Post on 30-Apr-2022
/ f
DISTRIBUTION SHEET To From
ANALYTICAL SERVICES Page 1 of 1
DISTRIBUTION From ANALYTICAL SERVICES Date: 03/06/95
Project Title/Work Order EDTNO.: EDT-610404 WHC-SD-WM-DP-097, Rev. 0, - "Tank Characterization 40-Day Crust Burn Report for Double Shell Tank 241-AW-101" ECN NO.: N/A
Name MSIN Text With all Attach
Addendum 1A Only
EDT/ECN Only
ONSITE Pacific Northwest Laboratory J. R. Gormsen K7-28 Westinahouse Hanford Company R. A. Esch T6-30 X G. D. Johnson S7-15 J. G. Kristofzski T6-06 X N. G. McDuffie S7-15 X P. Sathyanarayana R2-12 2 R. D. Schreiber R2-12 X Central Files L8-04 2 EDMC H6-08 X LTIC T6-03 OSTI L8-07 2 TFIC (Tank Farm Information Center) Rl-20
X X
DISCLAIMER
This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, make any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.
DISCLAIMER
Portions of this document may be illegible in electronic image products. Images are produced from the best available original document.
MAK08 1395 55 W p ^
ENGINEERING DATA TRANSMITTAL Pag* 1 of.
1.EDT 610404 2. To: (Receiving Organization)
Distribution 3. From: (Originating Organization) Program Support
4. Related EOT Ho.:
N/A 5. Proj./Prog./Dept./Div.:
Tank 241-AW-101/Waste Hanagement/PS/AS
6. Cog. Engr.:
Ruth A. Esch 7. Purchase Order No.
N/A
8. Originator Remarks: This document is being released into the Supporting Document System for re t r ievabi l i ty purposes.
9. Equip./Component No.:
N/A 10. System/Bldg./Facility:
N/A 11. Receiver Remarks: For Release.
12. Major Assm. Dug. No.
N/A 13. Permit/Permit Application No.
N/A 14. Required Response Date:
03/08/95 15. DATA TRANSMITTED ( F ) _i£L JJli. -iil. (A) Kern No.
(B) Document/Drawing No. (C)
Sheet No.
(D) Rev. No.
(E) Title or Description of Data Transmitted
Approval Designator
Reason for
Transmittal
Originator Disposition
Receiver
Disposition
WHC-SD-WM-DP-097 N/A Tank Characterization 40-Day Crust Burn Report for Double Shell Tank 241-AW-101
16. KEY Approval Designator (FJ Reason for Transmittal (G) Disposition (H) & (I)
E, S. Q. D or N/A (see WHC-CM-3-5, Sec.12.7),
1 . Approval 4. Review 2. Release S. Post-Review 3. Information 6. Dist. (Receipt Acknow. Required)
1. Approved 2. Approved w/comment 3. Disapproved w/comment
4. Reviewed no/comment 5. Reviewed w/comment 6. Receipt acknowledged
(G) (HI 17. SIGNATURE/DISTRIBUTION (See Approval Designator for required signatures)
(G) (H)
Reason
Disp. (J) Name (K) Signature (L) Date (M) MSIN (J) Name (K) Signature (L) Date (Ml MSIN Reason
Disp.
Cog.Eng. R. A. Esch />,.
Cog. Hgr. J. G. Kristofzski
QA EFnC u>. A . V\«>«i5>i£kc8.A
Safety
Env.
18.
A. E. Young
Signature q&EDT Originator
_2tkl5 Date
19.
Authorized Representative Dote for Receiving Organization
21. DOE APPROVAL (if required) Ctrl. No.
[] Approved [] Approved w/comments U Disapproved w/comments
BD-7400-172-2 (04/94) GEF097
BD-7400-172-1
<
RELEASE AUTHORIZATION
Document Number: WHC-SD-WM-DP-097, REV.O
Document Title: Tank Characterization 40-Day Crust Burn for Double Shell Tank 241-AW-101
Release Date: March 8, 1995
This document was reviewed following the procedures described in WHC-CM-3-4 and is:
APPROVED FOR PUBLIC RELEASE
WHC Information Release Administration Specialist:
£^7^04/? ~^/j£iJZ—> M a r c h 8 > 1995
/ yf ^ffa MT Broz
TRADEMARK DISCLAIMER. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof or its contractors or subcontractors. This report has been reproduced from the best available copy. Available in paper copy and microfiche. Printed in the United States of America. Available to the U.S. Department of Energy and its contractors from:
U.S. Department of Energy Office of Scientific and Technical Information (OSTI) P.O. Box 62 Oak Ridge, TM 37831 Telephone: (615) 576-8401
Available to the public from: U.S. Department of Commerce National Technical Information Service (NTIS) 5285 Port Royal Road Springfield, VA 22161 Telephone: (703) 487-4650
A-6001-400.2 (09/94) WEF256
<r
SUPPORTING DOCUMENT 1. Total Pages
2. Title
Tank Characterization 40-Day Crust Burn for Double Shell Tank 241-AW-lOl
3. Number WHC-SD-WM-DP-097
4. Rev No. 0
5. Key Words Tank Characterization, 40-Day, Crust Burn, Double Shell Tank, Tank AW-101, Tank 241-AW-lOl, 241-AW-101, AW-101
6. Author
Name: Ruth A. Esch
Signature
Organization/Charge Code 8E480/MDR21
7. Abstract
N/A
RELEASE STAMP
OFFICIAL RELEASE BYWHC
DATE HAR 0 8 55 i <^tQL.
A-6400-073 (08/94) UEF124
<r
® Westinghouse Hanford Company
P.O. Box 1970 Richland, WA 99352
WHC-SD-WM-DP-097, REV. 0
ANALYTICAL SERVICES
Project: TANK CHARACTERIZATION 40-DAY CRUST BURN REPORT FOR DOUBLE SHELL TANK
Tank: 241-AW-101
Date Pr inted: MARCH 2, 1995
DISTRIBUTION OF THiS DOCUMENT IS UNLIMITED
54-7600475 Hanford Operations and Engineering Contractor for the US Department of Energy
<
WHC-SD-WM-DP-097, REV. 0
TABLE OF CONTENTS
Narrative 1 Sample Data Summary 5 Undigested Sample Analyses - Direct 10
Differential Scanning Calorimetry Worklist #538 12 Worklist #539 21 Worklist # 540 . . . 27 Worklist #541 . 35 Worklist #547 39 Thermal Gravimetric Analyses Worklist #545 47 Worklist # 546 53 Worklist #548 59
This Document consists of pages 1 through 64.
ii
WHC-SD-WM-DP-097, REV. 0
NARRATIVE
1
c
WHC-SD-WM-DP-097,REV.O 40 DAY CRUST BURN SAFETY ISSUE RESULTS FOR TANK 241-AW-101
AUGERS 95-AUG-001, 95-AUG-004, 95-AUG-005
Summary Three auger samples from tank AW-101 were received by the 222-S laboratories. They were analyzed to support the crust burn safety issue. No sample results exceeded the notification criteria. Sample Receipt and Extrusion Riser 13A One 10 inch auger (95-AUG-001) was used to sample the tank AW-101 contents at riser 13A. The sample was taken on 1/25/95, and received at the 222-S laboratory on 1/27/95. Extrusion took place on 2/7/95. The total amount of solid material recovered was about 78 grams. There was less than 5 mL of drainable liquid which was not recovered. Based on the texture and type of material sampled, the recovery is estimated to be 85%. Most of the solid was a damp, dark brown, sludge material that was located on all nine flutes, with the heaviest accumulation on flutes 7, 8 and 9. The sample found on flutes 1 through 3 (top of the auger) consisted of this sludge with crystalline, crust material dispersed throughout (approximately 26 grams of material). This material was sampled separately, designated as a facie (crust), and assigned sample number S95T000107. The sludge material from flute 4 was subsampled (approximately 3 grams collected), designated as the Upper Half, and assigned sample number S95T000102. The sludge material from flute 9 was subsampled (approximately 2 grams collected), designated as the Lower Half, and assigned sample number S95T000103. The remaining material from flutes 4 through 9 (approximately 49 grams recovered) was collected and saved for further analysis. The initial results for the crust burn safety issue (DSC and TGA) for Riser 13A appear on page 1 of Table 1 and in Table 2. The final report will contain all other analyses.
