1

1

1. 2.

2

. 2 (1493~1496) , . , , ' , = coa () + ochu ( )

(rub) , Rubber() . '' () , gomme() gom() Vulcanization (1839) : Charles Goodyear (1906) : Oenslager () (1910) : (1924)

5 ?250 Kg ? 6 22 ? 50 Kg

Compound?Specific Physical PropertyRubberFillerNR, SBR, BR, Butyl . . .Carbon Black, Silica, Clay . . ., Ozone . . .Process Oil, Activator . . ., . . ., . . .B/M, ,Roll ( 9~15 )

( 200)1. Component - Target ( , , . . . ) - ( Crack , . . . )2. ( , Tack . . . )3. Cost 4. . . .Compd

; PHR (Per Hundred Rubber) - (Polymer) 100 Recipe * SBR1712 : 100 + A#2 Oil 37.5 100 Carbon Black 65 Oil 10 4 2.0 1.0

Total 183.0 phr SBR1712* 137.5 Carbon Black 75 Oil 9 4 2.2 1.5

Total 229.2 phr

2 : Step Banbury Mixer ( A : B : Final )

8

ROLL MIXING

MIXINGSHEETING

99CMB, TPE . .

1. 1. 2. 3. 4.

Filler , , ,, , , , , , , M.V, , , Chemical ,

Filler ,Chemical ,

, Rubber, Elastomer, Polymer(), (), Polymer()

10, , ( , ,) . (, Crosslinking, Curing) , . (C) (H)

, . (Backbone) (Vibrating) (Brown Motion) . Backbone

, , . ?

polymerTg ()NRIsoprene Rubber-72BRButadiene Rubber-79SBRStyrene-Butadiene Rubber-52NBR( (20%)Acrylonitrile-Butadiene Rubber (Nitrile Rubber)-56CRChloroprene Rubber-40IIRIsobutene-Isoprene Rubber (Butyl Rubber)-80 Vinyl-Methyl Silicone Rubber-118~-128 Chlorosulphonated Polyethylene Rubber -34

Dien : NR, SBR, BR -> .(Main Chain, , Backbone) , , ,

ASTM NR -40~60 ,,,,, ,, - SBR , -35~90 ,,, , BR NR -45~90 , ,, ,, CR ,,, -30~100 ,,, , NBR ,, -25~100 ,,,, top roll IIR ,, -40~120 , Curing bag ,,,, - EPDM ,, , -40~140 , CSM ,, -25~130 ,,, , ACM ANM , -10~160 FPM , -25~220 ,, , Q ,, ,, -90~200 ,, sealant,

1) (kgf/)2) (%)3) 4) 5) (pphm)6) 7) (): NR > NBR > CR > CPE > CSP > EVA > SR > SBR > EPDM.: NR > EPDM > SR > CSP > CPE > EVA > SBR > CR > NBR: SR > EPDM > CSP > CPE > EVA > CR > NBR > SBR > NR: SR > EPDM > CR > EVA > CSP > CPE > NBR > SBR > NR: EPDM > EVA > SR > CSP > CPE > CR > SBR > NBR > NR: NBR > CR > EVA > CSP > CPE > SR > SBR > EPDM > NR: EPDM > EVA > SR > CSP > SBR > NR > CPE > CR > NBR

.

19

88.23% 5.04% 4.10% 0.84% 1.74% , , . , , . Natrual Rubber

, Sheet Block

21

RSS#3 (Ribbed Smoked Sheet #3)TSR (Technically Specified Rubber, ) Special Rubber [ Light Grade & CV (Constant MV) ] TSR-10 (Dirt 0.10 % ) TSR-20 (Dirt 0.16 % ) STR [ Standard Thai R. ] SMR [ Standard Malaysian R. ] SIR [ Standard Indonesia R. ] SCR [ Standard China R. ] SVR [ Standard Vietnam R. ]

22

Styrene Butadiene Rubber ( 80%), , Styrene 23.5% High Styrene Hot, Cold Rubber , Cold(5 ~ 10 ) 80% Grade IISRP( ) . . , , , . , Scorch NR, BR Blend SBR .

Polymer . , Calender , , . Rubber , NR

SBR (Emulsion SBR ; E-SBR). Solvent : Water (Radical ). (MWD : 4 6), .. Microstructure Control (Random Copolymer). E-SBR Grade . SBR (Solution SBR ; S-SBR). Solvent : Hydrocarbon (Anionic ). Vinyl Styrene Microstructure .. E-SBR Sharp(MWD:1.052.2) , 10001500160017001800Hot E-SBRNon-Oil (Dry) Extended Cold E-SBRCarbon Black Master Batch Non-Oil Extended Cold E-SBROil Extended Cold E-SBRCarbon Black Master Batch Oil Extended Cold E-SB

(number-average molecular weight): Mn Mn = / ,

(weight-average molecular weight): Mw( x ) / .)

