DTP1

Chemical Formula: C24H35NOS

Molecular Weight: 385.61

HRMS (Direct injection):

MS: m/z 384 [M-H]-

MS: m/z 301 [M - piperidinyl]-

MS: m/z 157 [DMSO]

50 100 150 200 250 300 350 400 450 500 550 600 650 m/z0.0

2.5

5.0

7.5Inten.(x1,000,000)

15786

11879 301215 274 319192 384 476415372 494 534545 623 688579 657

1HNMR (DMSO)

13CNMR (CDCl3)

GC-MS:

DTP2

Chemical Formula: C23H33NO2S

Molecular Weight: 387.58

HRMS (Direct injection):

175.0 200.0 225.0 250.0 275.0 300.0 325.0 350.0 375.0 400.0 425.0 450.0 475.0 500.0 525.0 550.0 575.0 600.0 625.0 650.0 675.0 m/z0.0

5.0

Inten.(x10,000)174

301

445215 391

273257 347 374 436 686538 627478 568510 642582699

MS: m/z 301 [M - morpholino]-

LC-MS:

Datafile Name:DTP Morf._Mary's compounds 20160226_2262016_005.lcdSample Name:DTP Morf.Sample ID:DTP Morf.

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 min

0

25

50

mAU254nm,4nm

1HNMR (DMSO)

13CNMR (CDCl3)

DTP3

Chemical Formula: C23H33NOS

Molecular Weight: 371.58

HRMS (Direct injection):

175.0 200.0 225.0 250.0 275.0 300.0 325.0 350.0 375.0 400.0 425.0 450.0 475.0 500.0 525.0 550.0 575.0 600.0 625.0 650.0 675.0 m/z0.0

2.5

5.0

Inten.(x1,000,000)372

445217173 331257 413392285 519300 542483 615576 686649600

MS: m/z 372 [M+H]+

LC-MS:

Datafile Name:DTP PIRR M1+M2_LCMS Mary's compounds 03072016_372016_005.lcdSample Name:DTP PIRR M1+M2Sample ID:DTP PIRR M1+M2

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 min

0

250

500

750

1000

mAU254nm,4nm

1HNMR (DMSO)

GC-MS: