇酸树脂 第一节 概 述. - PowerPoint PPT Presentation

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  • COOalkyd resin

    2025

  • 1200 , , 2 , 3

  • (OL) OLf = OLf OL 95 % ,

  • OL (1) , - / (2) , , , OL ,

  • 100.00g0.400g9843.00g99.574.50g2 92 4398/92=0.458(mol) 30.4581.374(mol) 1482 74.5099.512/148=0.491(mol)220.4910.982(mol) 0.491188.835g100.043.009874.5128.835205.945g 100/205.945=49%

  • 1213 3

  • ()/ /(g/cm3)92.0918(290)1.26134.1256592951.1758136.15189(260)1.3862.07-13.3(197.2)1.12106.12-8.3(244.5)1.11876.09-60(187.3)1.036

  • PA(IPA)(TPA)(MA)(AA)(SE)TMA(AA)(SE)TMA

  • -9--912--9,12,15--9,11,13-12--9-

  • 1406 1004 10014046 1 5 0.900.94 g/cm : 5.0 mg KOH/g() 3

  • 1gKOH1gKOH KOH 240280 100g

  • LiOH0.02

  • , 1(V)(Ce)0.02%0.2%

  • 2(Ca)PbZr(Zn)(Ba)(Sr) 0.5%

  • 232332/232.4Crothers Pc2/2.40.833,322221:1:1

  • 1 65 6560 6055 5550 5040 4030 0 0 010 1015 1525 253505 515 1520 2030 304011

  • 2 34fPc1 609110552009135.5 1 210.135.578.1g 118g 60%()/(160)60%(14878.118)/(160)312.15g 312.1590280.94g 312.151031.22g

  • 14878.1312.1518520.25g 155520.25/55425.66g 425.6690383.09g 425.661042.57g 11

  • 230.31930.036921.000 /(0.319+30.319+0.0369+30.0369+0.550+1.000) 2.063 2/2.0630.969

    g280.94

    31.22

    78.1148.0879

    846

    1421480.3190.31930.3190.03690.036930.03690.5501.00031

    3142

  • 12 12

  • 12312312123

  • 1 1 2CO2N2, 3LiOH0.02 4 230250

  • 2 1801802208

  • 1127.862/127.86279.310148.0183830.81821.000/(21.000)0.2272(21+30.193)/0.818+0.193+1+30.193=1.992 2/1.992 1.004

  • 2 60CO2120 2h2205(250C1ml5ml) 18020min N26% 2h1952002h 8 mgKOH/g10s110

  • 1 305.886/305.886138.114148.0181.07318 55 41.01621.0001.073/(21.0001.073) 0.3222(21+1.073)/1.073+1.016+1+1.000=1.990 2/1.990 1.005

  • 2 8CO21h1801h 1h2002202h10mgKOH/g10s30min 55 30min8090

  • 601

  • 253.7128.19/253.7128.1967.6694.16148.0180.554618 6040.692421.0000.5546/(21.0000.5546) 0.0822(21+0.5546+30.2886+30. 0333)/0.2886+0.0333+0.5546+30.0333+30.288+0.6924+1.000 1.990 2/1.990 1.005

  • 2 ,CO21200.03LiOH 22024095(250C)135 200220CO2 5% 2002203h 10mgKOH/g10s30min 12020050

  • , , , , ,

  • 1 B67B99N

  • 2 BPO

  • 199533.4%50.5%16.1%200515%65% VOC

  • 1 1 PAIPAPTAADAZA14-14-CHDALALAIPA330 30%mass ratioAD

  • 2 TMP16-16-HDO14-14-CHDM12-NPG224--13-TMPDTMPCHDMTMPD 3 TMAPEG-5-DMPA

  • 4 5 6

  • 2 TMA PAIPATMP TMATMA

  • PEG

  • DMPADMPA

  • (Diels-Alder)14

  • , , , , , , 3 1TMA

  • PAIPA TMP500ml1401h1801h2301h10mgKOH/g170TMA50-60mgKOH/g120 85%7080%1h50%0.5h

  • 2PEG PA1801h2201h30mgKOH/g120 75%50%0.5h

  • 3DMPA 1600.5h180 1h2301h50-60mgKOH/g120oC80%7080%0.5h40%0.5h

  • 1 2 3