MWD : : Mw/Mn :

High Cis Polybutadiene (Tg) -100 . High Cis Polybutadiene . Roll , NR SBR Blend Low Cis Polybutadiene High Cis BR Low Cis BR (BR)

.

NR SBR , , . , Blending, , ,

Cold flow, Chipping Cutting Roll BR NR SBR Blending

Ethylene - Propylene - Diene Rubber Ethylene Propylene EPM Diene , , . , , , , , . . . bloom , .

, / / (Fillers) . 90~99% . Rubber

Polymer . Polymer . Silane Coupling Agent

/ ( Particle Size ) : , ( Structure ) : (H-bonding,Van der Waals bonding )

Structure

Structure SAFDie SwellISAFHAFFEFGPFSRFMT

3030

. , .CB GradeASTM No(nm) SAF(Super AbrasionFurnance)N110N13411~19 ISAF (Intermediate SuperAbrasion Furnance)N220N23420~25SAF HAF HAF(High Abrasion FurnanceN326N330N339N35126~30 , Fast Extruding Furnance)N550N58240~48SRF FEF , Modulus .SRF(Semi ReinforceFurnanceN762N77461~100 ,

Compound Carbon Black

Carbon blackParticle size Smaller Higher StructureLoading Level-upRubber propertiesSurface area LargerIncorporation time-DispersionUncuredMill-bagging-RubberMooney viscosityScorch timeDie-swell

Hardness300% ModulusTensile strengthCuredElongation-RubberTear resistanceWear resistanceReboundHeat-build-upHysteresisIncreaseDecreaseCompromisingSlightly increase

(Vulcanization) 3 . , .

Effective Crosslink

S1

S2

S3

SX

Sy

Acc. -- SzMono-Di-Poly-CyclicSulfidePendantSulfide

Rubber(diene polymer)Sulfur+ (Cross-link )

+ZnO+

Chain . 1839 C. Goodyear Polymer . , .

Polymer , Main Chain .. . Static Anti Oxidant Chemical AntiOzonant Wax Film . Dynamic Anti Oxidant AntiOzonant , Ozone

Rubber Rubber Rubber , Non-Vulcanizer Rubber , , , roller Processing OilPlasticizers

NRSBRCRBRNBREPT

()NO 6-1 F/P. ? ( ) , , (CMB,FMB ->//: 0.3%,:1.0%) - (F/P) - : 205, : 70% ( ) () (1/LOT) - : , - :

1. 2. POP : / 1. LOT2. 3. 4. 1. - : , , , (EVA, LDPE, ) - , , , SPC Bar Code . 2. Tag

3. 1. Bar Code : SIGNAL

PolymerC/BLACKFillerC/B M/BOILM/BZnO M.V 40, 100 C/B Rust [] Item . [] Item .

/ (2/1) NO Lot No (EX) 1 MGO 111040520110405 Lot No 2 S 1110418120110418 Lot No 3 P V I 180961B- Lot No 4 FAB 1BPLA0318- Lot No 5 ZNO () 1-6 D O P 1U10307D320110307 Lot No 7 P # 6 12011.2.1120110211 8 TP 95 10006527386- Batch No 9 BIB 40P 1-10 3 C 12011,03,1720110317 Production Date 11 K13(6C) 11102281092011022812 BLE N(65) 11101140120110114 Lot No 13 M B 102508-14 MBPC 2246 12010042720100427 Production Date 15 R D 11104210920110421 Lot No 16 SP N 12011,04,2420110424 Production Date 17 PAN 1011402- Lot No 18 TL PT 1102102- Lot No 19 AW-P 1371041- Lot No 20 TC 1-21 UL 160 15/4/201120110504 Date Produced 22 UL 200 18/9/201020100809 Date Produced 23 P WAX 1-24 FinaWax OK 1205/11/10- Batch No 25 P-Wax EP 1400 1000B11- Lot No 26 P # 1 12011.03.1120110311 27 P 90 1AD-5217- Lot No 28 S1503 1AD-0046- Lot No 29 STR 5L 115/1796- Lot No 30 B Z 1110213-31 D M 11102200120110220 Lot No 32 E Z 11102236120110223 Batch No 33 M 11101160120110116 Lot No

RR1(SBR)R3(EPDM)R6C/BCC FILLERCSILICAC5(caco3)C6PPSPOWDERSMMASTER BATCHMXXYYAA1WAXA5TACKTT

CODE

()NO 6-2 F/P. ? , () ( ) - , , - : 6 - : 1

. () / . -. () , -.

