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Research ArticleEffect of Melt Temperature and Hold Pressure on the Weld-LineStrength of an Injection Molded Talc-Filled Polypropylene
Yuanxin Zhou and P. K. Mallick
Center for Lightweighting Automotive Materials and Processing, University of Michigan-Dearborn, Dearborn, MI 48128, USA
Correspondence should be addressed to Yuanxin Zhou; yzhou@mytu.tuskegee.edu
Received 12 June 2013; Revised 21 December 2013; Accepted 21 January 2014; Published 5 March 2014
Academic Editor: Mircea Chipara
Copyright Β© 2014 Y. Zhou and P. K. Mallick. This is an open access article distributed under the Creative Commons AttributionLicense, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properlycited.
Tensile stress-strain behavior coupledwith fractographywas used to investigate theweld-line strength of an injectionmolded 40w%talc-filled polypropylene. The relationship between processing conditions, microstructure, and tensile strength was established.Fracture surface of the weld line exhibited skin-core morphology with different degrees of talc particle orientations in the coreand in the skin. Experimental results also showed that the thickness of the core decreased and the thickness of the skins increasedwith increasing melt temperature and increasing hold pressure, which resulted in an increase of yield strength and yield strain withincreasing melt temperature and increasing hold pressure. Finally, a three-parameter nonlinear constitutive model was developedto describe the strain softening behavior of the weld-line strength of talc-filled polypropylene. The parameters in this model arethe modulus E, the strain exponentm, and the compliance factor π½. The simulated stress-strain curves from the model are in goodagreement with the test data, and bothm and π½ are functions of skin-core thickness ratio.
1. Introduction
Injectionmolding is one of themost commonmanufacturingprocesses in the polymer industry owing to its versatility,high production rate, short cycle time, and low percentage ofscrap. In addition, this process can be used for a large varietyof thermoplastic polymers. One of the defects observed ininjection molded parts is weld line, which is formed whentwo or more separate melt fronts traveling from differentdirections meet and join as the mold cavity is filled [1]. Thishappens in multigated molds but can also occur when amelt front is divided by inserts used in the mold to createholes or other openings in injection-molded parts. Since weldlines cause reduction in mechanical properties and visualdefects, many studies have been conducted to explain theweakness at the weld line. For example, Mielewski et al.[2] have investigated the weld-line morphology of injectionmolded polypropylene. Tomari et al. [3] have reported V-notch at weld lines in polystyrene injection moldings. Fellahiet al. [4] investigated the morphology of the weld regionin injection-molded high-density polyethylene/polyamide-6 blends. In the homopolymer system, the weakness of
weld line can be explained by incomplete bonding due toinefficient molecular entanglement at the interface, distur-bance of molecular orientation parallel to the flow direction,inefficient diffusion time, existence of voids, and V-shapenotch owing to entrapped air or contaminants and notchdepth [5, 6]. On the other hand, loss in weld-line strengthin filled and fiber reinforced polymers depends on the shapeof the reinforcement. Fisa and Rahmani [7] studied theweld-line strength of injection molded short fiber reinforcedpolypropylene. The weld line in their study was formed byflow around a circular insert in the mold. They found thattheweld-line zone, which extended throughout the thickness,was 2 to 8mm wide and the fibers in this zone were orientedin a plane parallel to the weld line. Savadori et al. [8] haveobserved significant reduction in strength for rubber filledPP/EP blends.
The purpose of this study was to determine the effectof two injection molding processing conditions on the weldline strength of talc-filled polypropylene. Polypropylene is asemicrystalline engineering thermoplastic and is known forits balance of strength, modulus, and chemical resistance.Both polypropylene and polypropylene matrix composite
Hindawi Publishing CorporationJournal of CompositesVolume 2014, Article ID 846962, 8 pageshttp://dx.doi.org/10.1155/2014/846962
2 Journal of Composites
32
91
25108
25
21Flow direction
Flow direction
Weld line
R25
R25
Figure 1: Schematic of the tension specimen with weld line at themid length (dimensions are in mm.).
