Post on 04-Apr-2018
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Tab 1 - Mass Calibration (Mass Spectrometer [MS] Instrument Resolution)
Peak Resolution for the Perfluorokerosene (PFK) Reference Ion resolution must be > 10,000 resolving power
(e.g. 10% Valley)
Resolving Power = A/(A-B)
where: A = mass/charge (e.g. [m/z] ration signal {380.97604})
B = peak width of ion at 5% of maximum signal (e.g. 380.93795)
SDG Experiment: Function: ppm Volts File: Date Ref. Time A B
Resolving
Power Pass/FailG578-34 EXP_DB5MS 3 200 0.0470 Res_Check 11-Jul-2009 PFK 9:24 380.97604 380.93795 10,001.99632 Pass
G578-35 EXP_DB5MS 1 200 0.0508 A09JUL09A_L 9-Jul-2009 PFK 17:39 380.97604 380.93795 10,001.99632 Pass
G578-35 EXP_DB5MS 2 200 0.0617 A09JUL09A_L 9-Jul-2009 PFK 17:39 380.97604 380.93795 10,001.99632 Pass
G578-35 EXP_DB5MS 3 200 0.0577 A09JUL09A_L 9-Jul-2009 PFK 17:40 380.97604 380.93795 10,001.99632 Pass
G578-35 EXP_DB5MS 1 200 0.0466 Res_Check 10-Jul-2009 PFK 5:45 380.97604 380.93795 10,001.99632 Pass
G578-35 EXP_DB5MS 2 200 0.0529 Res_Check 10-Jul-2009 PFK 5:46 380.97604 380.93795 10,001.99632 Pass
G578-35 EXP_DB5MS 3 200 0.2410 Res_Check 10-Jul-2009 PFK 5:47 380.97604 380.93795 10,001.99632 Pass
G578-36 EXP_DB5MS 1 200 0.0695 A28JUL09A_L 28-Jul-2009 PFK 14:42 380.97604 380.93795 10,001.99632 Pass
G578-36 EXP_DB5MS 2 200 0.0944 A28JUL09A_L 28-Jul-2009 PFK 14:42 380.97604 380.93795 10,001.99632 Pass
G578-36 EXP_DB5MS 3 200 0.1007 A28JUL09A_L 28-Jul-2009 PFK 14:43 380.97604 380.93795 10,001.99632 Pass
G578-36 EXP_DB5MS 1 200 0.0767 Res_Check 29-Jul-2009 PFK 2:50 380.97604 380.93795 10,001.99632 Pass
G578-36 EXP_DB5MS 2 200 0.0915 Res_Check 29-Jul-2009 PFK 2:51 380.97604 380.93795 10,001.99632 Pass
G578-36 EXP_DB5MS 3 200 0.0884 Res_Check 29-Jul-2009 PFK 2:52 380.97604 380.93795 10,001.99632 Pass
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Tab 2 - Spot Check Calculations Where:Qis = internal std. added (pg)
Analyte conc. [ug/L]= [Qis x (An1+An
2)]/[(Ais
1+Ais
2) x RRFn x W] An
1and An
2= area of primary and secondary analyte ions
Ais1
and Ais2
= area of primary and secondary standard ions (13
C)
RRFn = Relative Response Factor of analyteW = Dry weight of sample extracted (grams)
SDG
Calibrated
using Lab Std# Analyte Qis An
1An
2
.
before
drying(g)
%solids W Ais
1Ais
2RRFn
SGSLab
G578-29-1B 20 1,2,3,7,8,9-HxCDD (#5) 2000 4.59E+05 3.67E+05 11.48 81.2 9.32 4.12E+07 3.30E+07 0.9649 2.48
G578-29-1B 21 1,2,3,4,6,7,8-HpCDD (#6) 2000 9.65E+06 9.25E+06 11.48 81.2 9.32 3.06E+07 2.90E+07 1.0612 64.1
G578-29-1B 22 OCDD (#7) 4000 3.31E+08 3.70E+08 11.48 81.2 9.32 4.67E+07 5.23E+07 1.0643 2860
G578-29-1B 23 2,3,7,8-TCDF (#8) 2000 2.37E+05 2.64E+05 11.48 81.2 9.32 5.82E+07 7.36E+07 1.0368 EMPC
G578-33-1B 20 1,2,3,7,8,9-HxCDD (#5) 2000 3.49E+05 2.84E+05 10.54 85.1 8.97 4.90E+07 3.88E+07 0.9649 1.67
G578-33-1B 21 1,2,3,4,6,7,8-HpCDD (#6) 2000 8.07E+06 7.86E+06 10.54 85.1 8.97 3.25E+07 3.08E+07 1.0612 52.9
G578-33-1B 22 OCDD (#7) 4000 3.84E+08 4.30E+08 10.54 85.1 8.97 5.19E+07 5.79E+07 1.0643 3110
G578-33-1B 23 2,3,7,8-TCDF (#8) 2000 1.76E+05 2.52E+05 10.54 85.1 8.97 7.61E+07 9.56E+07 1.0368 0.538
G578-34-1B 20 1,2,3,7,8,9-HxCDD (#5) 2000 2.77E+05 2.40E+05 11.66 83.8 9.77 5.67E+07 4.50E+07 0.9649 1.08
G578-34-1B 21 1,2,3,4,6,7,8-HpCDD (#6) 2000 8.10E+06 7.84E+06 11.66 83.8 9.77 3.75E+07 3.53E+07 1.0612 42.2
G578-34-1B 22 OCDD (#7) 4000 5.24E+08 5.87E+08 11.66 83.8 9.77 6.02E+07 6.71E+07 1.0643 3360
G578-34-1B 23 2,3,7,8-TCDF (#8) 2000 1.09E+05 1.39E+05 11.66 83.8 9.77 5.06E+07 6.40E+07 1.0368 0.428
G578-35-1B 20 1,2,3,7,8,9-HxCDD (#5) 2000 3.75E+05 3.04E+05 11.72 88.4 10.36 5.50E+07 4.37E+07 0.9649 1.38
G578-35-1B 21 1,2,3,4,6,7,8-HpCDD (#6) 2000 8.92E+06 8.46E+06 11.72 88.4 10.36 3.94E+07 3.72E+07 1.0612 41.2
G578-35-1B 22 OCDD (#7) 4000 5.72E+08 6.40E+08 11.72 88.4 10.36 6.42E+07 7.13E+07 1.0643 3240
G578-35-1B 23 2,3,7,8-TCDF (#8) 2000 2.24E+05 2.75E+05 11.72 88.4 10.36 8.41E+07 1.06E+08 1.0368 0.488
G578-36-1B 20 1,2,3,7,8,9-HxCDD (#5) 2000 1.00E+05 7.81E+04 10.14 67.6 6.85 4.95E+07 3.93E+07 0.9649 0.607
G578-36-1B 21 1,2,3,4,6,7,8-HpCDD (#6) 2000 1.49E+06 1.46E+06 10.14 67.6 6.85 3.44E+07 3.29E+07 1.0612 12
G578-36-1B 22 OCDD (#7) 4000 6.28E+07 7.05E+07 10.14 67.6 6.85 4.41E+07 4.91E+07 1.0643 783
G578-36-1B 23 2,3,7,8-TCDF (#8) 2000 1.75E+05 2.31E+05 10.14 67.6 6.85 7.57E+07 9.57E+07 1.0368 0.668
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Tab 2 - Spot Check Calculations Where:Qis = internal std. added (pg)
Analyte conc. [ug/L]= [Qis x (An1+An
2)]/[(Ais
1+Ais
2) x RRFn x W] An
1and An
2= area of primary and secondary analyte ions
Ais1
and Ais2
= area of primary and secondary standard ions (13
C)
RRFn = Relative Response Factor of analyteW = Dry weight of sample extracted (grams)
SDG
Calibrated
using Lab Std# Analyte Qis An
1An
2
.
before
drying(g)
%solids W Ais
1Ais
2RRFn
SGSLab
Note: per Method 8290, if a 2,3,7,8-TCDF isomer is detected on the DB-5
column, it must be confirmed using a DB-225 column; the result must be
reported from the DB-225 column (this relates to DB-5 isomer co-elution
issues)
G578-29-1B & G578-2C - the 2,3,7,8-TCDF isomer result was
flagged as EMPC with no second column confirmation
G578-30-1B and -2B / G578-33-1B and -2B / G578-34-1B and -2B /
G578-35-2B / G578-36-1B, -2B, -3B, -4B, -5B the 2,3,7,8-TCDF
isomer had positive hit results but there was no confirmation on the
DB-255 column reported.