() ()

, ,,

MAIN SILODAILY BINMIXERWEIGHING SYSTEMROLLER-DIEFEEDING SYSTEMBATCH OFF M/C

C/B TankA TankMixerRoller Die Ext.TakeAway C/VTakeAway C/VBatch off M/CWig-wag &C/VC/V

Non-pro Mixer Line

50 .

Final Mixer Line

51 .

Mixer Construction

RamHopper doorRotorDrop DoorLatchBedHopperChamberEnd Frame

Rotor ( )ChamberRotor BladeClearanceRotor ()

Chamber Rotor Mixing Banbury Mixer Mixing

, , Band Bank Bank Band( ) Bank Roll ( ) () Bank Band Bank Band , Bank , Roll Roll , Open Roll Mixing

Mixer Mixer ,Roll Mill Roll Band Mixing mixing Open : cooling Mixing Cycle .TangentialType Rotor Chamber [80%] Rotor Rotor , , , . B/t Kneader Mixer . , .IntermeshingType Rotor Rotor . Rotor . . .

ROLL 50~60120

Banbury MixerOpen Roll - - Thermochemical Breakdown - Rotor Wall Mixing - Chamber Mixing (Internal Mixier) - Cycle Time (50~90sec) - (180kg ) - - Mixing - - Mechanical Breakdown- Cylindrical Roll - ( Cutting, Overlaping ) - Open System ( ) - Cycle Time ( ) - -

. . Radical Filler network(Rubber Gel) .

57

Type 2W4W(S)4W4WH4WH-II6WIGeometryG/Details L : 40~ 45 S : 40 ~ 45 L : 30 S : 30 L : 35 S : 30 Low PowerLow Price.Thermal Advatage. Rapid and compact discharge. High Fill Factor. High Intake. High Energy Input.Large scale.High productivity.FlexibilityHigh ProductivityHigh QualityHigher productivityHigh qualityGood dispersionFinal + RemillMaster BatchMaster BatchFinal + Master Final + MasterMaster batch

LSM

Mixer Rotor Type Tangential Type

(4Wing)(Full 4Wing)

[ Tangential Type ] [ Intermeshing Type ][ ] Rotor Geometry

59

Tandem-PrincipleTop Machine: Ram Type MixerTandem MixerDump: Twin Screw Extruder with Roller Die

Tandem Mixing PrincipleConventional Multi-Step ProcessTandem Principle

()NO 7-2 F/P. ? , ( -> 0.5%) (F/P) - : 205, : 70% ( ) (F/P) F/PROOF - - / () Lay Out : ( ) LOT ( )

4. 4. 1. 2. /3. (,)4. () ; 5. Main Server DB 0.2kg 0.1kg 0.1kg 0.05kg1. Main Server DB 0.001kg 0.001kg

/1234567891011NR50(07)-C-1SVR-3LZNOSUNNOCPVI FABFEF(N550)MT-C3CRDK13(6C)P-WAX(EP-1400)1201510010024(g)40,000.003,200.00400.00120.00300.006,400.009,200.00800.00400.00400.00400.00R0115J01006940,000.003,200.00400.00120.00300.006,380.009,200.00800.00400.00400.00400.00R0115J01007040,000.003,199.00400.00120.00300.006,360.009,200.00800.00400.00400.00400.00R0115J01007140,000.003,202.00400.00120.00300.006,380.009,200.00800.00400.00400.00400.00NR50(07)-C-1SVR-3LZNOSUNNOCPVI FABFEF(N550)MT-C3CRDK13(6C)P-WAX(EP-1400)1201510020026(g)40,000.003,200.00400.00120.00300.006,400.009,200.00800.00400.00400.00400.00R0115J02006340,000.003,200.00400.00120.00300.006,400.009,200.00800.00400.00400.00400.00R0115J02006440,000.003,203.00400.00120.00300.006,380.009,200.00800.00400.00400.00400.00NR50(07)-C-1SVR-3LZNOSUNNOCPVI FABFEF(N550)MT-C3CRDK13(6C)P-WAX(EP-1400)1201510030027(g)40,000.003,200.00400.00120.00300.006,400.009,200.00800.00400.00400.00400.00R0115J03006040,000.003,201.00400.00120.00300.006,420.009,200.00800.00400.00400.00400.00R0115J03006140,000.003,198.00400.00120.00300.006,420.009,200.00800.00400.00400.00400.00NR50(07)-C-1SVR-3LZNOSUNNOCPVI FABFEF(N550)MT-C3CRDK13(6C)P-WAX(EP-1400)1201510050010(g)40,000.003,200.00400.00120.00300.006,400.009,200.00800.00400.00400.00400.00R0115J05002440,000.003,199.00400.00120.00300.006,420.009,200.00800.00400.00400.00400.00R0115J05002540,000.003,202.00400.00120.00300.006,420.009,200.00800.00400.00400.00400.00R0115J05002640,000.003,201.00400.00120.00300.006,420.009,200.00800.00400.00400.00400.00