have many potential applications in automobiles where creepresistance, stiffness, and some toughness are required in addi-tion to weight savings.Mechanical behavior of polypropyleneand its composites has been the subject of numerous studiesover the last few years. Some of these research studieshave investigated the relationship between the mechanicalbehavior of polypropylene, microstructure, and processingconditions. Diez-Gutierrez et al. [9] have reported thedynamic mechanical analysis of injection-molded discs ofpolypropylene and untreated and silane-treated talc-filledpolypropylene composites. Li and Cheung [10] have investi-gated the effect of mold temperature on the formation of πΌ/π½polypropylene blends in injection molding. All these resultsshow that the mechanical behavior of polypropylene and itscomposites is sensitive to the injection molding processingconditions. However, the effect of processing conditions ontheweld-line strength of talc-filled polypropylene compositeshas not been reported in the past.
2. Experimental
The material investigated in this study was a 40w% talc-filled polypropylene homopolymer. The average flow rateof this material was 6.8 g/10min. The melting point of thepolypropylene matrix was 160βC.The injection-molded platethickness was 2.5mm. A 90-ton Toyo injection moldingmachine was used to mold these plates. Three different melttemperatures were considered, namely, 209, 232, and 277βC.The peak injection pressure was 103MPa for all plates, but thehold pressurewas varied at three levels, namely, 27.6, 55.2, and82.7MPa.Themold temperature wasmaintained at 35βC.Thefollowing two groups of plates were injection molded:
(1) group I: hold pressure = 55.2MPa and melt tempera-ture = 209, 232, and 277βC,
(2) group II: melt temperature = 232βC and hold pressure= 27.6, 55.2, and 82.7MPa.
Dog-bone shaped specimens were prepared from the injec-tion molded plates with weld line. The specimen dimensionswere 100mm in overall length, 25mm in gage length, and12.7mm in gage width (Figure 1). The weld line, shown aslocated at themid length of the tensile specimens, was formedin the plates as the two melt fronts with the opposite flowdirections joined together at the mid length.
Uniaxial tensile tests were performed on an MTS ser-vohydraulic testing machine. Three specimens were tested
0.000 0.005 0.010 0.015Strain
0
5
10
15
20
At hold pressure 55.2 MPaMelt temperature
Stre
ss (M
Pa)
277βC232βC209βC
Figure 2: Effect of melt temperature on the stress-strain curves oftalc-filled polypropylene with weld line.
for each processing condition. The tensile tests were con-ducted at 1.25mm/min, which is equivalent to a strain rateof 0.05minβ1. Three parameters were evaluated from eachstress-strain curve: elastic modulus (πΈ), yield strength (π
π¦),
and yield strain (ππ¦). Elastic modulus or Youngβs modulus
is the initial slope of the stress-strain curve. Yield strengthis assumed to be the maximum stress observed in eachstress-strain diagram and the strain corresponding to theyield strength is the yield strain. During the tensile tests, allspecimens were observed to break at the weld zone.
3. Results and Discussion
Figures 2 and 3 show the tensile stress-strain curves oftalc-filled polypropylene with weld line under the differentprocessing conditions. It can be observed in these figures thatthe stress-strain diagrams are nonlinear even at strains lowerthan the yield strain. Each curve shows a maximum stress,which is assumed to be the yield strength of the material atthe weld line. After reaching the yield point, stress decreasedsteadily with strain until fracture occurred at the weld zone.
Figure 2 shows the effect of melt temperature on thetensile behavior of talc-filled polypropylene with weld line.The yield strength and yield strain increased by 9.3% and26.6%, respectively, as the melt temperature was increasedfrom 209βC to 277βC. But the effect of melt temperature onthemodulus is relatively small for the threemelt temperaturesinvestigated. Figure 3 shows the effect of hold pressure on thetensile behavior of talc-filled polypropylene with weld line.Increasing the hold pressure increases the yield strength, yield
Journal of Composites 3
Table 1: Weld-line tensile properties of talc filled polypropylene at different processing conditions.