Note: per SGS lab "DB-225 confirmation only used for
2,3,7,8-TCDF if the concentration or EMPC value is 1
pg/g for a 10 gram dry wt. sample"
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na y e
conc.
[ug/L]Shaw
2.475
64.114
2855
0.787
1.666
52.878
3106
0.536
1.078
42.233
3357
0.427
1.376
41.274
3245
0.489
0.606
12.052
784
0.667
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Tab 3 - ION PAIR CHECK - Selected Ion Current Profile (SICP)
Descriptor:
Analyte:
Ion ID:
SDG File Acq. Date Time Sample ID Accurate Mass/Charge [m/z] Ratio:
G578-29-1B A07OCT08A 7-Oct-08 17.23 3 Time (min/sec):
G578-29-1B A07OCT08A 7-Oct-08 17.23 3G578-29-1B A07OCT08A 7-Oct-08 17.23 3
G578-30-1B A06JUL09C 6-Jul-09 16.41.32 2
G578-30-1B A06JUL09C 6-Jul-09 16.41.32 2
G578-30-1B A06JUL09C 6-Jul-09 16.41.32 2
G578-30-1B A06JUL09C 6-Jul-09 16.41.32 2
G578-33-1B A09JUL09A 9-Oct-08 17.59.38 10
G578-33-1B A09JUL09A 9-Oct-08 17.59.38 10
G578-33-1B A09JUL09A 9-Oct-08 17.59.38 10
G578-33-1B A09JUL09A 9-Oct-08 17.59.38 10
G578-33-1B A09JUL09A 9-Oct-08 17.59.38 10G578-33-1B A09JUL09A 9-Oct-08 17.59.38 10
G578-34-1B A09JUL09A_5 11-Jul-09 10.15.38 2
G578-34-1B A09JUL09A_5 11-Jul-09 10.15.38 2
G578-34-1B A09JUL09A_5 11-Jul-09 10.15.38 2
G578-34-1B A09JUL09A_5 11-Jul-09 10.15.38 2
G578-34-1B A09JUL09A_5 11-Jul-09 10.15.38 2
G578-34-1B A09JUL09A_5 11-Jul-09 10.15.38 2
G578-34-1B A09JUL09A_5 11-Jul-09 10.15.38 2
G578-34-1B A09JUL09A_5 11-Jul-09 10.15.38 2
G578-35-1B A09JUL09A_5 11-Jul-09 11.52.17 4
G578-35-1B A09JUL09A_5 11-Jul-09 11.52.17 4
G578-35-1B A09JUL09A_5 11-Jul-09 11.52.17 4
G578-35-1B A09JUL09A_5 11-Jul-09 11.52.17 4
G578-35-1B A09JUL09A_5 11-Jul-09 11.52.17 4
G578-35-1B A09JUL09A_5 11-Jul-09 11.52.17 4
G578-35-1B A09JUL09A_5 11-Jul-09 11.52.17 4
G578-35-1B A09JUL09A_5 11-Jul-09 11.52.17 4
G578-36-1B A28JUL09A 28-Jul-09 17.58.11
G578-36-1B A28JUL09A 28-Jul-09 17.58.11
G578-36-1B A28JUL09A 28-Jul-09 17.58.11
G578-36-1B A28JUL09A 28-Jul-09 17.58.11G578-36-1B A28JUL09A 28-Jul-09 17.58.11
G578-36-1B A28JUL09A 28-Jul-09 17.58.11
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2 2 3 3 3 3 3 3 4 4 4
HpCDPE PFK HxCDD HxCDD HxCDD (S) HxCDD (5) OCDPE PFK HpCDD HpCDD HpCDD (S)
M+2 LOCK M+2 M+4 M+2 M+4 M+4 LOCK M+2 M+4 M+2
409.7974 354.9792 389.8156 391.8127 401.8559 403.8529 445.7555 430.9728 423.7767 425.7737 435.8169
??? ??? 37.03 37.03 40.34 40.35 40.33
37.10 37.10 37.09 37.09
37.25 37.25 37.24 37.24
35.42 35.42 35.41 35.41 38.48 38.48 38.47
??? ??? 35.46 35.46
36.00 36.00 35.59 35.59
34.34 34.34 37.57 37.57
34.58 34.59 38.47 38.47 38.46
35.11 35.10
35.46 35.46 35.45 35.45
36.00 36.00 35.59 35.59
34.34 34.34 38.03 38.03
34.45 34.45 38.53 38.53 38.52
35.11 35.12
35.25 35.25
36.02 36.02 36.02 36.02
36.14 36.14 36.13 36.13
34.35 34.35 37.58 37.5735.01 35.01 38.48 38.48 38.47
35.13 35.13
35.45 35.45
35.50 35.50 35.50 35.50
36.03 36.03 36.03 36.03
36.22 36.21
34.33 34.33 37.56 37.56
35.10 35.10 38.47 38.47 38.46
35.40 35.40
35.45 35.45
35.59 36.00 35.59 35.59
36.20 36.20
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4 4 4 5 5 5 5 1 1
HpCDD (S) NCDPE PFK OCDD OCDD DCDPE PFK TCDF TCDF
M+4 M+4 LOCK M+2 M+4 M+4 LOCK M M+2
437.8140 479.7165 430.9728 457.7377 459.7348 513.6775 442.9728 303.9016 305.8987
40.33 45.00 45.00 31.06 31.06
38.47 42.39 42.39 28.45 28.45
42.38 42.38 25.26 25.26
38.46 28.45 28.45
29.07 29.06
42.46 42.46 25.27 25.26
38.52 27.48 27.49
28.46 28.45
29.07 29.06
30.50 30.49
42.40 42.40 25.27 25.2638.47 27.20 27.21
27.48 27.48
28.45 28.45
29.06 29.06
30.50 30.49
42.38 42.38 25.25 25.25
38.46 27.20 27.20
27.47 27.47
28.44 28.45
30.50 30.49
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1 1 2 2 2 2 3 3 3 3 4
TCDF (S) TCDF (S) PeCDF PeCDF PeCDF (S) PeCDF (S) HxCDF HxCDF HxCDF (S) HxCDF (S) HpCDF
M M M+4 M+2 M+2 M+4 M+2 M+4 M M+2 M+2
315.9419 317.9389 341.8567 339.8597 351.9000 353.8970 373.8208 375.8178 383.8639 385.8610 407.7818
31.04 31.04 33.37 33.37 33.36 36.27 36.27 36.26 36.26 39.17
34.13 34.13 34.13 36.56 36.57 36.56 36.56 41.17
37.45 37.44 37.44 37.44
28.44 28.44 33.18 33.18 33.17 33.17 ??? ??? 35.02 35.02 37.40
32.32 32.32 32.32 32.32 35.08 35.08 35.08 35.08 39.23
35.36 35.36
33.07 33.07 33.07 33.07 36.17 36.17
31.55 31.56 34.11 34.11 37.40
28.43 28.43 32.01 32.01 34.18 34.18 38.07
32.20 32.20 34.41 34.41
32.32 32.32 32.32 32.32 35.03 35.02 35.02 35.02
32.40 32.40 35.35 35.35
33.07 33.07 33.07 33.06 35.08 35.07
32.01 32.01 34.10 34.10 37.47
32.22 32.22 34.19 34.18 38.13
32.33 32.33 32.34 32.33 34.27 34.27
32.42 32.42 34.41 34.41
33.10 33.09 33.10 33.10 34.51 34.51
30.54 30.53 35.16 35.15 35.15 35.15
35.54 35.54
35.21 35.21
31.59 31.59 34.12 34.12 37.4032.20 32.20 34.19 34.19 38.08
32.32 32.32 32.31 32.31 34.34 34.34
28.44 28.44 32.41 32.40 34.42 34.43
33.03 33.03 35.05 35.05 35.04
33.07 33.07 33.07 33.07 35.10 35.10
30.53 30.53 35.39 35.39
36.19 36.19
31.58 31.59 34.10 34.10 37.39
32.13 32.13 34.17 34.17 38.06
32.19 32.19 34.40 34.40
28.43 28.42 32.32 32.32 35.02 35.02 35.01 35.01
33.07 33.07 33.06 33.06 35.06 35.06
30.51 30.51 35.35 35.35
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4 4 4 5 5 5 5
HpCDF HpCDF (S) HpCDF OCDF OCDF OCDD (S) OCDD (S)
M+4 M M+2 M+2 M+4 M+2 M+4
409.7788 417.8250 419.8220 441.7428 443.7399 469.7780 471.7750
39.17 39.16 39.16 44.59 44.59
41.17 41.17 41.17 45.19 45.18 44.59 44.59
37.40 37.39 37.39 42.54 42.54 42.38 42.38
39.23 39.22 39.22 42.38 42.38
37.40 37.39 37.39 42.38 42.40 42.37 42.37
38.06 42.53 42.53
39.22 39.22 42.37 42.37
37.46 37.46 37.46 42.45 42.45
38.13 42.47 42.47 42.45 42.45
39.27 39.27 43.01 43.01
37.40 37.39 37.39 42.41 42.41 42.39 42.3938.08 42.54 42.54
39.22 39.22
42.39 42.39
37.39 37.38 37.38 42.36 42.37 42.37
38.06 42.53 42.53
39.22 39.21
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Tab 4 - Estimated Detection Limit (EDL)
EDL [ug/L]= [(Hx1+Hx
2) x Qis x Df x 2.5]/[(His
1+His
2) x RRFn x W] Where:
Hx1
and Hx2
= peak height of noise for primary and secondary ana
Lab using a correction factor of 3 and not 2.5 - see SGS e-mail Qis = internal std. added (pg)
Note: Shaw calc. correct for G578-30 1,2,3,7,8-PeCDD (#2) - see e-mail Df = Dilution factor
Value of 3 used instead of 2.5 for consistency with SGS Lab Calculations Qrs = recovery std. added (pg)
His1
and His2
= peak height of noise for primary and secondary inte
RRFn = Relative Response Factor of analyte
W = Dry weight of sample extracted
SDG
Estimated Detection
Limit (EDL) Hx1
Hx2
(see
note) Qis Df His1
His2
RRFn W (g)
Wt.
before
drying
(g) % solids
SGS
Lab
Shaw (m
calculati
G578-29-1B 2,3,7,8-TCDD (#1) 3.87E+03 4.93E+03 3 2000 1 7.66E+06 9.74E+06 1.0087 9.32 11.48 81.2 0.323 0.32
G578-30-1B 2,3,7,8-TCDD (#1) 4.38E+03 5.42E+03 3 2000 1 7.61E+06 9.57E+06 1.0087 9.90 11.50 86.1 0.342 0.34
G578-30-1B 1,2,3,7,8-PeCDD (#2) 5.20E+03 5.54E+03 3 2000 1 1.90E+07 1.15E+07 1.0517 9.90 11.50 86.1 0.505 0.20
G578-33-1B 2,3,7,8-TCDD (#1) 3.70E+03 4.11E+03 3 2000 1 8.88E+06 1.13E+07 1.0087 8.97 10.54 85.1 0.257 0.25
G578-33-1B 1,2,3,7,8,9-HxCDF (#14) 6.07E+03 4.64E+03 3 2000 1 1.47E+07 2.69E+07 0.9220 8.97 10.54 85.1 0.558 0.18
G578-34-1B 2,3,7,8-TCDD (#1) 4.86E+03 5.10E+03 3 2000 1 8.71E+06 1.10E+07 1.0087 9.77 11.66 83.8 0.316 0.30
G578-34-1B 1,2,3,7,8,9-HxCDF (#14) 4.91E+03 5.24E+03 3 2000 1 1.30E+07 2.52E+07 0.9220 9.77 11.66 83.8 0.512 0.17
G578-35-1B 2,3,7,8-TCDD (#1) 5.13E+03 4.90E+03 3 2000 1 1.08E+07 1.38E+07 1.0087 10.36 11.72 88.4 0.235 0.23
G578-35-1B 1,2,3,7,8,9-HxCDF (#14) 7.12E+03 7.00E+03 3 2000 1 1.60E+07 2.96E+07 0.9220 10.36 11.72 88.4 0.482 0.19
G578-36-1B 2,3,7,8-TCDD (#1) 4.28E+03 4.73E+03 3 2000 1 9.25E+06 1.18E+07 1.0087 6.85 10.14 67.6 0.372 0.37
G578-36-1B 1,2,3,7,8,9-HxCDF (#14) 6.63E+03 6.51E+03 3 2000 1 1.32E+07 2.52E+07 0.9220 6.85 10.14 67.6 0.729 0.32
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Tab 5 - Estimated Maximum Possible Concentration (EMPC)
Where:
EMPC [ug/L]= [(Ax1+Ax
2) x Qis x Df]/[(Ais
1+Ais
2) x RRFis x W] Ax
1and Ax
2= area of primary and secondary interna
Qis = recovery std. added (pg)
Ais1
and Ais2
= area of primary and secondary recove
RRFis = Relative Response Factor of Internal S
Note: SGS Lab incorrectly calculated EMPC for 1,2,3,7,8-PeCDF (see e-mail) Qis = internal std. added (pg)
W = Dry weight of sample extracted
SDG Analyte Ax1
Ax2
Qis (pg) Df Ais1
Ais2
RRFnWt. beforedrying (g) % solids W (g)
SGSLab EMPC [ug/
G578-29-1B 1,2,3,7,8-PeCDD (#2) 2.66E+05 1.39E+05 2000 1 4.73E+07 2.97E+07 1.0517 11.48 81.20 9.32 1.080 1.073
G578-30-1B 1,2,3,4,6,7,8-HpCDF (#15) 5.74E+04 4.42E+04 2000 1 2.06E+07 4.67E+07 1.3752 11.50 86.10 9.90 0.222 0.222
G578-33-1B 1,2,3,7,8-PeCDF (#9) 7.71E+04 6.20E+04 2000 1 9.12E+07 5.75E+07 0.9873 10.54 85.10 8.97 0.212 0.211
G578-33-1B 2,3,4,6,7,8-HxCDF (#13) 1.18E+05 1.12E+05 2000 1 3.90E+07 7.38E+07 1.0650 10.54 85.10 8.97 0.426 0.427
G578-34-1B 1,2,3,7,8-PeCDF (#9) 5.01E+04 4.57E+04 2000 1 8.93E+07 5.62E+07 0.9873 11.66 83.8 9.77 0.137 0.137
G578-34-1B 2,3,4,6,7,8-HxCDF (#13) 7.34E+04 4.79E+04 2000 1 3.96E+07 7.54E+07 1.0650 11.66 83.8 9.77 0.203 0.203
G578-35-1B 1,2,3,7,8-PeCDF (#9) 9.52E+04 6.09E+04 2000 1 1.10E+08 6.99E+07 0.9873 11.72 88.4 10.36 0.596 0.170
G578-35-1B 1,2,3,7,8,9-HxCDF (#14) 4.12E+04 2.86E+04 2000 1 4.37E+07 8.22E+07 0.9220 11.72 88.4 10.36 0.116 0.116
G578-36-1B 1,2,3,7,8-PeCDF (#9) 3.52E+04 3.03E+04 2000 1 8.34E+07 5.21E+07 0.9873 10.14 67.6 6.85 0.143 0.143
G578-36-1B 2,3,4,7,8-PeCDF (#10) 9.08E+04 7.42E+04 2000 1 8.34E+07 5.21E+07 1.0154 10.14 67.6 6.85 0.350 0.350
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Tab 6 - Internal Standard % RecoveriesInternal Std. % Recovery (%Ris)= [(Ais +AiS ) x Qrs x 100]/[(Aris +Ars ) x RRFis x Qis]
Ais1
and Ais2
= area of primary and secondary internal st
Where: Qrs = recovery std. added (pg)
Ars1
and Ars2
= area of primary and secondary recovery
RRFis = Relative Response Factor of Internal Std.