/123456789101112131415161718EP40(04E)-2KEP 960EPDM(KEP210)()MISTRON VAPORFEF(N550)P#1 (P-1)P-WAXZNO FABBZCZ(CBS(G))TTNA-22MIRAD-RGSCIR#90CaCO3PEG4000 ,MB1201510010001(g)15,525.0012,650.0013,800.00345.0011,500.001,150.001,150.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00R0115J01000115,650.0012,770.0013,720.00345.0011,420.001,151.001,149.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00R0115J01000215,640.0012,720.0013,740.00345.0011,420.001,151.001,151.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00EP40(04E)-2KEP 960EPDM(KEP210)()MISTRON VAPORFEF(N550)P#1 (P-1)P-WAXZNO FABBZCZ(CBS(G))TTNA-22MIRAD-RGSCIR#90CaCO3PEG4000 ,MB1201510030017(g)15,525.0012,650.0013,800.00345.0011,500.001,150.001,150.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00R0115J03004015,460.0012,670.0013,780.00345.0011,410.001,150.001,149.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00R0115J03004115,410.0012,720.0013,780.00345.0011,410.001,151.001,150.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00EP40(04E)-2KEP 960EPDM(KEP210)()MISTRON VAPORFEF(N550)P#1 (P-1)P-WAXZNO FABBZCZ(CBS(G))TTNA-22MIRAD-RGSCIR#90CaCO3PEG4000 ,MB1201510040002(g)15,525.0012,650.0013,800.00345.0011,500.001,150.001,150.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00R0115J04000315,540.0012,650.0013,840.00345.0011,410.001,151.001,151.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00R0115J04000415,550.0012,660.0013,860.00345.0011,410.001,151.001,150.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00EP40(04E)-2KEP 960EPDM(KEP210)()MISTRON VAPORFEF(N550)P#1 (P-1)P-WAXZNO FABBZCZ(CBS(G))TTNA-22MIRAD-RGSCIR#90CaCO3PEG4000 ,MB1201510070020(g)15,525.0012,650.0013,800.00345.0011,500.001,150.001,150.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00R0115J07004515,600.0012,640.0013,800.00345.0011,420.001,151.001,149.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00R0115J07004615,600.0012,640.0013,780.00345.0011,410.001,150.001,149.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00EP40(04E)-2KEP 960EPDM(KEP210)()MISTRON VAPORFEF(N550)P#1 (P-1)P-WAXZNO FABBZCZ(CBS(G))TTNA-22MIRAD-RGSCIR#90CaCO3PEG4000 ,MB1201510100018(g)15,525.0012,650.0013,800.00345.0011,500.001,150.001,150.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00R0115J10003515,520.0012,700.0013,820.00345.0011,410.001,150.001,151.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00R0115J10003615,520.0012,710.0013,820.00345.0011,420.001,149.001,149.00230.00368.00115.00138.00115.00345.0092.00460.002,300.00230.00115.00

NR50 POP DATA EP40 POP DATA : SPEC POP LOT

- - pop - check -

P.O.P DATA, FOOL PROOF SYSTEM

6767

() Oil . , . , . : 1/( Batch ) . :

Oil

, 1. -> . : : -> Breakdown[mastication], [Incorporation], [Distribution][Dispersion], [Simple Mixing]

Mixing Procedure Subdivision 1000 mIncorporation, Rubber , 10 mDispersion[Shear Stress] [Agglomerate] size , 0.1 mDistribution [Entropy] Simple MixingMastication,