Melttemperature(βC)
Hold pressure(MPa)
Modulus(GPa)
Yield strength(MPa)
Yield strain(%) π
π½(1/MPa)
209 55.2 6.56 (Β±0.23) 17.5 (Β±0.31) 0.79 (Β±0.04) 2.81 113232 55.2 6.84 (Β±0.19) 17.9 (Β±0.40) 0.91 (Β±0.04) 2.79 90.4277 55.2 6.94 (Β±0.20) 19.1 (Β±0.34) 1.00 (Β±0.07) 2.57 28.2232 27.6 6.71 (Β±0.24) 17.1 (Β±0.23) 0.86 (Β±0.04) 2.87 149232 82.7 6.92 (Β±0.20) 22.5 (Β±0.30) 1.31 (Β±0.03) 2.32 6.9
0
5
10
15
20
0.000 0.005 0.010 0.015Strain
0.020
25
Stre
ss (M
Pa)
Melt temperature is 232βCHold pressure (MPa)
Simulated results
82.8
55.2
27.6
Figure 3: Effect of hold pressure on the stress-strain curves of talc-filled polypropylene with weld line.
strain, and failure strain. But the modulus is not sensitive tohold pressure.The tensile properties ofmaterial with differentprocessing conditions are listed in Table 1.
From Figures 2 and 3 and Table 1, it can be concluded thatthe weld-line yield properties of talc-filled polypropylene aresensitive to the two processing conditions considered. Figures4 and 5 show that the variation of yield strength π
π¦and yield
strain ππ¦with melt temperature and hold pressure can be
represented by linear relationships. The following two linearrelationships are proposed:
ππ¦= ππ¦(π0, π0) [1 + π½melt (π β π
0)] β1 + π½pressure (π β π0)β ,
ππ¦= ππ¦(π0, π0) [1 + πΏmelt (π β π
0)] β1 + πΏpressure (π β π
0)β ,
(1)
20
18
16
14
200 220 240 260 280
2.0
1.5
1.0
0.5
Yiel
d str
engt
h (M
Pa)
Melt temperature (βC)
Yiel
d str
ain
(%)
Yield strength
Yield strain
Figure 4: Effect of melt temperature on the yield strength and yieldstrain.
Yiel
d str
engt
h (M
Pa)
Yiel
d str
ain
(%)
Yield strength
Yield strain
25
20
15
10
20 40 60 80 100
2.0
1.5
1.0
0.5
Hold pressure (MPa)
Figure 5: Effect of hold pressure on the yield strength and yieldstrain.
4 Journal of Composites
Strain
Talc filled polypropylene without weld line
Talc filled polypropylene with weld line
30
20
10
0
0.00 0.02 0.04 0.06 0.08 0.10
Stre
ss (M
Pa)
Figure 6: Stress-strain curves of talc-filled polypropylene with andwithout weld line.
where π½melt, πΏmelt and π½pressure, πΏpressure are melt temperaturesensitivity factor and hold pressure sensitivity factor. π
0
and π0are reference melt temperature and reference mold
pressure. ππ¦(π0, π0) and π
π¦(π0, π0) are the reference yield
strength and yield strain. Mathematically, π½melt, πΏmelt andπ½pressure, πΏpressure can be obtained by
π½melt =πππ/ππ(π0, π0)
ππor πΏmelt =
πππ/ππ(π0, π0)
ππ,
π½pressure =πππ/ππ(π0, π0)
ππor πΏpressure =
πππ/ππ(π0, π0)
ππ.
(2)
Assuming the reference melt temperature π0= 232βC and
reference hold pressure π0= 55.2MPa, one can obtain the
average values of the melt temperature sensitivity factor andthe hold pressure sensitivity factor as
π½melt = 0.024/βC, πΏmelt = 0.0029/βC
π½pressure = 0.098/MPa, πΏpressure = 0.0082/MPa.(3)
Figure 6 shows comparison of stress-strain curves fortalc-filled polypropylene with weld and without weld line.When the weld line was introduced, the yield strength,yield strain, and failure strain decreased by 35%, 73%, and92%, respectively. But the presence of weld line does notinfluence the modulus. After the yield strain is reached, theweld-line specimen breaks quickly, with very little additionaldeformation, indicating that the weld line is a weak zonein the material. According to Merah et al. [11], weld line isa brittle zone; the yield strain and failure strain for weld-line specimens have the same value. But in the talc-filledpolypropylene with weld line, 0.3β0.6% plastic strain was
(a)
(b)
(c)
Figure 7: Skin-core morphologyof the weld zone of talc-filledpolypropylene with weld-line injection molded at 55.2MPa holdpressure and 232βC melt temperature. (a): general view; (b): in thecore (white band); (c): in the skin (darker zone).
observed after yielding (as shown in Figures 2 and 3). InFigure 6, strain softening behavior was found for specimenswith and without weld line, which was conjectured to be dueto the strain softening behavior of polypropylene matrix [12].