Qis = internal std. added (pg)
SDG Analyte Ais1
(Ion 1) Ais2
(Ion 2) Qrs(pg) Ars1
(Ion 1) Ars2
(Ion 2) RRFis Qis(pg)
SGS (lab
calculation)
% Ris
manu
G578-29-1B13
C 2,3,7,8-TCDD (#18) 4.19E+07 5.30E+07 2000 4.53E+07 5.72E+07 1.1153 2 000 83.0 8
G578-29-1B13
C 1,2,3,7,8-PeCDD (#19) 4.73E+07 2.97E+07 2000 4.53E+07 5.72E+07 0.8155 2 000 92.1 9
G578-29-1B13
C 1,2,3,6,7,8-HxCDD (#20) 4.12E+07 3.39E+07 2000 4.76E+07 3.79E+07 1.0442 2 000 83.1 8
G578-29-1B13
C 1,2,3,4,6,7,8-HpCDD (#21) 3.06E+07 2.90E+07 2000 4.76E+07 3.79E+07 0.7878 2 000 88.5 8
G578-29-1B13
C OCDD (#22) 4.67E+07 5.23E+07 2000 4.76E+07 3.79E+07 0.6269 4 000 92.2 9
G578-30-1B13
C 2,3,7,8-TCDD (#18) 4.09E+07 5.19E+07 2000 4.66E+07 5.92E+07 1.1153 2 000 78.6 7
G578-30-1B13
C 1,2,3,7,8-PeCDD (#19) 4.87E+07 3.01E+07 2000 4.66E+07 5.92E+07 0.8155 2 000 91.3 9
G578-30-1B13
C 1,2,3,6,7,8-HxCDD (#20) 4.59E+07 3.65E+07 2000 4.93E+07 3.97E+07 1.0442 2 000 88.7 8
G578-30-1B13
C 1,2,3,4,6,7,8-HpCDD (#21) 3.06E+07 2.92E+07 2000 4.93E+07 3.97E+07 0.7878 2 000 85.4 8
G578-30-1B13
C OCDD (#22) 4.43E+07 4.96E+07 2000 4.93E+07 3.97E+07 0.6269 4 000 84.1 8
G578-33-1B13
C 2,3,7,8-TCDD (#18) 4.65E+07 5.90E+07 2000 5.39E+07 6.80E+07 1.1153 2 000 76.6 7
G578-33-1B13
C 1,2,3,7,8-PeCDD (#19) 5.50E+07 3.48E+07 2000 5.39E+07 6.80E+07 0.8155 2 000 90.4 9G578-33-1B
13C 1,2,3,6,7,8-HxCDD (#20) 4.90E+07 3.88E+07 2000 5.20E+07 4.14E+07 1.0442 2 000 90.1 9
G578-33-1B13
C 1,2,3,4,6,7,8-HpCDD (#21) 3.25E+07 3.08E+07 2000 5.20E+07 4.14E+07 0.7878 2 000 86.1 8
G578-33-1B13
C OCDD (#22) 5.19E+07 5.79E+07 2000 5.20E+07 4.14E+07 0.6269 4 000 93.7 9
G578-34-1B13
C 2,3,7,8-TCDD (#18) 5.02E+07 6.38E+07 2000 6.51E+07 8.21E+07 1.1153 2 000 69.5 6
G578-34-1B13
C 1,2,3,7,8-PeCDD (#19) 5.12E+07 3.24E+07 2000 6.51E+07 8.21E+07 0.8155 2 000 69.6 6
G578-34-1B13
C 1,2,3,6,7,8-HxCDD (#20) 5.67E+07 4.50E+07 2000 6.04E+07 4.82E+07 1.0442 2 000 89.6 8
G578-34-1B13
C 1,2,3,4,6,7,8-HpCDD (#21) 3.75E+07 3.53E+07 2000 6.04E+07 4.82E+07 0.7878 2 000 85.1 8
G578-34-1B13
C OCDD (#22) 6.02E+07 6.71E+07 2000 6.04E+07 4.82E+07 0.6269 4 000 93.4 9
G578-35-1B13
C 2,3,7,8-TCDD (#18) 5.95E+07 7.58E+07 2000 6.31E+07 7.96E+07 1.1153 2 000 85.0 8
G578-35-1B13
C 1,2,3,7,8-PeCDD (#19) 6.78E+07 4.28E+07 2000 6.31E+07 7.96E+07 0.8155 2 000 95.0 9
G578-35-1B13
C 1,2,3,6,7,8-HxCDD (#20) 5.50E+07 4.37E+07 2000 5.93E+07 4.73E+07 1.0442 2 000 88.6 8
G578-35-1B13
C 1,2,3,4,6,7,8-HpCDD (#21) 3.94E+07 3.72E+07 2000 5.93E+07 4.73E+07 0.7878 2 000 91.2 9
G578-35-1B13
C OCDD (#22) 6.42E+07 7.13E+07 2000 5.93E+07 4.73E+07 0.6269 4000 101.0 10
G578-36-1B13
C 2,3,7,8-TCDD (#18) 4.58E+07 5.79E+07 2000 4.48E+07 5.65E+07 1.1153 2 000 91.8 9
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Tab 6 - Internal Standard % RecoveriesInternal Std. % Recovery (%Ris)= [(Ais +AiS ) x Qrs x 100]/[(Aris +Ars ) x RRFis x Qis]
Ais1
and Ais2
= area of primary and secondary internal sta
Where: Qrs = recovery std. added (pg)
Ars1
and Ars2
= area of primary and secondary recovery st
RRFis = Relative Response Factor of Internal Std.
Qis = internal std. added (pg)
SDG Analyte Ais
1
(Ion 1) Ais
2
(Ion 2) Qrs(pg) Ars
1
(Ion 1) Ars
2
(Ion 2) RRFis Qis(pg)
SGS (lab
calculation)
% Ris (
manua
G578-36-1B13
C 1,2,3,7,8-PeCDD (#19) 5.12E+07 3.25E+07 2000 4.48E+07 5.65E+07 0.8155 2000 101.0 101
G578-36-1B13
C 1,2,3,6,7,8-HxCDD (#20) 4.95E+07 3.93E+07 2000 4.91E+07 3.91E+07 1.0442 2000 96.4 96
G578-36-1B13
C 1,2,3,4,6,7,8-HpCDD (#21) 3.44E+07 3.29E+07 2000 4.91E+07 3.91E+07 0.7878 2000 96.8 96
G578-36-1B13
C OCDD (#22) 4.41E+07 4.91E+07 2000 4.91E+07 3.91E+07 0.6269 4000 84.3 84
G578-36-1B13
C 2,3,7,8-TCDF (#23) 7.57E+07 9.57E+07 2000 4.48E+07 5.65E+07 1.6529 2000 102.0 102
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Tab 7 - First & Last Eluters (Spot Check)First & Last Isomer Eluters for each homologue of PCDD and PCDF
SDG Lab Sample ID Comment Instrument ID File Name
Sample
No.