Riser 12A One 10 inch auger (95-AUG-004) was used to sample the tank AW-101 contents at riser 12A. The sample was taken on 1/26/95, and received at the 222-S laboratory on 1/27/95. Extrusion took place on 2/7/95. The total amount of solid material recovered was about 12 grams. There was less than 5 mL of drainable liquid collected. Based on the texture and type of material sampled, the recovery is estimated to be 60%. The solid was a damp, dark brown, sludge material that was located on flutes 4 through 9 only, with the heaviest accumulation on flutes 8 and 9. There was no crust material observed. The sludge material from flutes 5 and 6 was subsampled (approximately 0.5 grams collected), designated as the Upper Half, and assigned sample number S95T000110. The sludge material from flute 9 was subsampled (approximately 2 grams collected), designated as the Lower Half, and assigned sample number S95T000111. The remaining material from flutes 4 through 9 (approximately 10 grams recovered) was collected and archived. The initial results for the crust burn safety issue (DSC and TGA) for Riser 12A appear on page 2 of Table 1 and in Table 2. The final report will contain all other analyses.
2
WHC*SD-WM-DP-097,REV.O Riser 24B One 10 inch auger (95-AUG-005) was used to sample the tank AW-101 contents at riser 24B. The sample was taken on 1/27/95, and received at the 222-S laboratory on 1/27/95. Extrusion took place on 2/8/95. The total amount of solid material recovered was about 18 grams. There was less than 5 mL of drainable liquid which was not recovered. Based on the texture and type of material sampled, the recovery is estimated to be 60%. The solid was a damp, dark brown, sludge material that was located on flutes 6 through 10 only, with the heaviest accumulation on flutes 9 and 10. There was no crust material observed. The sludge material from flute 6 was subsampled (approximately 1 gram collected), designated as the Upper Half, and assigned sample number S95T000113. The sludge material from flute 10 was subsampled (approximately 3 grams collected), designated as the Lower Half, and assigned sample number S95T000114. The remaining material from flutes 6 through 10 (approximately 15 grams recovered) was collected and archived. The initial results for the crust burn safety issue (DSC and TGA) for Riser 24B appear on page 3 of Table 1 and in Table 2. Analytical Results
There are two result tables attached. The first, Table 1, is the summary table from the Laboratory Information Management System (LIMS). Table 2 provides additional calculated results for net exothermic energy and the total energy, requested by the Flammable Gas Safety Program cognizant scientist. The data used for these calculations was obtained from the summary report and additional information that is reported in the comment section for each sample in the LIMS.
TGA (Moisture)
The weight percent water by thermogravimetric analysis (TGA) was performed on a Mettler Model 20 thermogravimetric analyzer, using procedure LA-560-112 with an air purge. All samples results met the accuracy and precision criteria of 20%. The results were all within the range of 31.81% water to 42.46% water. There were no notification (action) limits for these analyses.
DSC
Differential thermal calorimetry (DSC) was performed using procedure LA-514-113, and a Mettler Model 20 differential scanning calorimeter under an air purge. There were no results which exceeded the notification limit of 586 Joules/g. One sample (S95T000107) exceeded the precision limit of 20%. This sample was from the portion of Riser 13A that consisted of crust material mixed with sludge. The initial sample result was 86.4 Joules/g and the duplicate was 0 Joules/g. A third sample was run giving a result of 111.3 Joules/g, which was reported as the duplicate in the summary report. The duplicate had a second endotherm at 300°C that did not appear in the other two analyses. No further reruns were requested due to the small exotherm, the dose rate and the heterogeneous nature of this sample. All samples met the accuracy criterion of 20%.
3
<• t
WHC-SD-WM-DP-097, REV. 0 Sample S95T000102, collected from Riser 13A just below the crust layer, produced three exotherms. The first was 14.7 Joules/g, the second 30.5 Joules/g, and the third 77.7 Joules/g. The sum of the three is reported in Table 1. The dry weight calculations for the exothermic energy were calculated using the sum of all measured exotherms. The sample result for dry weight was calculated using the percent water result reported as sample, and the duplicate used the percent water result reported as duplicate. Due to the heterogeneous nature of these samples, this method of calculation may introduce an additional precision error. This is exemplified in sample S95T000102 by the increase in the relative percent deviation (RPD) between the sample and duplicate from 11.5% for exothermic energy based on wet weight to 23.3% based on dry weight. Since the duplicate result for sample number S95T000107 was 0 Joules/g, the result of 111.3 Joules/g, measured on the third sample portion, was used for the dry weight calculation for the duplicate.
Reference WHC-SD-WM-TP-229, REV. 0, "Tank 241-AW-101 Tank Characterization Plan", dated November 22, 1994, Westinghouse Hanford Company, Richland, WA 99352
4
jf I
WHC-SD-WM-DP-097, REV. 0
SAMPLE DATA SUMMARY
5
06-mar-1995 11:58:06 A-0002-1
Page: 1
Table 1: 40 DAY CRUST BURN SAFETY ISSUE RESULTS AW-101
CORE NUMBER: n/a SEGMENT #: 95-AUG-001 SEGMENT PORTION Facie
Sample* R A# Analyte Unit Action Limits
Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% Sample* R A# Analyte Unit Lower Upper Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% S95T000107 % Water by TGA using Mettler % n/a n/a 98.67 n/a 41.33 41.01 41.17 0.78 n/a 0.000 n/a S95T000107 DSC Exotherm Dry Calculated Joules/g Dry n/a :;$8&;$QS: n/a n/a 147 189 168.0 25.0 n/a 0.000 n/a S95T000107 DSC Exotherm using Mettler Joules/g n/a n/a 105.4 n/a 86.4 111.3 98.85 25.2 n/a 0.000 n/a SEGMENT PORTION: U Upper Half of Segment
Sample* R A# Analyte Unit Action Limits
Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% Sample* R A# Analyte Unit Lower Upper Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% S95T000102 % Water by TGA using Mettler % n/a n/a 98.67 n/a 38.82 37.24 38.03 4.15 n/a 0.000 n/a S95T000102 DSC Exotherm Dry Calculated Joules/g Dry n/a ;*5&™e: n/a n/a 201 159 180.0 23.3 n/a 0.000 n/a S95T000102 DSC Exotherm using Mettler Joutes/g n/a n/a 105.4 n/a 122.9 99.6 111.2 20.9 n/a 0.000 n/a
SEGMENT PORTION: L Lower Half of Segment
Sample* R A# Analyte Unit Action Limits
Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% Sample* R A# Analyte Unit Lower Upper Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% S95T000103 % Water by TGA using Mettler % n/a n/a 98.56 n/a 39.94 40.62 40.28 1.69 n/a 0.000 n/a S95T000103 DSC Exotherm Dry Calculated Joules/g Dry n/a ISS&H® n/a n/a 190 217 203.5 13.3 n/a 0.000 n/a S95T000103 DSC Exotherm using Mettler Joules/g n/a n/a 103.0 n/a 114 128.9 121.5 12.3 n/a 0.000 n/a
=> Limit violated => Selected Limit
<T»
06-mar-1995 11:58:23 A-0002-1
Page: 2
Table 1: 40 DAY CRUST BURN SAFETY ISSUE RESULTS AW-101
CORE NUMBER: n/a SEGMENT #: 95-AUG-004
SEGMENT PORTION U Upper Half of Segment
Sample* R A# Analyte Unit Action Limits
Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% Sample* R A# Analyte Unit Lower Upper Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% S95T00O110 % Water by TGA using Mettier % n/a n/a 98.56 n/a 41.90 42.13 42.02 0.55 n/a 0.000 n/a S95T000110 DSC Exotherm Dry Calculated Joules/g Dry n/a •^MMsm n/a n/a 175 193 184.0 9.78 n/a 0.000 n/a S95T000110 DSC Exotherm using Mettler Joules/g n/a n/a 103.0 n/a 101.5 111.6 106.5 9.48 n/a 0.000 n/a SEGMENT PORTION: L Lower Half of Segment
Sample# R A# Analyte Unit Action Limits
Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% Sample# R A# Analyte Unit Lower Upper Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% S95T000111 % Water bv TGA using Mettler % n/a n/a 97.91 n/a 39.21 38.75 38.98 1.18 n/a 0.000 n/a S95T000111 DSC Exotherm Dry Calculated Joules/g Dry n/a MSSil^ n/a n/a 119 114 116.5 4.29 n/a 0.000 n/a S95T000111 DSC Exotherm using Mettler Joules/g n/a n/a 104.4 n/a 72.4 69.8 71.10 3.66 n/a 0.000 n/a
=> Limit violated => Selected Limit
< ! O o
o -a <b to
ID rn
06-mar-1995 11:58:35 A-0002-1
Page:
CORE NUMBER: n/a SEGMENT #: 95-AUG-005
Table 1: 40 DAY CRUST BURN SAFETY ISSUE RESULTS AW-101
SEGMENT PORTION U Upper Half of Segment
Sample* R A# Analyte Unit Action Limits
Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% Sample* R A# Analyte Unit Lower Upper Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% S95T000113 % Uater by TGA using Mettler % n/a n/a 97.91 n/a 31.81 35.80 33.80 11.8 n/a 0.000 n/a S95T000113 DSC Exotherm Dry Calculated Joules/g Dry n/a i^^i n/a n/a 248 270 259.0 8.49 n/a 0.000 n/a S95T000113 DSC Exotherm using Mettler Joules/g n/a n/a 104.4 n/a 168.9 173.1 171.0 2.46 n/a 0.000 n/a
SEGMENT PORTION: L Lower Half of Segment
Sample# R A# Analyte Unit Action Limits
Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% Sample# R A# Analyte Unit Lower Upper Standard % Blank Result Duplicate Average RPD % Spk Rec % Det Limit Count Err% S95T000114 % Water by TGA using Mettler % n/a n/a 99.43 n/a 42.46 38.13 40.30 10.7 n/a 0.000 n/a S95T000114 DSC Exotherm Dry Calculated Joules/g Dry n/a sSSMQa; n/a n/a 177 162 169.5 8.85 n/a 0.000 n/a S95T000114 DSC Exotherm using Mettler Joules/g n/a n/a 102.6 n/a 101.8 100.1 100.9 1.68 n/a 0.000 n/a
=> Limit violated => Selected Limit
0a o
o
s
Table 2: Additional Calculated Results for Tank 241-AW-101 Crust Burn Flammable Gas Safety Issue
95-AUG-001 Riser 13A
Sample # Segment Portion
Net Exothermic Energy (Joules/g Dry)
Net Exothermic Energy (Joules/g)
Net Endothermic Energy (Joules/g)
Total Energy (Joules/g)
Notification Limit 586.6
S95T000107 Facie (Crust) 147.0 86.40 1285 -1198
S95T000102 Upper half sludge 201.0 122.9 1129 -1006
S95T000103 Lower half sludge 190.0 114.0 842.1 -728.1
95-AUG-004 Riser 12A
Sample # Segment Portion
Net Exothermic Energy (Joules/g Dry)
Net Exothermic Energy (Joules/g)
Net Endothermic Energy (Joules/g)
Total Energy (Joules/g)
Notification Limit 586.0
S95T000110 Upper half sludge 175.0 101.5 1095 -993.4
S95T000111 Lower half sludge 119.0 72.40 999.2 -926.8
95-AUG-005 Riser 24B
Sample # Segment Portion
Net Exothermic Energy (Joules/g Dry)
Net Exothermic Energy (Joules/g)
Net Endothermic Energy (Joules/g)
Total Energy (Joules/g)
Notification Limit 586.6
S95T000113 Upper half sludge 248.0 168.9 976.6 -807.7
S95T000114 Lower half sludge 177.0 101.8 974.8 -873.0
t I
WHC-SD-WM-DP-097, REV. 0
UNDIGESTED SAMPLE ANALYSES- DIRECT
10
LABCORE Data Entry Template for Worklist# 583
Analyst: ^"""ffif/ Instrument: DSC01 Method:
Worklist Comment: Calculated AW-101 dry DSC. bdv
Seg Type Sample# RepAI Test Matrix
1 SAMPLE S95T000107 0 DSC-02 SOLID
2 DUP S95T000107 0 DSC-02 SOLID
3 SAMPLE S95T000102 0 DSC-02 SOLID
4 DUP S95T000102 0 DSC-02 SOLID
5 SAMPLE S95T000103 0 DSC-02 SOLID
6 DUP S95T000103 0 DSC-02 SOLID
7 SAMPLE S95T000110 0 DSC-02 SOLID
8 DUP S95T000110 0 DSC-02 SOLID
9 SAMPLE S 9 5 T 0 0 0 1 1 1 0 DSC-02 SOLID
10 DUP S 9 5 T 0 0 0 1 1 1 0 DSC-02 SOLID
11 SAMPLE S95T000113 0 DSC-02 SOLID
12 DUP S95T000113 0 DSC-02 SOLID
13 SAMPLE S95T000114 0 DSC-02 SOLID
14 DUP S95T000114 0 DSC-02 SOLID
LA-514-113- n/».f
Wt -T3A D& da r\T\J -Actual
III. 3
I1U
(00.1
Analyst Signature Q~
Final page for worklist # 583
41-33 41.0/
Analyst Signature
ty Date
Unit
m 122.3 3%.R2> Z0\ <¥\.f> 37.i4 159 H4.0 3QM i%
\i£.<\ 10.U Zil-101.5 M.% 1̂ 5
42-/3 1̂ 3 7 i l4 31.21 11̂ k°i.% 38.15 |i4 ! # . ? J/.g) 24? 173.1 3 5 ft) 5-70
m 38-13
Joule
Joule <* Joule
JouleT
Joule*"
Joule^
Joule*
Joule^
Joule^
Joule^
Joule
Joule*1
Joule
Joule
WHC-SD-WM-DP-097, REV. 0
Data Entry Comments: «*. u-mH - 3bo-\«/g
Uh/& shown for QC (SPK) may not reflect the actual units.
1 1
Page: 1
LABCORE Data Entry Template for WorkhW 538 • »
Analyst: .bios Instrument: DSC01 Method: LA-514-113 B-l WorWist Comment: Please run AW-101 DSC UNDER AIR. bdv
WHC-SD-WM-DP-097, REV. 0 Seg Type Sample# RepAl Test Matrix Actual Found DL Unit
1 STD tWIHA DSC-01 SOLID AIH5 60.0 N/A T 1 ^ J o u l e
2 SAMPLE S 9 5 T 0 0 0 1 0 7
S 9 5 T 0 0 0 1 0 7
0
0
DSC-01
DSC-01
DSC-01
SOLID
SOLID
SOLID
N/A
•Or N/A
N/A
J o u l e
3 DUP
S 9 5 T 0 0 0 1 0 7
S 9 5 T 0 0 0 1 0 7
0
0
DSC-01
DSC-01
DSC-01
SOLID
SOLID
SOLID
8U 32M5
•Or N/A
N/A
J o u l e
4 STD
S 9 5 T 0 0 0 1 0 7
S 9 5 T 0 0 0 1 0 7
0
0
DSC-01
DSC-01
DSC-01
SOLID
SOLID
SOLID
8U 32M5 «#.?
N/A
N/A J o u l e "^
5 DUP2 S 9 5 T 0 0 0 1 0 7 0 DSC-01 SOLID ®(oA ///. -2 N/A J o u l e
6 SAMPLE S 9 5 T 0 0 0 1 0 2
S 9 5 T 0 0 0 1 0 2
0
0
DSC-01
DSC-01
SOLID
SOLID
N/A
I3.| J o u l e Hf
7 DUP
S 9 5 T 0 0 0 1 0 2
S 9 5 T 0 0 0 1 0 2
0
0
DSC-01
DSC-01
SOLID
SOLID I*? I3.| N/A J o u l e *
Final page for worklist # 538
Analyst Signature ' « Q cJ Date
^ l^w ̂ - 3bu.Ws l<\
g( ia^.b^/a. S15TD00IQ^ prsduxx^ an wcfoihcrm ajr \*pcL ajiih ^ dilfa. M U l̂.Z /̂a ; -/hi Sample oJso JMUL Z ctfw .QMcrtfWmp ar\o aJc
^!6 TC arith a dllta, H- <l 30.5 JA *M Mo Unto shown for QC (SPK) may not reflect the actual units. ^ l ^ ' T ^ »u I m u. wxw u, VQ ^ ^ . ^ 1 Oih&r (U- 4 3 U ' G c0i+*i a fllttf* H ̂ ^ 7 . ? ^
LABCORE Data Entry Template for Worklist# 538
Analyst: rWS
Worklist Comment: Please
Instrument: DSC01 Method: LA-514-113 - £ - (
run AW-101 DSC UNDER AIR. bdv WHC-SD-WM-DP-097, REV. 0
Seg Type
1 STD
2 SAMPLE
Sampled
S95T000107
S95T000107
S95T000102
S95T000102
Rep AI
0
0
0
0
Test
DSC-01
DSC-01
DSC-01
DSC-01
DSC-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
Actual
N/A
Found
30.0 8^4
DL
N/A
Unit
Joule
Joule
3 DUP
Sampled
S95T000107
S95T000107
S95T000102
S95T000102
Rep AI
0
0
0
0
Test
DSC-01
DSC-01
DSC-01
DSC-01
DSC-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
01.1 N/A
Found
30.0 8^4
N/A
N/A
Joule
4 SAMPLE
Sampled
S95T000107
S95T000107
S95T000102
S95T000102
Rep AI
0
0
0
0
Test
DSC-01
DSC-01
DSC-01
DSC-01
DSC-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
01.1 N/A
N/A
N/A
Joule
5 DUP
Sampled
S95T000107
S95T000107
S95T000102
S95T000102
Rep AI
0
0
0
0
Test
DSC-01
DSC-01
DSC-01
DSC-01
DSC-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
N/A
N/A Joule
IX Analyst Signature
«™&Z^ -
Final page for worklist # 538
2-/£-<r.r Date
Data Entry Comments:
Units shown for QC (SPK) may not reflect the actual units. Page:
13
DSC STD wm 6.465 mg Rate: 10.0 *C/min
File: 00035.001 Ident: 0.0
DSC METTLER i2-Feb-95 222-S Laboratory
Integration Delta H 194 mJ
30.0 J/g Peak 158.6*C
-14.5 mW o CO o o
m
SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST THAT COMPLETED/VERIFIED THE CALIBRATION/ANALYSIS ON PAGES 14 TO 20
120 140. 160 180 'C
-iv-VJ"
DSC STD 12N14A F i le : 00057.001 DSC METTLER 13--Feb-95 6.465 mg Rate: 10 0 *C/min Ident: 0. 0 222-•S Laboratory
exo>
I i •
hi i }
i l l
1 HIT
E
in I
( i I I 1 I 1 t 1 < 1 i
[ » WHC-SD-
1 i 1 I 1 I 1 i 1 I 1 i 1 i In tegrat ion
•WM-D
1 i I t I I I I I t l i It I I 11 11 li li
Delta
Peak
H 192 mJ 2 9 . 7 J / g
1 5 8 . 7 # C - 1 2 . 4 mW
P-097, REV. 0
i 1 1 i - '"T" 1 ' i 1 ' l 1 •
120. 140 . 160 . 180 . •c
)
AjJLh-^t
S95T000107 AIR 17.406 mg Rate: 10.0 *C/min
F i le : 00037.001 DSC METTLER Ident: 0.0 222-S Laboratory
• i
l lTITlVr^ i t i *
^ — 1 1
12-Feb-95
BEST AVAILABLE COPY
Integration' Delta H 1504
86.4 Peak 399.6'
3.0
Integration Delta H22360 mJ
1284.6 J/g Peak 132.9*C
-53.2 mW
mJ J/g c mW
o CO
to
m
i 1 1 1 1 r
100. — I — 400. •c 200. 300
S95T000107(DUP) AIR 23.346 mg Rate: 10.0 *C/min
Fi le :00039.001 Ident: 0.0
DSC METTLER 222-S Laboratory
12-Feb-95
Integration Delta H 2127 mJ
91.1 J/g Peak 302.4*C
-13.0 mW o en o
o
o
100 200 300 400 "C
S95T000107 (DUP2) AIR 19.4B1 mg Rate: 10.0 *C/min
F i l e : 00058.001 Ident : 0.0
DSC METTLER l3-Feb-95 222-S Laboratory
Integration Delta H20986 mJ
1077.3 J/g Peak 132.7'C
-55.4 mW
Integration Delta H 2168 mJ
1 i i. 3 J, g Pea* 3?5.7*C
4.8 mW
BEST AVAILABLE COPY o CO
o
o
<o
m o
100. 200 300 " ~ 1 — 400. •c
S95T000102 21 .990 mg
A o x Q)
AIR Rate: 10.0 *C/min
F i l e : 00041 .001 Ident: 0 . 0
DSC METTLER 222-S Laboratory
12-Feb-95
3: E
O in
Integration Delta H 324 mJ
14.7 J/g Peak 241.3' •c
1.7 mW
J™ Del ta H 671
30.5 Peak 315.7
5.6
I n t e g r a t i o n Del ta H24831 mJ
1129.2 J/g Peak 130. r c
-63 .8 mW
mJ J/g C mW Integration Delta H 1708
77.7 Peak 431
4 6 5
DO
o mJ J/g C mW
100. 200. 300. 400. •c
S95T000102(DUP) AIR 18.288 mg Rate: 10.0 *C/min
F i l e : 00043.001 DSC METTLER 12-Feb-95 Ident : 0.0 222-S Laboratory
317 .6 3 . 3
c mW
10
o in
nnrn^_
BEST AVAILABLE COPY
Integration Delta H17993 mJ
983.9 J/g Peak 130.5' 'C
-57.3 mW
o CO
o to
a Integration Delta H 1139 mJ
62.3 J/g Peak 421.6'C
2.9 mW
100. 200. 300. ~~1— 400. 'C
LABCORE Data Entry Template for Worklist# 539
Seg Type Sample? Rep Al Test
1 STD I2AMMA DSC-01
2 SAMPLE S95T000103 0 DSC-01
3 DUP S95T000103 0 DSC-01
4 SAMPLE S95T000110 0 DSC-01
5 DUP S95T000110 0 DSC-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
Actual
4 MS Found
J1A
%d^2^>_ "/. I ^uJ^, Analyst Signature
^ >
Final page for worklist # 539
'^[{mirnd^ (duru-
Date
N/A
/
^
Analyst: "^Jfttf Instrument: DSC01 Method: LA-514-113 / / S /
Worklist Comment: Please run AW-101 UNDER AIR. bdv WHC-SD-WM-DP-097, REV. 0 DL Unit
N/A m.o
101.5 I I I . b
m.o m.o
101.5 I I I . b
N/A
N/A
m.o
101.5 I I I . b 10/.5
m.o
101.5 I I I . b N/A
Joule
Joule
Joule
Joule
Joule
Data Entry Comments:
- ]Q£ I \^AJoX^ Z12UP5.
Units shown for QC (SPK) may not reflect the actual units. 21
DSC STD I2WM/4 6.465 mg Hate: 10.0 *C/min
F i l e : 00046.001 DSC METTLER 13-Feb-95 Ident : 0.0 222-S Laboratory
Integration Delta H 189 mJ
29.3 J/g Peak 158.7"C
-13.7 mW
SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST THAT COMPLETED/VERIFIED THE CALIBRATION/ANALYSIS ON PAGES 22 TO 26 .
_, , j r
140 .
o t
CO o
o
120 180
'Y. yj£*J''fern^ *C
< z ^
2 / 2 2 / ^
S95T000110 AIR 14.032 mg Rate: 10.0 *C/min
File: 00051.001 Ident: 0.0
DSC METTLER l3-Feb-95 222-S Laboratory
Integration Delta H15364
1094.S Peak 135.4'
-37.8
Integration Delta H 1600 mJ
1 1 4 . 0 J / g Peak 3 1 5 . 6 ' C
4 . 3 rnVi
BEST AVAILABLE COPY
mJ J / g C mW
9 CO o
o
J*4
m
100 ~ " 1 — 200.
~ I — 3 0 0 .