To investigate the failure mechanism of the weld line, thefracture surfaces at the weld line were examined in a scanningelectron microscope. Fracture surface in Figure 7(a) exhibitsskin-core morphology with different degrees of talc particleorientations in the core and in the skin. A βwhite bandβ canbe observed in the center section of the fracture surface. Itconsists of talc particles with their surface oriented normalto the flow direction (Figure 7(b)). Nomatrix material can beseen adhering to the particles, indicating poor or no adhesion
Journal of Composites 5
(a)
(b)
Figure 8: Skin-core morphologyat the weld zone of talc-filledpolypropylene injection molded at two different hold pressures ((a):27.6MPa and (b): 82.7MPa) and 232βC melt temperature.
between the talc particles and the polypropylene matrix. Inthis area, the particles prevented the polymer chain to bridgeacross the weld line interface to form a strong bond and theorientation of the molecules is parallel to the weld-line ratherthan across it. Brittle fracture of talc particles can also beobserved in Figure 7(b). Talc particles outside the core tendto be parallel to the flow direction (same as the tensile testdirection). The color of this area is dark. Polymer chains inthis area can easily bridge across the weld line to form astrong bond between the two sides and the orientation ofthe molecules is normal to the weld line rather than parallelto it. Magnification of the fracture initiation site was shownin Figure 7(c). The matrix material was drawn in the tensilestress direction and fibrillated around the talc particles. Theductility of weld line can be mainly attributed to the largeelongation of polypropylene in the dark area.
The formation of skin-core morphology along the weldline of talc-filled polypropylene can be explained by referringto the viscous flow behavior of the liquid material as it flowsin the injection molding cavity. The shear stress in the flowchannel decreases from its highest value at the cavity wallsto a near-zero value at the center. Near the cavity walls, theplaty talc particles as well as the polymer molecules becomeoriented parallel to the flow direction as a result of the highshear stress in this area. But near the center, where the shearstress is the lowest and the flow velocity is the highest, theparticles turn to normal to the flow direction.
(a)
(b)
Figure 9: Skin-core morphologyat the weld zone of talc-filledpolypropylene injection molded at two different melt temperatures((a): 209βC and (b): 277βC) and 55.2MPa hold pressure.
Figures 8(a) and 8(b) show the fracture surfaces of thespecimens injection molded at hold pressures 27.6MPa and82.7MPa, respectively. The thickness of the βwhite bandβdecreased with the increasing hold pressure; more and moretalc particles tend to be parallel to the flow direction (tensiledirection). Figures 9(a) and 9(b) show the fracture surfaces ofthe specimens injection molded at melt temperatures 209βCand 277βC, respectively. Here also, the thickness of the βwhitebandβ decreased with increasing melt temperature.
FromFigures 7β9, it can be concluded that the total cross-sectional area of the weld line can be divided intowell bondedarea (dark zone) and nonbonded area (white band). If weassume that the total load is shared by the two areas, then theyield strength of the weld line can be expressed as
ππ¦= π0(π΄0β π΄π
π΄0
) + ππ(π΄π
π΄0
) , (4)
where π0, ππare the yield strengths of the injection molded
part without and with βwhite band.β π΄0is the total cross-
sectional area of the specimen andπ΄πis cross-sectional area
of the nonbonded white area. Furthermore, if we assumethat both dark and white bands have the same width as thespecimen width, the skin-core thickness ratio can be definedas
π π=π΄π
π΄0
=ππ
π0
, (5)
6 Journal of Composites
20
1.5
1.0
0.5Yiel
d str
engt
h (M
Pa)
Yiel
d str
ain
Yield strength
Yield strain
25
15
Thickness ratio
0.0
0.35 0.40 0.45 0.50 0.55 0.60
Figure 10: Effect of skin-core thickness ratio on weld-line yieldstrength and strain.
where ππ€and π
0are thickness of white band and thickness
of entire specimen. Equation (4) can then be rewritten as
ππ¦= π0β (π0β ππ) π π. (6)
Similarly, the yield strain of the weld line can be expressed as
ππ¦= π0β (π0β ππ) π π. (7)
Figure 10 shows the variation between yield strength, yieldstrain, and thickness ratio. Linear relationships are observedand the constants were simulated by using the least squaremethod
π0= 32.6MPa, π
π= 5.4MPa,
π0= 2.30%, π
π= β0.3%.