Date
Acquired
Time
Acquired
Date
Processed
Time
Processed Name
First Eluter
(RT)
G578-29 RETCON S30-144H Ical WG17173 a07oct08a 1 7-Oct-08 15.46.35 8 -Oct-08 08.19.56 TCDD 28.35
G578-29 PeCDD 33.02
G578-29 HxCDD 35.48
G578-29 HpCDD 39.37
G578-29 OCDD 44.60
G578-29 TCDF 26.52G578-29 PeCDF 32.11
G578-29 HxCDF 35.22
G578-29 HpCDF 39.16
G578-29 OCDF 45.19
G578-29 RETCON S32-184L a30jun09a 1 30-Jun-08 16.43.56 1-Jul-09 07.02.23 TCDD 26.12
G578-29 PeCDD 32.02
G578-29 HxCDD 34.34
G578-29 HpCDD 37.57
G578-29 OCDD 42.39
G578-29 TCDF 24.30
G578-29 PeCDF 30.51
G578-29 HxCDF 34.11
G578-29 HpCDF 37.40
G578-29 OCDF 42.53
G578-29 RETCON S32-184L a30jun09a 15 1-Jul-09 04.00.27 1-Jul-09 07.02.30 TCDD 26.11
G578-29 PeCDD 32.01
G578-29 HxCDD 34.34
G578-29 HpCDD 37.57
G578-29 OCDD 42.38
G578-29 TCDF 24.30
G578-29 PeCDF 30.51
G578-29 HxCDF 34.11
G578-29 HpCDF 37.39
G578-29 OCDF 42.53
G578-29 RETCON S32-184L a02jul09 1 2-Jul-09 13.24.00 3-Jul-09 09.30.03 TCDD 26.13
G578-29 PeCDD 32.02
G578-29 HxCDD 34.35
G578-29 HpCDD 37.59
G578-29 OCDD 42.41
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Tab 7 - First & Last Eluters (Spot Check)First & Last Isomer Eluters for each homologue of PCDD and PCDF
SDG Lab Sample ID Comment Instrument ID File Name
Sample
No.
Date
Acquired
Time
Acquired
Date
Processed
Time
Processed Name
First Eluter
(RT)
La
G578-29 TCDF 24.31
G578-29 PeCDF 30.52
G578-29 HxCDF 34.12
G578-29 HpCDF 37.41
G578-29 OCDF 42.55
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Tab 8 - Total Dioxin/Furan Calculations
Note: see attached e-mail from SGS Laboratory regarding Totals Calculations
SDG Name (Totals)
Kept
(Y/N) RT Conc.
EDL (SDG
Lab)
Status
(SDG
Lab) SDG Lab
Peaks
(SDG
Lab)
Shaw
(manual) Comment
G578-29-1B Tetra-Dioxins 26.12 0.344 0.344 0.1361 ok
26.28 0.213 0.213 0.1361 ok
26.51 0.139 0.139 0.1361 ok
27.31 0.090 0.1361 S2N
27.46 0.291 0.291 0.1361 ok
28.00 0.143 0.1361 S2N
28.10 0.181 0.181 0.1361 ok
28.34 0.318 0.318 0.1361 ok
28.57 0.161 0.161 0.1361 ok
29.42 0.106 0.1504 S2N 2378-TCDD
30.01 0.118 0.118 0.1361 ok S2N (Manual Correc
30.43 0.089 0.1361 S2N
0.1504 EDL (2378-TCDD)
1.7650 8 Total EMPC Tetra-Di
1.7650 8 1.7650 Total Tetra-Dioxins
G578-29-1B Hepta-Furans 37.42 4.653 0.0994 ok
37.58 0.185 0.1116 ok 123678-HpCDF
38.07 7.056 0.1116 ok39.24 0.254 0.1274 ok 1234789-HpCDF
0.1274 0.1274 EDL (123478-HpCDF
12.1480 4 12.1480 Total EMPC Hepta-F
12.1480 4 12.1480 Total Hepta-Furans
G578-29-1B Tetra-Furans y 24.30 0.192 0.192 0.1498 ok
y 24.55 0.145 0.145 0.1498 ok
y 25.27 0.586 0.586 0.1498 ok
n 25.46 0.280 0.1498 EMPC
y 26.06 0.261 0.261 0.1498 ok
n 26.30 0.303 0.1498 EMPC
y 26.43 0.091 0.1498 S2N
n 27.12 0.168 0.1498 EMPC
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Tab 8 - Total Dioxin/Furan Calculations
Note: see attached e-mail from SGS Laboratory regarding Totals Calculations
SDG Name (Totals)
Kept
(Y/N) RT Conc.
EDL (SDG
Lab)
Status
(SDG
Lab) SDG Lab
Peaks
(SDG
Lab)
Shaw
(manual) Comment
y 27.22 0.417 0.417 0.1498 ok
y 27.49 0.268 0.268 0.1498 ok
n 28.04 0.091 0.1498 S2N
n 28.16 0.105 0.1498 S2N
n 28.31 0.187 0.1498 EMPC
n 28.39 0.169 0.1498 EMPC
2378-TCDF n 28.46 0.366 0.1498 EMPC
y 29.07 0.359 0.359 0.1498 ok
n 30.52 0.198 0.1498 EMPC
0.1498 EDL (2378-TCDF)
2.2280 7 2.2280 Total Tetra-Furans
3.8990 14 Total EMPC Tetra-Fura
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Tab 9 - Matrix Spike/Matrix Spike Duplicate %Recovery Recalculation(e.g. Ongoing Precision Results [OGP] / Ongoing Precision Duplicate Results [OGPD])
Where: %R = percent recovery
MS/MSD %R = (Spike Recovered - Sample original conc.) x 100 / Spike Added Spk rec. = Spike concentration recovered
% RPD = ABS(MS-MSD) x 100 / Average % recovery Spk add = Spike concentration added
Orig. conc. = Original sample concentration
SDG AnalyteSample(pg/uL)
Spiked (amt.
added)pg/uL
MS Recovery
(SGS Calc.)pg/uL
MS %
Recovery
(SGSCalc.)
MSD Recovery
(SGS Calc.)pg/uL
MSD %
Recovery(SGS Calc.)
MS % Recovery(Shaw manual)
MSD %
Recovery
(Shawmanual)
G578-29 2,3,7,8-TCDD (#1) 0.106 10 10.2 102 10.6 106.0 100.8 104.5
G578-29 1,2,3,7,8-PeCDD (#2) 0.501 50 48.8 97.6 48.2 96.4 96.6 95.4
G578-29 1,2,3,4,7,8-HxCDD (#3) 0.426 50 50.7 101 50.3 101.0 100.6 99.7
G578-29 1,2,3,6,7,8-HxCDD (#4) 1.259 50 48.0 95.9 46.9 93.8 93.4 91.3
G578-30 2,3,7,8-TCDD (#1) 0.342 10 9.9 99.4 10.1 101.0 96.0 97.6
G578-30 1,2,3,7,8-PeCDD (#2) 0.505 50 46.1 92.2 46.0 92.0 91.2 91.0
G578-30 1,2,3,4,7,8-HxCDD (#3) 0.505 50 45.7 91.4 45.3 90.5 90.4 89.6
G578-30 1,2,3,6,7,8-HxCDD (#4) 0.505 50 44.3 88.6 43.2 86.5 87.6 85.4
G578-33 2,3,7,8-TCDD (#1) 0.369 10 11.0 110 10.4 104.0 106.3 100.3
G578-33 1,2,3,7,8-PeCDD (#2) 0.563 50 49.0 98 48.5 97.0 96.9 95.9
G578-33 1,2,3,4,7,8-HxCDD (#3) 0.563 50 50.4 101 48.9 97.8 99.7 96.7
G578-33 1,2,3,6,7,8-HxCDD (#4) 0.563 50 48.6 97.3 48.9 97.8 96.1 96.7
