Efficient Synthesis of B-Iododialkyl- and B-Alkyldiiodoboranes as Their Acetonitrile Complexes: Application for the Enolboration–Aldolization of Ethyl Ketones
An efficient enantioselective total synthesis of a trifluoromethyl analog of blastmycinolactol
Asymmetric synthesis of 6-(2′,3′,4′,5′,6′-pentafluorophenyl)-δ-lactones via “allyl”boranes: application for the synthesis of fluorinated analog of key pharmacophore
Preparative-scale synthesis of both antipodes of B-γ,γ-dimethylallyldiisopinocampheylborane: application for the synthesis of C1–C6 subunit of epothilone
Relationship between the structure and enantioselectivity in the asymmetric reduction of 2′,6′-disubstituted acetophenones with DIP-ChlorideTM. An ab initio study
A remarkable inversion in configuration of the product alcohols from theasymmetric reduction of ortho-hydroxyacetophenones with B-chlorodiisopinocampheylborane
Efficient general synthesis of 1,2- and 1,3-diols in high enantiomeric excess via the intramolecular asymmetric reduction of the corresponding ketoalkyl diisopinocampheylborinate intermediates
Rate enhancing effect of hydrogen chloride and methanesulfonic acid on the intramolecular asymmetric reduction of 0-aminoaceto- and -benzophenones with diisopinocampheylborane
Efficient Syntheses of 2-Isopinocampheyl- and Related 2-Terpenyl-1,3,2-dioxaboroles from 1,2-Dicarbonyls and 2-Hydroxyketones
Vinylalumination of activated carbonyl compounds
1,4-diazabicyclo[2.2.2]octane-catalyzed self- and cross-condensation of α-acetylenic ketones
Asymmetric synthesis of goniothalamin, hexadecanolide, massoia lactone, and parasorbic acid via sequential allylboration–esterification ring-closing metathesis reactions
A convenient synthesis of functionalized vinylepoxides
Lithium-B-Iso-2-ethylapopinocampheyl-9-borabicyclo[3.3.1]nonyl hydride as an improved reagent for asymmetric reduction of unhindered aliphatic ketones. Further evidence for the improved
A facile synthesis of chiral ω-allyl- and ω-n-propyllactones via asymmetric allylboration of formyl esters with B-allyldiisopinocampheylborane
B,B-dihaloterpenylboranes as reagents for the diastereo- and enantioselective synthesis of syn-aldols
Efficient general asymmetric syntheses of 3-substituted 1(3H)-isobenzofuranones in very high enantiomeric excess
An efficient preparation of optically pure C2-symmetric aromatic diols by the asymmetric reduction of diacylaromatic compounds with B-chlorodiisopinocampheylborane
Contrasting steric effects of the ketones and aldehydes in the reactions of the diisopinocampheyl enolborinates of methyl ketones with aldehydes