Power Profile 0: 1: Ram Down2 : Mixing(Rubber)3 : Filler + Chemicals 4 : Ram Down5 : 4~5 BT(Black Incorporation) BIT6 : Oil Injection Or Clean7 : : , [Power level down] 1 : , / [Power level up] 2 : , /, [Power down] 3 : , [Power Plateau]SubdivisionIncorporationDispersion & DistributionSimple Mixing(Mastication)

Optimum Fill Factor Energy Input(ESP) Mixing Chart(BIT, Flow, Tq Amplitude) Heat Generation Rate(/sec) Mixing Sound Amplitude of Ram Movement(2~3cm) Step Viscosity Reduction Rate(From Non-Pro to FMB Mixing)

1. Slip 2. Torque Amplitude3. Ram Indicator (Optimum Movement 2~3cm )Fill factor 1. Mixing Energy Input ( + + )2. Mixing Sequence E . Filler Energy Loss BIT(Carbon Incorporation Time)

Volume69.35%B/M VOL: 255 Liter 1.1667(W)PHR(d)V(w/d)SBR 35KgNRSBRZnO70.030.060.05.03.01.03.00.930.921.825.600.921.211.0075,2732.6132.970.893.260.833.0081.6735.0070.005.833.501.673.50 172.01.1557148.82204.4

VOLUNE 2. Component = x PHR ) NR : 1.1667 X 70 = 81.67 Kg3. VOL CMB 4. Mixing Volume = Total Wt(Kg) / Mixer Vol. / Density ) 204.4 / 255 /1.1557 =69.35%1. ( Fill Factor ) Volume ) SBR BALE : 35Kg : 35/30 = 1.1667PHR (Kg) ( 4 ) (Kg) phr

[ Volume : ] 50 - 90%75~100%75~110% 60 - 80%80~95%80~100%Scorch60~70%75~85%75~90 %

A

1. Cheesy, Crumble Polymer 80% 2nd Peak . Slip .Oil Injection Clean Stagnation Zone Mixing Surface 2. 2nd Peak ~ 2nd Peak 85% 2 Clean Slope Ram Sweep

System Lot , Over Mixing, Over Heating . Step . Next Step . Drop Door Open . Rotor, Chamber, Drop Door . Mixing .

Mixing Parameter Control Method Classical: High Viscosity Polymer(NR Block), :High Grade Fillers,High Loading(70part )Fill factor : Slip,Torque, interaction(Rheology),Dispersion, , Ram Press(Hydrodynamic Stress) : , , TCU Set Value : , Mixing Effect, -(Classical,U/S/D)- Main Factor - Fill factor, Ram ,Pressure- Rotor Speed, TCU SetMixing Sequence - - Mixing- Oil or Clean- Dump Out- Emergency

1) Conventional Mixing Upside down Mixing2) Mixing Method Muti Step Process 1 Stage Mixing Process Mixing ProcessMethodMixingConventional, ,CB, CHMICAL , .BATCH . Upside-Down CB Oil High Loading Fill factor . OR

Mixing Method

Principle (sec) (Kwh)Wu = k P[t]dt/Vb High Oil Loading Compd (Mixer Slip ) ( Hardening Compd Slope ) (Kw) Torque Viscosity () , , ,

()NO 7-1 ? - (), / - , ( )

ROLL , 80 , , ,

15G07-115G07-215G07-3

15J05-115J05-215J05-3

15J01-115J01-215J01-3 B/T (POP : POWER CHART )

()NO 8-1 F/P. (,,Chamber,) , - , Chamber, ROLL (F/P) , , - - 8-2 (,) , - , , ,

6. 7. /1. /2. MIXING Main Server DB , , , .3. 4. 5. (,,,...)6. 1. 2. 3. 4. / :BLEND , , 5. C/VC/V 2O/R 6. 7. 8.

6. BOM 7.1, 2. BOM / 3. 4. B.O.M 5. ()6. FMB SLITTING 7. SLITTING /1. ( 205) Bar Code Location

- - 5 chiller - 15 - 40 - 5

10. /1. 2. 3. ( vs )3. 3-1. ( , ) 3-23. / / / / Bar Code

RF-ID

BAR-PRT

MCS Server

RS-422RS-422RS-232RS-422TCP/IPSOCKETTCP/IPOracle SQL-NetTCP/IPOracle SQL-NetTCP/IPSOCKETTCP/IPINTOUCHEthernetTCP/IPRS-232

PLCEthernet

TCP/IPSOCKET

PCC

RelaySignal

RelaySignalOFF-LINE BAGTCP/IPOracle SQL-NetTCP/IPOracle SQL-NetTCP/IPOracle SQL-Net