G578-34 2,3,7,8-TCDD (#1) 0.316 10 10.3 103 10.5 105.0 99.8 101.8 G578-34 1,2,3,7,8-PeCDD (#2) 0.285 50 48.7 97.3 48.4 96.8 96.8 96.2
G578-34 1,2,3,4,7,8-HxCDD (#3) 0.516 50 48.2 96.5 49.1 98.2 95.4 97.2
G578-34 1,2,3,6,7,8-HxCDD (#4) 1.110 50 49.7 99.4 49.3 98.6 97.2 96.4
G578-35 2,3,7,8-TCDD (#1) 0.235 10 10.3 103 10.5 105.0 100.7 102.7
G578-35 1,2,3,7,8-PeCDD (#2) 0.521 50 48.7 97.3 48.4 98.6 96.4 95.8
G578-35 1,2,3,4,7,8-HxCDD (#3) 0.828 50 48.2 96.5 49.1 98.2 94.7 96.5
G578-35 1,2,3,6,7,8-HxCDD (#4) 1.070 50 49.7 99.4 49.3 98.6 97.3 96.5
G578-36 2,3,7,8-TCDD (#1) 0.372 10 10.4 104 10.7 107.0 100.3 103.3
G578-36 1,2,3,7,8-PeCDD (#2) 0.729 50 47.7 95.4 48.6 97.2 93.9 95.7
G578-36 1,2,3,4,7,8-HxCDD (#3) 0.292 50 45.5 91 49.0 98.0 90.4 97.4
G578-36 1,2,3,6,7,8-HxCDD (#4) 0.493 50 49.7 99.4 48.9 97.8 98.4 96.8
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Tab 10 - Spot Check Relative Response Factor Calculations & Ion Ratios(RRF Calculation for unlabeled PCDDs/PCDFs &
13C-labeled Recovery Standard)
Response Factor (RRFn)= [(An1+An
2) x Qis]/[(Ais
1+Ais
2) x Qn]
Ion Ratio (RRFis) = [(Ais +Ais ) x Qrs]/[(Ars +Ars ) x Qis]
Where: An1
and An2
= areas of the primary and secondary ions of interest
Ais1
and Ais2
= area of primary and secondary internal standard ions
Ars1
and Ars2
= area of primary and secondary recovery standard ions
rs =13
C 1,2,3,4-TCDD (#27) is=13
C 1,2,3,7,8-P
rs =13
C 1,2,3,7,8,9-HxCDD (#28) is=13
C 1,2,3,6,7,8
Qn = quantity of unlabeled PCDD/PCDF analyte injected (pg)Qis = quantity of internal standard injected (pg)
Qn = quantity of recovery (e.g Injection) standard injected (pg)
SDG Name RRFn# RRFn (SDG Lab) RRFn (Shaw - manual) An1
An2
Qis Ais1
A
G578-29-1B 2,3,7,8-TCDD (#1) 1 1.06 1.0612 1.76E+05 2.40E+05 100 6.93E+07 8.7
2 0.99 0.9902 1.26E+06 1.58E+06 100 6.37E+07 7.9
3 0.99 0.9870 6.26E+06 8.22E+06 100 6.53E+07 8.1
4 1.01 1.0052 2.68E+07 3.46E+07 100 6.81E+07 8.4
5 1.00 1.0013 1.38E+08 1.79E+08 100 7.05E+07 8.7
Mean 1.0087 1.0090
%RSD 2.99
An1
An2
Qis Ais1
A
1,2,3,7,8-PeCDD (#2) 1 1.06 1.0595 8.52E+05 5.73E+05 100 6.61E+07 4.1
2 1.04 1.0421 6.65E+06 4.25E+06 100 6.41E+07 4.0
3 1.06 1.0544 3.44E+07 2.18E+07 100 6.52E+07 4.1
4 1.05 1.0481 1.45E+08 9.25E+07 100 6.95E+07 4.3
5 1.06 1.0558 7.85E+08 5.02E+08 100 7.46E+07 4.7
Mean 1.0517 1.0520
%RSD 6.26
RRFis (SDG Lab) RRFis (Shaw - manual) Ais1
Ais2
Qrs Ars1
A13
C 1,2,3,7,8,9-PeCDD 0.7882 0.7879 6.52E+07 4.14E+07 100 5.99E+07 7.513
C 1,2,3,6,7,8-HxCDD 1.0656 1.0665 6.18E+07 4.89E+07 100 5.79E+07 4.5
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Tab 12 - Continuing Calibration Recalculation for Concentration of Unlabeled Compound
Where: An1
and An2
= areas of the primary and secondary ions of interest
Qis = the concentration of the internal standard
Cc = [(An1+An
2) x Qis]/[(Ais
1+Ais
2) x RRFICAL] Ais
1and Ais
2= area of primary and secondary internal standard ions
%D= [(RRFICAL-RRFCCAL) x 100]/RRFICAL RRFCCAL = the response of the analyte from Continuing Calibration
RRFICAL = the response of the analyte from Initial Calibration
Cc = concentration of the unlabeled compound in the extract
Ct = concentration of the actual spiked compound%D = % Difference between RRFICAL & RRFCCAL
Analyte An1
(Ion 1) An2
(Ion 1) Qis Ais1
(Ion 1) Ais2
(Ion 2) RRFCCAL RRFICAL
Cc (SDG
Lab)
Ct (SDG
Lab)
%D
(SDG
Lab)
%D
(Shaw
manual)
Cc (Shaw
manual)
w/
RRFCCAL
G578-29 2,3,7,8-TCDD 9.12E+06 1.16E+07 100 8.90E+07 1.13E+08 1.0289 1.0087 10.200 10 2.00 2.0 9.97
G578-29 1,2,3,7,8-PeCDF 5.79E+07 3.74E+07 100 1.14E+08 7.25E+07 1.021 1.0517 48.540 50 -2.90 -3.0 50.05
G578-29 2,3,7,8-TCDF 1.27E+07 1.64E+07 100 1.36E+08 1.73E+08 0.9418 1.0368 9.084 10 -9.20 -10.1 10.00
G578-30 2,3,7,8-TCDD 1.05E+07 1.33E+07 100 9.59E+07 1.21E+08 1.0989 1.0087 10.890 10 -0.03 8.2 9.99
G578-30 1,2,3,7,8-PeCDF 9.39E+07 6.03E+07 100 1.96E+08 1.25E+08 0.9622 1.0517 48.730 50 -6.20 -9.3 49.92
G578-30 2,3,7,8-TCDF 1.61E+07 2.04E+07 100 1.56E+08 1.94E+08 1.0425 1.0368 10.060 10 -7.60 0.5 10.00
G578-33 2,3,7,8-TCDD 2.30E+07 2.93E+07 100 2.23E+08 2.83E+08 1.0341 1.0087 10.250 10 2.50 2.5 10.00
G578-33 1,2,3,7,8-PeCDF 1.97E+08 1.25E+08 100 4.02E+08 2.52E+08 0.9834 1.0517 49.800 50 -0.40 -6.9 50.07
G578-33 2,3,7,8-TCDF 3.41E+07 4.29E+07 100 3.33E+08 4.19E+08 1 .0241 1.0368 9.878 10 -1.20 -1.2 10.00
G578-34 2,3,7,8-TCDD 1.69E+07 2.18E+07 100 1.70E+08 2.16E+08 1.0042 1.0087 9.955 10 -0.40 -0.4 9.98
G578-34 1,2,3,7,8-PeCDF 1.47E+08 9.47E+07 100 3 .10E+08 1.98E+08 0.9508 1.0517 48.150 50 -3.70 -10.6 50.04
G578-34 2,3,7,8-TCDF 2.46E+07 3.15E+07 100 2.50E+08 3.13E+08 0.997 1.0368 9.161 10 -3.80 -4.0 9.99
G578-35 2,3,7,8-TCDD 1.69E+07 2.18E+07 100 1.70E+08 2.16E+08 1.0042 1.0087 9.955 10 -0.40 -0.4 9.98
G578-35 1,2,3,7,8-PeCDF 1.47E+08 9.47E+07 100 3 .10E+08 1.98E+08 0.9508 1.0517 48.150 50 -3.70 -10.6 50.04
G578-35 2,3,7,8-TCDF 2.46E+07 3.15E+07 100 2.50E+08 3.13E+08 0.997 1.0368 9.616 10 -3.80 -4.0 9.99
G578-36 2,3,7,8-TCDD 3.75E+06 4.73E+06 100 3.57E+07 4.52E+07 1.0485 1.0087 10.390 10 3.90 3.8 10.00
G578-36 1,2,3,7,8-PeCDF 2.95E+07 1.89E+07 100 6 .24E+07 3.96E+07 0.9487 1.0517 48.040 50 -3.90 -10.9 50.02
G578-36 2,3,7,8-TCDF 5.64E+06 7.18E+06 100 5.75E+07 7.12E+07 0 .9959 1.0368 9.606 10 -3.90 -4.1 10.00
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Tab 13 - Spot Check Continuing Calibration Recalculation for Concentration of Labeled Compound
Where: Cc = concentration of the unlabeled compound in the extract
Ct = True Concentration
An1
and An2
= areas of the primary and secondary ions of interest
Cc = [(An1+An
2) x Qis]/[(Ais
1+Ais
2) x RRFIs] Qis = the concentration of the internal standard
%D= [(RRFICAL-RRFCCAL) x 100]/RRFICAL Ais1
and Ais2
= area of primary and secondary internal standard ion
RRFIs = the response from the internal standard
RRFICAL = the response of the analyte from Initial Calibration
RRFCCAL = the response of the analyte from Continuing Calibration
%D = % Difference between RRFICAL & RRFCCAL
SDG CCAL Analyte An1
An2
Qis Ais1
Ais2
RRFIS RRFICAL RRFCCAL
Cc (SGS
Lab)
Ct (SGS
Lab)
Cc (Shaw
manual)
w/
RRFCCAL
%
(SG
La
G578-29 Initial37
CL 2,3,7,8-TCDD 2.10E+07 100 8.90E+07 1.13E+08 1.1097 1.1889 1.1592 9.750 10 9.37 -2
G578-29 Final37
CL 2,3,7,8-TCDD 2.60E+07 100 1.09E+08 1.39E+08 1.1036 1.1889 1.1406 9.594 10 9.50 -4
G578-30 Initial37
CL 2,3,7,8-TCDD 2.20E+07 100 9.41E+07 1.19E+08 1.1296 1.1889 1.1801 9.926 10 9.14 -3
G578-30 Final37
CL 2,3,7,8-TCDD 2.30E+07 100 9.59E+07 1.21E+08 1.1253 1.1889 1.2077 10.160 10 9.42 -2
G578-33 Initial
37
CL 2,3,7,8-TCDD 2.90E+07 100 1.23E+08 1.56E+08 1.1154 1.1889 1.1652 9.801 10 9.32 -1G578-33 Final
37CL 2,3,7,8-TCDD 5.20E+07 100 2.23E+08 2.83E+08 1.1193 1.1889 1.1516 9.724 10 9.18 -0
G578-34 Initial37
CL 2,3,7,8-TCDD 2.80E+07 100 1.19E+08 1.51E+08 1.1231 1.1889 1.1623 9.777 10 9.23 0
G578-34 Final37
CL 2,3,7,8-TCDD 3.90E+07 100 1.70E+08 2.16E+08 1.1434 1.1889 1.1713 9.852 10 8.84 1
G578-35 Initial37
CL 2,3,7,8-TCDD 2.80E+07 100 1.19E+08 1.51E+08 1.1231 1.1889 1.1623 9.777 10 9.23 2
G578-35 Final37
CL 2,3,7,8-TCDD 3.90E+07 100 1.70E+08 2.16E+08 1.1434 1.1889 1.1713 9.852 10 8.84 3
G578-36 Initial37
CL 2,3,7,8-TCDD 8.20E+06 100 3.46E+07 4.37E+07 1.0771 1.1889 1.1317 9.519 10 9.72 4
G578-36 Final37
CL 2,3,7,8-TCDD 8.30E+06 100 3.57E+07 4.52E+07 1.0767 1.1889 1.1058 9.301 10 9.53 5
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Tab 14 - Recalculation of Percent Difference for the RRFs for the Continuing Calibration V
% Difference (%D) = (RRFCCAL - RRFICAL) x 100 / RRFCCAL
Where:
RRFICAL = Relative Response factor from the initial calibration
RRFCCAL = Relative Response factor from the continuing calibration
(SDG lab) Shaw (manual)
SDG Analyte RRFCCAL RRFICAL %D %D
G578-29 2,3,7,8-TCDD (#1) 1.0058 1.0087 -0.3 -0.3
G578-29 1,2,3,7,8-PeCDD (#2) 1.0349 1.0517 -1.6 -1.6
G578-29 1,2,3,4,7,8-HxCDD (#3) 0.9240 0.9489 -2.6 -2.6
G578-29 1,2,3,6,7,8-HxCDD (#4) 0.9427 0.9916 -4.9 -4.9
G578-29 1,2,3,7,8,9-HxCDD (#5) 0.9430 0.9649 -2.3 -2.3
G578-29 1,2,3,4,6,7,8-HpCDD (#6) 1.0057 1.0612 -5.2 -5.2
G578-29 OCDD (#7) 1.0255 1.0643 -3.6 -3.6
G578-29 2,3,7,8-TCDF (#8) 0.9577 1.0368 -7.6 -7.6
G578-29 1,2,3,7,8-PeCDF (#9) 0.9262 0.9873 -6.2 -6.2
G578-29 2,3,4,7,8-PeCDF (#10) 0.9515 1.0154 -6.3 -6.3
G578-30 2,3,7,8-TCDD (#1) 1.0093 1.0087 0.1 0.1
G578-30 1,2,3,7,8-PeCDD (#2) 1.0110 1.0517 -3.9 -3.9
G578-30 1,2,3,4,7,8-HxCDD (#3) 0.9361 0.9489 -1.3 -1.3
G578-30 1,2,3,6,7,8-HxCDD (#4) 0.9457 0.9916 -4.6 -4.6
G578-30 1,2,3,7,8,9-HxCDD (#5) 0.9386 0.9649 -2.7 -2.7
G578-30 1,2,3,4,6,7,8-HpCDD (#6) 1.0428 1.0612 -1.7 -1.7
G578-30 OCDD (#7) 1.0437 1.0643 -1.9 -1.9
G578-30 2,3,7,8-TCDF (#8) 0.9600 1.0368 -7.4 -7.4
G578-30 1,2,3,7,8-PeCDF (#9) 0.9391 0.9873 -4.9 -4.9
G578-30 2,3,4,7,8-PeCDF (#10) 1.0044 1.0154 -1.1 -1.1
G578-33 2,3,7,8-TCDD (#1) 1.0341 1.0087 2.5 2.5
G578-33 1,2,3,7,8-PeCDD (#2) 1.0488 1.0517 -0.3 -0.3
G578-33 1,2,3,4,7,8-HxCDD (#3) 0.9328 0.9489 -1.7 -1.7
G578-33 1,2,3,6,7,8-HxCDD (#4) 0.9577 0.9916 -3.4 -3.4
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Tab 14 - Recalculation of Percent Difference for the RRFs for the Continuing Calibration V
% Difference (%D) = (RRFCCAL - RRFICAL) x 100 / RRFCCAL
Where:
RRFICAL = Relative Response factor from the initial calibration
RRFCCAL = Relative Response factor from the continuing calibration
(SDG lab) Shaw (manual)
SDG Analyte RRFCCAL RRFICAL %D %D
G578-33 1,2,3,7,8,9-HxCDD (#5) 0.9282 0.9649 -3.8 -3.8
G578-33 1,2,3,4,6,7,8-HpCDD (#6) 1.0534 1.0612 -0.7 -0.7
G578-33 OCDD (#7) 1.0593 1.0643 -0.5 -0.5
G578-33 2,3,7,8-TCDF (#8) 1.0241 1.0368 -1.2 -1.2
G578-33 1,2,3,7,8-PeCDF (#9) 0.9834 0.9873 -0.4 -0.4