(8)
Small value in ππand negative value in π
πdeclare the loading
bearing capability of the βwhite bandβ can be ignored.
4. One-Dimensional Constitutive Equation
In this section, we apply a one-dimensional constitutiveequation that was developed earlier [13] for welded talc-filledpolypropylene. The total strain is assumed to be additivelydecomposed into elastic and inelastic parts,
π = ππ+ ππ, (9)
where ππand π
πrepresent the elastic and inelastic strains,
respectively.The elastic strain is assumed to be path indepen-dent, such that
ππ=π
πΈ, (10)
where πΈ is elastic modulus of the material and π is the stress.The inelastic strain, π
π, is assumed to be a function of stress
and total strain in the following way:
ππ= π½πππ. (11)
Substituting (10) and (11) into (9) gives
π =πΈπ
1 + πΈπ½ππ. (12)
Equation (12) represents the constitutive equation. At smallstrains, πΈπ½ππ βͺ 1, one can obtain
ππ
ππ=πΈ + (1 β π)πΈ2π½ππ
[1 + πΈπ½ππ]2
β πΈ. (13)
Therefore, at very small strains, (12) approximates an elasticmaterial. At large strains, πΈπ½ππ β« 1, and (12) can besimplified as
π =
{{{{{{{{{{{{{{{
1
π½π1βπ π < 1 Strain Hardening,
1
π½π = 1 Critical Value,
1
π½π1βπ π > 1 Strain Softening.
(14)
To determine the parameters in the constitutive equation, (12)is written as
π
π= π½ππ +
1
πΈ, (15)
ln( ππβ1
πΈ) = lnπ½ + π ln π. (16)
Equation (16) represents a linear equation when ln[π/π β1/πΈ] is plotted against ln π. From the slope and intercept of thelinear plot,π and π½ of the material can be obtained by usingthe least square method. Plots of ln[π/π β 1/πΈ] versus ln π oftalc-filled polypropylene with weld line, shown in Figure 11,are linear at different processing conditions. The values of πand π½ obtained from these plots are listed in Table 1.
Figure 12 shows the compliance factor π½ and strainexponent π plotted as a function of thickness ratio. It canbe observed from this figure that both π and π½ increasedwith increasing thickness ratio. Their relationships can beexpressed by the following equations:
π = 1.22 + 2.87π π,
π½ (1/MPa) = 0.014 exp (7.68π π) .
(17)
Substituting elastic modulus πΈ, compliance factor π½, andstrain exponent π into (12), the simulated stress-strain plotswere drawn in Figures 2 and 3 and they seem to fit theexperimental data well.
5. Conclusions
Weld-line yield strength, yield strain, and failure strain oftalc-filled polypropylene increase with increasing melt tem-perature and increasing hold pressure.The effects of these twoinjection molding process parameters are explained in termsof their influence on the skin-core morphology observed onthe fracture surfaces in the weld zone.The core contained talc
Journal of Composites 7
Strain π
Hold pressure (Psi)
π/πβ1/E
(1/M
Pa)
82.8
55.2
26.7
1E β 3
1E β 4
1E β 5
1E β 3 1E β 2 1E β 1
(a)
Strain π
277
232
209
π/πβ1/E
(1/M
Pa)
1E β 3
1E β 4
1E β 5
1E β 3 1E β 2 1E β 1
Melt temperature (βC)
(b)
Figure 11: Plots of [π/π β 1/πΈ] versus π in log-log scale for 40w% talc-filled polypropylene with weld line ((a): with different hold pressure;(b): with different melt temperature).