RF-IDBar-CodeScanner

BATCH SHEET

NMP

PLC

SCC

MCS Client

UACSTCP/IPOracle SQL-NetInterface

92

[ ] A Monitoring

93

[ ] , ,

[ Off-Line Line ]

94

List

95

97

[ ] Trend Log (Linear)

98

[ ] Trend Log (Overlap)

99

1) ( ) 1) POP ->

LOTNOLOT(A)()()(F)RPMSTEP (mm:ss)INPUTOUTPUTSTEP1STEP2STEP3STEP4STEP5STEP616111024A7023021A70232011-10-2415:47:4616:10:2122:350.0~176.033.0~121.019.0~22.022.0~25.00.0~7.60.0~30.0240210210600017111024A7023031A70232011-10-2416:35:2417:07:2432:000.0~172.029.0~115.019.0~22.022.0~25.00.0~7.30.0~30.0240210210600018111024A7023041A70232011-10-2510:56:2611:18:2321:570.0~177.036.0~121.019.0~22.022.0~25.00.0~7.40.0~29.0240210210600019111024A7023051A70232011-10-2513:30:1613:51:1921:030.0~161.020.0~123.019.0~22.020.0~25.00.0~7.60.0~29.0240210210600020111024A7023061A70232011-10-2513:55:5114:18:5823:070.0~165.063.0~123.020.0~25.024.0~30.00.0~7.60.0~29.0240210210600021111024A7023071A70232011-10-2514:36:0315:02:2426:210.0~163.043.0~123.027.0~30.028.0~33.00.0~7.60.0~29.0240210210600022111024E7002011E70022011-10-2411:49:1811:58:4209:240.0~178.026.0~85.020.0~22.022.0~24.00.0~6.00.0~29.0180119000023111024E7002021E70022011-10-2510:25:2010:44:3519:150.0~189.043.0~74.019.0~22.022.0~24.00.0~6.30.0~28.01801200000

, , , , M.V, , ,

()NO 8-3 F/P.CMB/FMB ? - ,,,, ( -> tc90 10% : ) - () SPC - , , , , - ( : O O O)

8.9. 1. () 2. / 3. Compound 3-1. ,Scorch,, 3-2. 4. 5. 1. 2. 3. / 4. / 5.

ODRMDR RHEO METER

Tmax455152.2Tmin11.522.40.6t506.514.20.7t9091.57.40.9

SPEC10% SPEC3 10% 3 CEP4082F3:50604:0024(4.000.40)4:00452.74%0.00%CEP5082H3:40603:4422(3.720.31)3:445519.8%0.76%EP804:1425(4.220.41)4:1490%0%

-

A GEP1365F

D : D3 : 3 5 : 5 LINEE :

()NO 9-1 F/P.(CMB, FMB) ? , / (F/P) - : 205, : 70% ( )

()NO 9-2 F/P. ? ( ) , Tag () , , - - , , , ( ) FMB (FMB ) FMB ( -> 0.5% ) / FMB

116

: ML, TC10, TC90 TORQUE

117

118

, ,

,

2. MAN

120

Rheometer ts2 Rheometer ts1 -> ts2

Rheometer

.-,,

- POP

(,,) (,,) )

(,,)

BAR CODE , F/PROOF PROGRAM

- - () - -

() ()

: Cpk : 0.25

: Cpk : 1.82

/

1200(1PPM)

1400(1PPM)

( )

- () BOX

60 80

6080

- , BOX - BOX ,

Lay-out Lay-out

Lay-out

Lay-out

GNR2970

Lay-out

.

CMB/FMB Tag FMB () , CMB ()

CMB

, () ,

.(:0~100 ,:145~150) (0 ~ 300)

(, )

OVER

( / ) (,) ( )

NAME PLATE NAME PLATE

NAME PLATE

, ,

: 170 10 : 170 10 ) : 170 10 :160 10 : 170 10 :160 10

- -

158158158158

MAN

, or OJT ,

. OJT

CompositionHeat

ResistanceOzone ResistanceBloom

RateVolatilityPersistance

77PDN,N'-bis(1,4-dimethylphenthyl-PPD

IPPDN-phenyl-N-isopropyl-PPD

6PPDN-(1,3-dimethylbutyl-N'-phenyl-PPD

W-100Mixed Diaryl-PPD

TMQPoly(2,2,4-trimethyl-1,2-dihydroqunoline

BLEHihg temperature reaction product of

acetone and diphenylamine