~ ~ I — 4 0 0 . # C
S95T000110(DUP) AIR 16.651 mg Rate: 10.0 *C/min
File: 00053.001 Ident: 0.0
DSC METTLER 222-S Laboratory
13-Feb-95
Integration Delta H 99 mJ
5 .9 J /g Peak 2 3 1 . l ' C
- 1 . 8 mW
Integral ion f j t l t a H P.iAS mJ
i ? 8 . 9 J / g t rf Ps 3 2 1 ,~ '*C
6 . ~i ml
BEST AVAILABLE COPY Integration Delta H16539 mJ
993.3 J/g Peak 141.0*C
- 4 4 . 6 mW
o CO
5 CO
m .<: o
100. 200 300. 400. •c
S95T000103 AIR 16.573 mg Rate: 10.0 *C/min
File: 00047.001 Ident: 0.0
DSC METTLER l3-Feb-95 222-S Laboratory
en
EST AVAILABLE COPY
CO
o
o •D <S > l
m . < o
100 — 1 — 200. 3 0 0 . 4 0 0 . %C
S95T000103(DUP) AIR 10.709 mg Rate: 10.0 *C/min
File: 00049.001 Ident: 0.0
DSC METTLER 13-Feb-95 222-S Laboratory
IS) (7).
3* o
I
o
EST AVAILABLE COPY
o
m :< o
I n t e g r a t i o n Del ta H 6677 mJ
623.4 J /g Peak 124.4*C
- 1 7 . 5 mW
100. ~ ~ l — 200.
~ ~ 1 — 300.
_ _ 1 —
400. *C
LABCORE Data Entry Template for Worklist# 540
Analyst: DUB Instrument: DSC01
WorkMst Comment: Please run AW-101 UNDER AIR. bdv
Seg Type Sample# RepAI Test Matrix
1 STD \2titt-A DSC-01 SOLID
2 SAMPLE S 9 5 T 0 0 0 1 1 1 0 DSC-01 SOLID
3 DUP S 9 5 T 0 0 0 1 1 1 0 DSC-01 SOLID
4 SAMPLE S 9 5 T 0 0 0 1 1 3 0 DSC-01 SOLID
5 STD 12-MlH-A DSC-01 SOLID
6 DUP S 9 5 T 0 0 0 1 1 3 0 DSC-01 SOLID
Method: LA-514-113 B ' l
WHC-SD-WM-DP-097, REV. 0 Actual Found DL Unit
J17A5 S°iA N/A -*•£. H
Final page for worklist # 540
Analyst Signature 0
Verifcrn ^ 1 ^ ^ ^ r Date
^ / / ? 5 "
N/A Joule^
Joule^
1lA 6^-ff N/A Joulef
N/A \loB -^ Joule"*
N/A Joule 5*
\M>°I 173.1 N/A Joule-*
>f aw ̂ _s = jiouAes/«
ItaaE/rtry wwwtt. ^ 5 T D Q Q H j p r D 0 [ t L a ( ( faro J / V ^ Q ^ A W OlOg A> 13?-, 3°G
LUrJ-ffi QL djulfzc H ̂ ^18.1- ^/a^Quniih dudimd oJr 33-5.0°C yjiiha. (ktt(tW s^ ACS T/a. 395"Tt)0D//3 pwdMdul m wdoifaiMvi af 135",2'6 Units Shoffar QC (SPK) may not reflect the actual units. UJJTrl A flUTO, n ^ ^rh.b fa Page: I
27 °
LABCORE Data Entry Template for Worklist# 540
Analyst: Instrument: DSC01
Worklist Comment: Please run AW-101 UNDER AIR.
Method: LA-514-113 £ - 1
bdv WHC-SD-WM-DP-097, REV. 0
Seg Type
1 STD
Sample# Rep Al
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 3 0
S 9 5 T 0 0 0 1 1 3 0
Test
DSC-01
DSC-01
DSC-01
DSC-01
DSC-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
Actual Found DL
N/A
N/A
N/A
Unit
J o u l e
2 SAMPLE
Sample# Rep Al
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 3 0
S 9 5 T 0 0 0 1 1 3 0
Test
DSC-01
DSC-01
DSC-01
DSC-01
DSC-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
N/A
DL
N/A
N/A
N/A
J o u l e
3 DUP
Sample# Rep Al
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 3 0
S 9 5 T 0 0 0 1 1 3 0
Test
DSC-01
DSC-01
DSC-01
DSC-01
DSC-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
DL
N/A
N/A
N/A
J o u l e
4 SAMPLE
Sample# Rep Al
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 3 0
S 9 5 T 0 0 0 1 1 3 0
Test
DSC-01
DSC-01
DSC-01
DSC-01
DSC-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
N/A
DL
N/A
N/A
N/A
J o u l e
5 DUP
Sample# Rep Al
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 3 0
S 9 5 T 0 0 0 1 1 3 0
Test
DSC-01
DSC-01
DSC-01
DSC-01
DSC-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
DL
N/A
N/A
N/A
J o u l e
Analyst Signature
Final page for worklist # 540
2-/g- <rT-Date
Data Entry Comments:
Units shown for QC (SPK) may not reflect the actual units. Page: 1
DSC STD IzMW'A 6.465 mg Rate: 10.0 'C/mln
File:00076.001 Ident: 0.0
DSC METTLER 18-Feb-95 222-S Laboratory
E o
Integration Delta H 192 mJ
29.7 J/g Peak 158.5*C
-14.0 mW
SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST COMPLETED/VERIFIED THE CALIBRATION/ANALYSIS ON PAGES 29 TO 34
~ T ™ ~ 120.
9 CO
o CO
m <£ O
140 160. 180. *C
S95T000111 AIR 16.623 mg Rate: 10.0 * C/min
F i le : 00077.001 DSC METTLER i8-Feb-95 Ident: 0.0 222-S Laboratory
Integration Delta H 340 mJ
20.5 J/g Peak 233.0*C
-4.6 mW
Integration Delta H16269 mJ
978.7 J/g Peak 137.2*C
-39.5 mW
Integration Delta H 1204 mJ
72 .4 J /g Peak 319 .7 'C
3 .8 mW
o CO
o -o <b
5S o
100. —T— 200. 300 400.
~T" *C
S95T000111 (DUP) AIR 80.028 mg Rate: 10.0 *C/min
T "
Fi le:00079.001 DSC METTLER i8-Feb-95 Ident: 0.0 222-S Laboratory
^yfiiV; . i • * 1
Integration Delta H 621 mJ
31.0 J/g Peak 232.8'C
-7.5 mW
100.
Integration Delta H19251 mJ
961.5 J/g Peak 134.6*C
-48.0 mW
T 200. 300
Integration Delta H 1398 mJ
69.8 J/g r L d ix 317 7*C
D . b mw
BEST AVAILABLE COPY
4 0 0 .
CO o
o <b
rn .<
_ ~ J >
r S95T000113 AIR 17.158 mg Bate: 10.0 *C/min
Fi le: 00081.001 Ident: 0 .0
DSC METTLER l8-Feb-95 222-S Laboratory
Integration Delta H16756 mJ
976.6 J/g Peak 135.2"C
-40.3 mW
Integration Delta H 2 8 Si 7 mJ
168.3 J/g Peak 3?i,?"C
5.2 mW
BEST AVAILABLE COPY 9 CO o
I
o _"vl ID
rn o
T
100. 2 0 0 . 3 0 0 . — 1 _
4 0 0 . •c
DSC STD 12N14-A 6.465 mg Rate: 10.0 *C/min
File: 00083.001 DSC METTLER l9~Feb-95 Ident: 0.0 222-S Laboratory
I n t e g r a t i o n D e l t a H 185 mJ
28 .6 J /g Peak 158.9*C
- 1 3 . 5 mW o CO
o
2 ID m . < o
160. 120. 140. 180. *C
UJolZX ^ t^-^
S95T000113(DUP)AIR 24.605 mg Rate: 10.0 *C/min
3: £
O in
Integration Delta H25665 mJ
1043.1 J/g Peak 131.6*C
-70.9 mW
T ™
100. 200.
F i le : 00085.001 DSC METTLER l9-~Feb-95 Ident: 0.0 222-S Laboratory
Integration Delta H 4260 mJ
173.1 J/g Peak 3?i.9*C
8.7 mW
BEST AVAILABLE COPY
o CO
o
to
m
300. -T——T"
400. - C J
LABCORE Data Entry Template for Worklist# 541
Analyst: •^tP Instrument: DSC01
Worklist Comment: Please run AW-101 UNDER AIR. bdv
Method: LA-514-113/^-^- fa/is
WHC-SD-WM-DP-097, REV. 0 Seg Type
1 STD
2 SAMPLE
3 DUP
Sample# Rep Al
S95T000114 0
S95T000114 0
Test
DSC-01
DSC-01
DSC-01
Matrix Actual Found
N/A ici.g SOLID
SOLID IOL6 (00.1
Final page for worklist # 541
Analyst Signature
Venfe (g^ (W— 0-YaJk^>-^
Date
DL Unit
SOLID o?f, *^5 <^<?- 2- N/A Joule
Joule
N/A Joule
-Hf u.m-V-s = -i^u-\£.%j.