G578-33 2,3,4,7,8-PeCDF (#10) 0.9766 1.0154 -3.8 -3.8
G578-34 2,3,7,8-TCDD (#1) 1.0195 1.0087 1.1 1.1
G578-34 1,2,3,7,8-PeCDD (#2) 1.0445 1.0517 -0.7 -0.7
G578-34 1,2,3,4,7,8-HxCDD (#3) 0.9430 0.9489 -0.6 -0.6
G578-34 1,2,3,6,7,8-HxCDD (#4) 1.0022 0.9916 1.1 1.1
G578-34 1,2,3,7,8,9-HxCDD (#5) 0.9935 0.9649 3.0 3.0
G578-34 1,2,3,4,6,7,8-HpCDD (#6) 1.0519 1.0612 -0.9 -0.9
G578-34 OCDD (#7) 1.0563 1.0643 -0.7 -0.8
G578-34 2,3,7,8-TCDF (#8) 1.0030 1.0368 -3.3 -3.3
G578-34 1,2,3,7,8-PeCDF (#9) 0.9689 0.9873 -1.9 -1.9
G578-34 2,3,4,7,8-PeCDF (#10) 1.0235 1.0154 0.8 0.8
G578-35 2,3,7,8-TCDD (#1) 1.0195 1.0087 1.1 1.1
G578-35 1,2,3,7,8-PeCDD (#2) 1.0445 1.0517 -0.7 -0.7
G578-35 1,2,3,4,7,8-HxCDD (#3) 0.9430 0.9489 -0.6 -0.6
G578-35 1,2,3,6,7,8-HxCDD (#4) 1.0022 0.9916 1.1 1.1
G578-35 1,2,3,7,8,9-HxCDD (#5) 0.9935 0.9649 3.0 3.0
G578-35 1,2,3,4,6,7,8-HpCDD (#6) 1.0519 1.0612 -0.9 -0.9
G578-35 OCDD (#7) 1.0563 1.0643 -0.7 -0.8
G578-35 2,3,7,8-TCDF (#8) 1.0030 1.0368 -3.3 -3.3
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Tab 14 - Recalculation of Percent Difference for the RRFs for the Continuing Calibration V
% Difference (%D) = (RRFCCAL - RRFICAL) x 100 / RRFCCAL
Where:
RRFICAL = Relative Response factor from the initial calibration
RRFCCAL = Relative Response factor from the continuing calibration
(SDG lab) Shaw (manual)
SDG Analyte RRFCCAL RRFICAL %D %D
G578-35 1,2,3,7,8-PeCDF (#9) 0.9689 0.9873 -1.9 -1.9
G578-35 2,3,4,7,8-PeCDF (#10) 1.0235 1.0154 0.8 0.8
G578-36 2,3,7,8-TCDD (#1) 1.0181 1.0087 0.9 0.9
G578-36 1,2,3,7,8-PeCDD (#2) 1.0174 1.0517 -3.3 -3.3
G578-36 1,2,3,4,7,8-HxCDD (#3) 0.9225 0.9489 -2.8 -2.8
G578-36 1,2,3,6,7,8-HxCDD (#4) 0.9465 0.9916 -4.5 -4.5
G578-36 1,2,3,7,8,9-HxCDD (#5) 0.9111 0.9649 -5.6 -5.6
G578-36 1,2,3,4,6,7,8-HpCDD (#6) 1.0211 1.0612 -3.8 -3.8
G578-36 OCDD (#7) 1.0300 1.0643 -3.2 -3.2
G578-36 2,3,7,8-TCDF (#8) 0.9769 1.0368 -5.8 -5.8
G578-36 1,2,3,7,8-PeCDF (#9) 0.9419 0.9873 -4.6 -4.6
G578-36 2,3,4,7,8-PeCDF (#10) 0.9780 1.0154 -3.7 -3.7
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Tab 15 - Toxic Equivalency Factors (TEF) "Spot Check"
SDG SEM Lab ID Sampled Extracted Analyzed
G578-29-1B SEM-015 9794676006 6/15/2009 6/29/2009 7/2/2009G578-30-1B SEM-017 9794971005 6/16/2009 7/5/2009 7/7/2009
G578-30-2B SEM-017 9794971005 6/16/2009 7/5/2009 7/7/2009
G578-33-1B SEM-029 9796518001 6/25/2009 7/7/2009 7/10/2009
G578-33-2B SEM-029 9796518003 6/25/2009 7/7/2009 7/10/2009
G578-33-3B SEM-029 9796518004 6/25/2009 7/7/2009 7/10/2009
G578-33-4B SEM-029 9796518005 6/25/2009 7/7/2009 7/10/2009
G578-34-1B SEM-035 9797431001 7/1/2009 7/8/2009 7/11/2009
G578-34-2B SEM-035 9797431002 7/1/2009 7/8/2009 7/11/2009
G578-35-1B SEM-031 9796885001 6/29/2009 7/8/2009 7/11/2009
G578-35-2C SEM-031 9796885002 6/29/2009 7/8/2009 7/11/2009
G578-36-1B SEM-034 9797191001 6/30/2009 7/23/2009 7/28/2009
G578-36-2B SEM-034 9797191004 6/30/2009 7/23/2009 7/28/2009
G578-36-3B SEM-034 9797191005 6/30/2009 7/23/2009 7/28/2009
G578-36-4B SEM-034 9797191006 6/30/2009 7/23/2009 7/28/2009
G578-36-5B SEM-034 9797191007 6/30/2009 7/23/2009 7/28/2009
Spot Check: G578-29-1B
Where: if [conc] = ND, then for ND=0.5 TEF WHO 2005 use [EDL] or [E
TEF WHO 2005
Value
ND = 0.5 (for
EDL or EMPC
values)
[Sample Conc.] x
WHO 2005 TEF EDL or EMPC
ND = 0 (forEDL or
EMPC
values)
2,3,7,8-TCDD 1 0.162 0.1615 0.323 0
1,2,3,7,8-PeCDD 1 0.269 0.2685 0.537 0
1,2,3,4,7,8-HxCDD 0.1 0.914 0.0914 0.914
1,2,3,6,7,8-HxCDD 0.1 2.7 0.27 2.7
1,2,3,7,8,9-HxCDD 0.1 2.48 0.248 2.48
1,2,3,4,6,7,8-HpCDD 0.01 64.1 0.641 64.1
OCDD 0.0003 2860 0.858 2860
2,3,7,8-TCDF 0.1 0.161 0.0161 0.322 0
1,2,3,7,8-PeCDF 0.03 0.352 0.01056 0.352
2,3,4,7,8-PeCDF 0.3 1.05 0.315 1.05
1,2,3,4,7,8-HxCDF 0.1 1.26 0.126 1.26
1,2,3,6,7,8-HxCDF 0.1 0.646 0.0646 0.646
2,3,4,6,7,8-HxCDF 0.1 0.951 0.0951 0.951
1,2,3,7,8,9-HxCDF 0.1 0.269 0.02685 0.537 0
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1,2,3,4,6,7,8-HpCDF 0.01 9.99 0.0999 9.99
1,2,3,4,7,8,9-HpCDF 0.01 0.545 0.00545 0.545
OCDF 0.0003 21.4 0.00642 21.4
3.30 TEQ [pg/g]
where ND=0.5
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WHO 2005 (ND=0)
EMPC [WHO
2005 TEQ
(ND=0)]
WHO 2005
TEQ
(ND=1/2)
EMPC [WHO 2005
TEQ (ND=1/2)]
[pg/g] [pg/g] [pg/g] [pg/g]
2.83 4.01 3.30 4.170.0895 0.0918 0.7530 0.7530
0.0568 0.0606 0.9180 0.9180
2.67 2.72 2.87 2.88
2.86 2.86 3.24 3.24
3.50 3.58 4.23 4.27
0.0979 0.1660 0.8340 0.8030
2.15 2.20 2.39 2.39
0.1730 0.2980 0.7390 0.6190
2.53 3.14 2.68 3.14
0.0167 0.0487 0.7900 0.8140
0.5770 0.6870 1.40 1.39
1.19 1.43 1.59 1.58
1.16 1.43 1.64 1.64
0.2190 0.2190 0.7780 0.7780
0.0478 0.0478 0.6790 0.6790
PCs] at for the ND= value
[Sample Conc.] x
WHO 2005 TEF
0
0
0.0914
0.2700
0.2480
0.6410
0.8580
0
0.0106
0.3150
0.1260
0.0646
0.0951
0
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0.0999
0.0055
0.0064
2.83 TEQ [pg/g]
where ND=0