150
100
50
0
0.35 0.40 0.45 0.50 0.55 0.60
4.0
3.5
3.0
2.5
2.0
Com
plia
nce f
acto
r,π½
(1/M
Pa)
Thickness ratio
Stra
in ex
pone
nt (m
)π½
m
Figure 12: Compliance factor π½ and strain exponentπ as a functionof skin-core thickness ratio π
π
.
particles that were oriented normal to the loading directionand the skins contained talc particles oriented parallel tothe loading direction. The thickness of the core decreasedand the thickness of the skins increased with increasing melttemperature and increasing hold pressure. A three-parameternonlinear constitutive model is applied to describe the stress-strain curves of the talc-filled polypropylene.The parameters
in this model are the modulus πΈ, the strain exponent π, andthe compliance factor π½. Both π and π½ are sensitive to theskin-score thickness ratio.
Conflict of Interests
The authors declare that there is no conflict of interestsregarding the publication of the paper.
References
[1] N. Mekhilef, A. Ait-Kadi, and A. Ajji, βWeld lines in injection-moulded immiscible blends:model predictions and experimen-tal results,β Polymer, vol. 36, no. 10, pp. 2033β2042, 1995.
[2] D. F. Mielewski, D. R. Bauer, P. J. Schmitz, and H. Van Oene,βWeld line morphology of injection molded polypropylene,βPolymer Engineering and Science, vol. 38, no. 12, pp. 2020β2028,1998.
[3] K. Tomari, S. Tonogai, T. Harada et al., βV-notch at weld linesin polystyrene injection moldings,β Polymer Engineering andScience, vol. 30, no. 15, pp. 931β936, 1990.
[4] S. Fellahi, B. D. Favis, and B. Fisa, βMorphological stabilityin injection-moulded high-density polyethylene/polyamide-6blends,β Polymer, vol. 37, no. 13, pp. 2615β2626, 1996.
[5] J. K. Kim, S. H. Park, T. O. Hyun, and H. K. Jeon, βThe effectof weld-lines on the morphology and mechanical propertiesof amorphous polyamide/poly(ethylene-ran-propylene) blendwith various amounts of an in situ compatibilizer,β Polymer, vol.42, no. 5, pp. 2209β2221, 2001.
8 Journal of Composites
[6] O.G. Ersoy andN.Nugay, βAnew approach to increaseweld linestrength of incompatible polymer blend composites: selectivefiller addition,β Polymer, vol. 45, no. 4, pp. 1243β1252, 2004.
[7] B. Fisa andM.Rahmani, βWeldline strength in injectionmoldedglass fiber-reinforced polypropylene,β Polymer Engineering &Science, vol. 31, no. 18, pp. 1330β1336, 1991.
[8] A. Savadori, A. Pelliconi, and D. Romanini, βWeld line resis-tance in polypropylene composites,β Plastics and Rubber Pro-cessing and Applications, vol. 3, no. 3, pp. 215β221, 1983.
[9] S. Diez-Gutierrez, M. A. Rodriguez-Perez, J. A. De Saja, and J.I. Velasco, βDynamic mechanical analysis of injection-mouldeddiscs of polypropylene and untreated and silane-treated talc-filled polypropylene composites,β Polymer, vol. 40, no. 19, pp.5345β5353, 1999.
[10] J. X. Li and W. L. Cheung, βEffect of mould temperature on theformation of πΌ/π½ polypropylene blends in injection moulding,βJournal of Materials Processing Technology, vol. 63, no. 1β3, pp.472β475, 1997.
[11] N. Merah, M. Irfan-ul-Haq, and Z. Khan, βTemperature andweld-line effects on mechanical properties of CPVC,β Journalof Materials Processing Technology, vol. 142, no. 1, pp. 247β255,2003.
[12] Y. Zhou andP. K.Mallick, βEffects of temperature and strain rateon the tensile behavior of unfilled and talc-filled polypropylene.Part I: experiments,β Polymer Engineering and Science, vol. 42,no. 12, pp. 2449β2460, 2002.
[13] Y. Zhou and P. K.Mallick, βEffects of temperature and strain rateon the tensile behavior of unfilled and talc-filled polypropylene.Part II: constitutive equation,β Polymer Engineering and Science,vol. 42, no. 12, pp. 2461β2470, 2002.
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