Data Entry Comments: :S4swoons prodjucjicL -hjoo jmclo-Uwrmv cm aJr \3o,3*c tnfffia. (idJtvL H of ^-8^/j oM^k MtmcL /g.o J/j oJ- £35.z°c
Units shown for QC (SPK) may not reflect the actual units. Page: 1
35
DSC STD l^m 6.465 mg Rate: 10.0 *C/min
File:00061.001 Ident: 0.0
DSC METTLER -±4=-Feb-95
BEST AVAILABLE COPY
SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST THAT COMPLETED/VERIFIED THE CALIBRATION/ANALYSIS ON PAGES 36 TO
T
222-S Laboratory ^ C | « , 5
I n t e g r a t i o n D e l t a K 189 mJ
9.9.2 J / 'g Peak 5 8 . 7 * C
-i?.
o I
v>
•
38
S95T000114 AIR 11.416 mg Rate: 10.0 *C/min
File: 00062.001 Ident: 0.0
DSC METTLER 222-S Laboratory
i4^Feb-95
! ! t
!
. i MM i i
ii tf i ; 1 , i ; i? V '< U • :
S/8 X 1 5 »/ S \« B ! y • \f
' !..!..!
u Integration / Delta H 205 mJ ' 18.0 J/g
Peak 235.2* c ~2.5 mW
Integration Oelta H10922 mJ
956.8 J/g Peak 130.3*C
-21.4 mW
.Hi L q r a i i o n ijf.-;.. •.. d r: „ :'.bf- rr-'u
10 1 .6 J 'g
3 . 9 mW
3EST AVAILABLE COPY
HI o
I CO
o -a <b to
3 o
100. 200. ~ ~ l — 300.
~~! 400. *C
S95T000114(DUP) AIR 19.038 mg Rate: 10.0 *C/min
F i le : 00064.001 Ident: 0.0
DSC METTLER 222-S Laboratory
A O X 0)
e
o CM
a-TT"
Integration Delta H 438 mJ
23.0 J/g Peak 235.0'C
-5.6 mW
Integr "•ation Del ta H16695 mJ
876.9 J /g Peak 137.2 ' 'C
- 4 0 . 0 mW
Integration l.'e?. ta r' 190b mJ
' 100 . 1 u/'n Peak. 323.8*C
BEST AVAILABLE COPY
o CO o
o <b
m o
100. 200. ~ 1 — 300.
" 1 — 400. •c
LABCORE Data Entry Template for Worklist# 547
Analyst: b^S
Worklist Comment: Please
Instrument: TGA01 Method: LA-560-112 A ~Z.
run AW-101 TGA UNDER AIR. bdv WHC-SD-WM-DP-097, REV. 0
Seg Type
1 STD
Sample*
S 9 5 T 0 0 0 1 1 1
S 9 5 T 0 0 0 1 1 1
S 9 5 T 0 0 0 1 1 3
42.M8-A
S 9 5 T 0 0 0 1 1 3
RepAl
0
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
SOLID
Actual
N/A
Found
51.1 S" 6°iZ\
38.15 31.81 51.^5 35.80
DL
N/A
Unit
%
2 SAMPLE
Sample*
S 9 5 T 0 0 0 1 1 1
S 9 5 T 0 0 0 1 1 1
S 9 5 T 0 0 0 1 1 3
42.M8-A
S 9 5 T 0 0 0 1 1 3
RepAl
0
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
SOLID
Actual
N/A
Found
51.1 S" 6°iZ\
38.15 31.81 51.^5 35.80
%
3 DUP
4 SAMPLE
Sample*
S 9 5 T 0 0 0 1 1 1
S 9 5 T 0 0 0 1 1 1
S 9 5 T 0 0 0 1 1 3
42.M8-A
S 9 5 T 0 0 0 1 1 3
RepAl
0
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
SOLID
N/A
Found
51.1 S" 6°iZ\
38.15 31.81 51.^5 35.80
N/A
N/A
%
5 STD
Sample*
S 9 5 T 0 0 0 1 1 1
S 9 5 T 0 0 0 1 1 1
S 9 5 T 0 0 0 1 1 3
42.M8-A
S 9 5 T 0 0 0 1 1 3
RepAl
0
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
SOLID Si.81
Found
51.1 S" 6°iZ\
38.15 31.81 51.^5 35.80
N/A
N/A %
6 DUP
Sample*
S 9 5 T 0 0 0 1 1 1
S 9 5 T 0 0 0 1 1 1
S 9 5 T 0 0 0 1 1 3
42.M8-A
S 9 5 T 0 0 0 1 1 3
RepAl
0
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
SOLID Si.81
Found
51.1 S" 6°iZ\
38.15 31.81 51.^5 35.80 N/A %
Final page for worklist # 547
Analyst Signatured (_J n~*~ Date
\ aJkn^wi^
Data Entry Comments:
Units shown for QC (SPK) may not reflect the actual units. • J < 4 Page:
LABCORE Data Entry Template for Worklist# 547
Analyst: £$uK Instrument: TGA01 Method: LA-560-112 -4= A-Worklist Comment: Please run AW-101 TGA UNDER AIR. bdv
Analyst: £$uK Instrument: TGA01 Method: LA-560-112 -4= A-Worklist Comment: Please run AW-101 TGA UNDER AIR. bdv
Seg Type
1 STD
Sample# Rep Al
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 3 0
S 9 5 T 0 0 0 1 1 3 0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
Actual Found DL Unit
N/A %
2 SAMPLE
Sample# Rep Al
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 3 0
S 9 5 T 0 0 0 1 1 3 0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
N/A %
3 DUP
Sample# Rep Al
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 3 0
S 9 5 T 0 0 0 1 1 3 0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
N/A %
4 SAMPLE
Sample# Rep Al
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 3 0
S 9 5 T 0 0 0 1 1 3 0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
N/A %
5 DUP
Sample# Rep Al
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 1 0
S 9 5 T 0 0 0 1 1 3 0
S 9 5 T 0 0 0 1 1 3 0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID N/A %
Final page for worklist # 547
?-/*~?J-Date
WHC-SD-WM-DP-097, REV. 0
Date £nfry Comments:
Units shown for QC (SPK) may not reflect the actual units. 40
Page: 1
4*
TGA STD 42/J&-A File: 00075.001 TG METTLER 17-•Feb-95 ie i.595 mg Rate: 10.0 *C/min Ident: 0.0 222-S Laboratory
^ s . S t e p A n a l y s i s H e i g h t - 9 . 5 8 mg
- 5 7 . 7 5 % R e s i C . 7 . 0 1 mg
4 2 . 2 5 % Dpeak B3.0*C
D) p E GO <?
in
WM-DP-097, RE
?c
•
o
SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST THAT COMPLETED/VERIFIED THE CALIBRATION/ANALYSIS ON PAGES 4 1 TO 4 6 .
I.
1 j 1 1 i i 1 " i « "™! 1 1 I
5 0 . 100 . 1 5 0 . • i
•c
^/7 ^ J
S95T000111 AIR Fi le : 00078.001 TG METTLER 17-Feb-95 20.885 mg
j Rate: 10.0 #C/mln Ident: 0.0 222-S Laboratory
i\
Step Analysis Height - 8 . 1 9 mg
- 3 9 . 2 1 % ResiC. 12.70 mg |
D> 60.79 %
C-S
E Dpeak 105.0*C o •
in
\
i/VM-DP-097, REV.
o
T 1 1 r- —r T— T 1 1 — I — T - i i 1 — -i — i — T r . 1 . . . . , 100. 200. 300. 400. *C
S95T00011KDUP) AIR Fi le : 00080.001 TG METTLER 17-Feb-95 25.585 mg Rate:
i 10.0 *C/min Ident: 0.0 222-S Laboratory
K Step Analysis Height - 9 . 9 1 mg
- 3 8 . 7 5 % ResiC. 15.67 mg
61.25 %
WHC-SD-
CJ) E Dpeak 111.0'C § in
-DP-097, REV.
.
X i
o
i
o
*T 1 • I 1 1 1 1 i | i 1 i i I k i i • • i i i • 1 100. 200. 300. 400. •c
S95T000113 AIR 22.734 nig Rate: 10.0 *C/min
File: 00082.001 TG METTLER 17-Feb-95 Ident: 0.0 222-S Laboratory
CD E
in
Step Analysis Height -7.23 mg
-31.81 % ResiC. 15.50 mg
6 8 . 1 9 % Dpeak l l l . C T C
— » - • -
100. ~~T— 200.
~ i — — T ~ 1 r ~ T 300.
T r
O i
CO
o o
DO m O
~n— 400. •c
TGA STD 42N8-A File: 00084.001 TG METTLER l8-Feb-95 15.459 mg Rate: 10.0 *C/min Ident: 0.0 222-S Laboratory
T - i : j — ; "T- '—i ! 1 T ~ — j •—r — r — — 1 — — — T : j 1— 1 . ,- — r
5 0 . 100 . 1 5 0 . 'C
S95T000113(DUP)AIR Fi le : 00086.001 TG METTLER 18-Feb-95 24.736 mg Rate:
• < •
10.0 *C/min Ident: 0.0 222-S Laboratory
i\
Step Analysis Height - 8 . 8 6 mg
-35 .80 % OHM
5.
mg ResiC. 15.88 mg
64.20 % Dpeak 113.O'C
-SD-WM-DP-097, REV.
o
T 1 1 1 1 1 1 1 i | i i t i i i I I • i I I • 1 1 100. 200. 300. 400. •c
LABCORE Data Entry Template for Worklist# 545
Analyst: pud S
Worklist Comment: Please
Instrument: TGA01 Method: LA-560-112-R—&• A-2.
run AW-101 TGA UNDER AIR. bdv W H C . S D . W M . D p ^ 7 p ^ ^ l *
Seg Type
1 STD
Sample?
S 9 5 T 0 0 0 1 0 7
S 9 5 T 0 0 0 1 0 7
S95TQ00102
S 9 5 T 0 0 0 1 0 2
RepAl
0
0
0
0
Test Matrix i
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
i j Actual
N/A
Found
58,40 Ml.33 m.oi 38.82-31.7A
DL Unit
N/A %
2 SAMPLE
Sample?
S 9 5 T 0 0 0 1 0 7
S 9 5 T 0 0 0 1 0 7
S95TQ00102
S 9 5 T 0 0 0 1 0 2
RepAl
0
0
0
0
Test Matrix i
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
i j Actual
N/A
Found
58,40 Ml.33 m.oi 38.82-31.7A
O
3 DUP
Sample?
S 9 5 T 0 0 0 1 0 7
S 9 5 T 0 0 0 1 0 7
S95TQ00102
S 9 5 T 0 0 0 1 0 2
RepAl
0
0
0
0
Test Matrix i
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
Hi. 33 N/A
Found
58,40 Ml.33 m.oi 38.82-31.7A
N/A %
4 SAMPLE
Sample?
S 9 5 T 0 0 0 1 0 7
S 9 5 T 0 0 0 1 0 7
S95TQ00102
S 9 5 T 0 0 0 1 0 2
RepAl
0
0
0
0
Test Matrix i
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
Hi. 33 N/A
Found
58,40 Ml.33 m.oi 38.82-31.7A
"5
5 DUP
Sample?
S 9 5 T 0 0 0 1 0 7
S 9 5 T 0 0 0 1 0 7
S95TQ00102
S 9 5 T 0 0 0 1 0 2
RepAl
0
0
0
0
Test Matrix i
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID
TGA-01 SOLID 388Z
Found
58,40 Ml.33 m.oi 38.82-31.7A N/A %
Final page for worklist # 545
2 - /-2,-^LT Date
^ W x « ^ DValingJ^ 4 - ^ - 9 5
Ztaia £>z#y Comments:
Units shown for QC (SPK) may not reflect the actual units. Page: 1
47
TGA STD 4ZW8A F i l e : 00034.001 TG METTLER 12 -Feb-95 18.771 mg Rate: 10.0 *C/min Ident: 0.0 222-S Laboratory
•
i 1 j
1 ^ s .
Step Analys i s Height -10.96 mg
-58 .40 % %. ResiC. 7 .81 mg O
i 41.60 % o O) Dpeak 90.3*C E i
o # -a in
-097, REV.
^""""~*-»^ ^ ^ > ~ ^
o
SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST THAT COMPLETED/VERIFIED THE CALIBRATION/ANALYSIS ON PAGES 4 8 TO 52 .
I i | i i i i | i i i i i i i i
5 0 . 1 0 0 . 1 5 0 . 1
"C
S95T000107 AIR F i l e : 00036.001 TG METTLER 12-Feb-95 IS 1.243 mg Rate: 10.0 *C/min Ident : 0.0 222-S Laboratory
\
Step Analysis -OHM
Ol Height - 7 . 9 5 mg o E - 4 1 . 3 3 %
W in ResiC. 11.29 mg
58.67 % Dpeak 105.O'C
\ •
-DP-097, REV. 0
'
' ' ' ' 1 ' 100.
» • • - — - — — - — • - - • • • . - — • — — — — — — • — — • — • • -
, _,. ..., ... . 1 — ...T_. ,,... , . , ,.. ,
200. 300. i | i r i
400. ' 1
•c
S95T000107(DUP) AIR 20.286 mg Rate: 10.0 *C/min
F i l e : 00038.001 Ident: 0.0
TG METTLER 12-Feb~95 222-S Laboratory
en E in
Step Analysis Height
ResiC.
Dpeak
-8.32 mg 41.01 % 11.97 mg 58.99 %
109.0' 'C
o I c/> o
a
100. 200 300. —\ 400.
S95T000102 AIR 20 .611 mg Rate: 10.0 *C/min
File:00040.001 Ident: 0.0
TG METTLER 12-Feb-95 222-S Laboratory
e
in
Step Analysis Height - 8 . 0 0 mg
- 3 8 . 8 2 % ResiC. 12.61 mg
6 1 . 1 8 % Dpeak 117.0*C
100 2 0 0 .
o •
CO o
o -o <b CO
ID ss
3 0 0 . ~ T — 4 0 0 . 'C
S95T000102(DUP) AIR Fi le :00042.001 TG METTLER 12-Feb-95 2C .088 mg Rate: 10.( ) 'C/min Ident : 0.0 222-S Laboratory
\
Step Analysis
en
Height - 7 . 4 8 mg - 3 7 . 2 4 %
ResiC. 12.61 mg
WHC-S
OT E 62.76 % o
1 _
tt ID
\.
VM-DP-097, REV. 0 i
"1 1— "I 1 1 1 ' 1 " " 1 1 ' | i i i r— " i "i - - i 1 — T 1 1 1 1 " - ' 1 100. 200. 300. 400. "C
LABCORE Data Entry Template for Worklist# 546
Analyst:
Worklist Co mment: Please
'instrument: TGA01 Method: 'LA-560-112./^-
run AW-101 TGA UNDER AIR. bdv
-9 A- z 6fc>V
Seg Type
1 STD
2 SAMPLE
Sample#
\\m-k S 9 5 T 0 0 0 1 0 3
S 9 5 T 0 0 0 1 0 3
S 9 5 T 0 0 0 1 1 0
S 9 5 T 0 0 0 1 1 0
RepAl
0
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
Actual
N/A
Found
At bz 41%
4i.\5
DL
N/A
Unit
%
%
3 DUP
Sample#
\\m-k S 9 5 T 0 0 0 1 0 3
S 9 5 T 0 0 0 1 0 3
S 9 5 T 0 0 0 1 1 0
S 9 5 T 0 0 0 1 1 0
RepAl
0
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
N/A
Found
At bz 41%
4i.\5
N/A %
4 SAMPLE
Sample#
\\m-k S 9 5 T 0 0 0 1 0 3
S 9 5 T 0 0 0 1 0 3
S 9 5 T 0 0 0 1 1 0
S 9 5 T 0 0 0 1 1 0
RepAl
0
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID
N/A
Found
At bz 41%
4i.\5 %
5 DUP
Sample#
\\m-k S 9 5 T 0 0 0 1 0 3
S 9 5 T 0 0 0 1 0 3
S 9 5 T 0 0 0 1 1 0
S 9 5 T 0 0 0 1 1 0
RepAl
0
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
SOLID 4*. r10
-42.12)
Found
At bz 41%
4i.\5 N/A "5
yam 6E>V
—^ Analyst Signature
Final page for worklist # 546
,^-/^-7^> Date
/-95-
Data £ntry Comments:
WHC-SD-WM-DP-097, REV. 0
Unity shown for QC (SPK) may not reflect the actual units. Page:
TGA STD H2.M8-A 15.357 mg Rate: 10.0 *C/min
F i l e : 00044.001 TG METTLER 12-Feb-95 Ident : 0.0 222-S Laboratory
-+
BEST AVAILABLE COPY
en
in
Step Analysis Height -8.96 mg
-58.34 % ResiC. 6.40 mg
41.66 % Dpeak 80.0'C
o I CO o
to
m :<
+ SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST THAT I COMPLETED/VERIFIED THE CALIBRATION/ANALYSIS ON PAGES 54 TO ! 58
T T ~t r ~t r ~1 200.
T r 50 100 150. *C
S95T000103 AIR 10.541 mg Rate: 10 .0 *C/min
O) E
CM
Step Analysis Height - 4 . 2 1 mg
- 3 9 . 9 4 % ResiC. 6 .33 mg
60 .06 % Dpeak 93.0*C
F i l e : 00048 .001 Ident: 0 . 0
TG METTLER 222-S Laboratory
12-Feb-95
9 CO
o
o CO
za m < : o
_J J J ( x { !
200. 300 100. I
400. *C
S95T000103(DUP) AIR File: 00050.001 TG METTLER 12-Feb-95 22.196 mg Rate:
• 10.0 *C/min Ident: 0.0 222-S Laboratory
i *
N T ~"t BEST AVAILABLE COPY
Step A n a l y s i s H e i g h t - 9 . 0 2 mg
- 4 0 . 6 2 % i OJ R e s i C . 13 .18 mg o E 59 .3B % CO
o in Dpeak 127 .0*C
WM-DP-097, RE
**" \ < :
+ \ •
\ i
o
1 I i 1
i i • • 1 i i i
100.
1 1 l 1 1 1 1 1 1 1 1 1 l l 1
2 0 0 . 3 0 0 . 4 0 0 . • 1
"C
S95T000110 AIR F i le : 00052.001 TG METTLER 12-Feb-95 7.301 mg Rate: 10.0 *C/min Ident : 0.0 222-S Laboratory
T 1 i 1 1 1 1 1 1 1 1 1 r 1 1 1 1 1 1 1 1 1 r
1 0 0 . 2 0 0 . 3 0 0 . 4 0 0 . *C
S95T000110 (DUP) AIR 19.890 mg
en E
in
Rate:10.0 *C/min F i le : 00054.001 TG METTLER Ident: 0.0 222-S Laboratory
12-Feb-95
ResiC
Step Analysis Height -8.38 mg
•A?.. 13 % 51 mg
0/ 5"7.B7' ,c Dpeak 97.0'C
BEST AVAILABLE COPY
o I
CO
o "O
m . < o
T r T 1 1 r T 1 1 r T r T r
100. 2 0 0 . 300 4 0 0 . •c
LABCORE Data Entry Template for Worklist# 548
Analyst: SMF
Worklist Comment: Please
Instrument: TGA01 Method: LA-560-112//?"^
run AW-101 TGA UNDER AIR. bdv WHC-SD-WM-DP-097, REV. 0
Seg Type
1 STD
Sample?
S95T000114
S95T000114
S95T000114
RepAl
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
Actual
N/A
Found
SB.85 DL
N/A
Unit
%
2 SAMPLE
Sample?
S95T000114
S95T000114
S95T000114
RepAl
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
Actual
N/A 4-ZAb %
3 DUP
Sample?
S95T000114
S95T000114
S95T000114
RepAl
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
4-2.U
42 Ab
3S.\3 N/A %
4 DUP2
Sample?
S95T000114
S95T000114
S95T000114
RepAl
0
0
0
Test
TGA-01
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
SOLID
4-2.U
42 Ab M.n N/A %
Analyst Signature/u 0
Final page for worklist # 548
Date
VerifoL h ' ^ U ; U V WuahjJih^
Date i&ziry Comments:
Units shown for QC (SPK) may not reflect the actual units. Page: 1
LABCORE Data Entry Template for Worklist# 548 < ' i -i
Analyst: ^'y^f Instrument: TGA01 Method: LA-560-112
Worklist Comment: Please run AW-101 TGA UNDER AIR. bdv WHC-SD-WM-DP-097, REV. 0
Seg Type
1 STD
Sample# Rep Ai
S 9 5 T 0 0 0 1 1 4 0
S 9 5 T 0 0 0 1 1 4 0
Test
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
Actual Found DL
N/A
Unit
a
2 SAMPLE
Sample# Rep Ai
S 9 5 T 0 0 0 1 1 4 0
S 9 5 T 0 0 0 1 1 4 0
Test
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID
N/A o
3 DUP
Sample# Rep Ai
S 9 5 T 0 0 0 1 1 4 0
S 9 5 T 0 0 0 1 1 4 0
Test
TGA-01
TGA-01
TGA-01
Matrix
SOLID
SOLID
SOLID N/A
Final page for worklist # 548
Analyst Signature Date
Data Entry Comments:
Units shown for QC (SPK) may not reflect the actual units. Page:
60
TGA STD W&b File: 00060.001 TG METTLER 13 -Feb-95 16.259 mg Rate: 10.0 *C/min Ident: 0.0
. SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST THAT 222-S Laboratory
J COMPLETED/VERIFIED THE CALIBRATION/ANALYSIS ON PAGES 6 1 TO 6 4 -
S t e p A n a l y s i s H e i g h t - 9 . 5 7 mg
- 5 8 . 8 5 % R e s i C . 6 . 6 9 mg
4 1 . 1 5 %
WHC-SI
5.
mg Dpeak 8 5 . 0 ' C
D-WM-DP-097, REV. 0
i •
1 1 i •
i l l i i i i i i • • i • i • i • 1 i I I •
50. 100. 150. /? ^ -7§00-n, sr. •c
c ^ 4lmfo5 m
S95T000114 AIR 10.971 mg Rate: 10.0 *C/min
E
OJ
Step A n a l y s i s H e i g h t - 4 . 5 6 mg
'-tC- , f C /C
ResiC. 5.3i mg
Doeak Sb.O'C
i 1 1 r
100. T — — r
2 0 0 .
File: 00063.001 TG METTLER i3-Feb-95 Ident: 0.0 222-S Laboratory
BEST AVAILABLE COPY
o I en o
o «b
33 a
1 1 1 1 1 1 1 1 1 1 r—
3 0 0 . 4 0 0 . *C
S95T000114(DUP) AIR 8.154 mg Rate: 10.0 *C/min
Step A n a l y s i s Height - 3 . 1 1 mg
- 3 8 . 1 3 % Res iC . 5 . 1 5 mg
63 .20 % Dpeak 91.0"C
E
cu
File: 00065.001 TG METTLER l3-Feb-95 Ident: 0.0 222-S Laboratory
o I
o
o
a
100 200. 300. 400. *C
S95T000114(DUP) AIR File: 00066.001 — — — - — — •
TG METTLER l3-Feb-95 12.110
•
mg Rate:10.0 *C/min Ident: 0.0 222-S Laboratory
i
! i i
Step Analysis Height - 5 . 0 6 mg
- 4 1 . 7 7 % ResiC. 7 .27 mg o
i _ 60.00 % CO
o Dpeak 93.0*C i
2.
mg . i
i \ 1 \ A
i-DP-097, REV.
o
1 f
! 1 — . .„ — « — . .,.—, _.. 3—.._
\Kk fv / V \ f\A.I\j*ji\l\Aji ^^^
i I I t
T 1 1 ' 1 * i i i 1 i i i . , . . . . | - - - * • I
__ 100. 200. 300. 400. *C