Post on 01-Feb-2022
Bioreactor Landfills:Theory and Practice
A Training Course Presented at the MPCA Air, Water and Waste
Conference, 2003February 25
Objective
• Provide overview of bioreactor landfills and their potential use as part of integrated solid waste management systems
Outline
I. Definitions and overviewII. What makes a bioreactor?III. Rules and regulationsIV. Leachate recirculationV. Impact on leachate quality
Outline
VI. Impact on gas productionVII.Operation and monitoringVIII.Other IssuesIX. ClosureX. Summary
About Instructor
• Associate ProfessorDept of Environmental Engineering SciencesUniversity of FloridaGainesville, Florida ttown@ufl.edu
Bioreactor Landfill Research
Polk County
Alachua County
New River Regional Landfill
Alachua County Southwest Landfill
New River Regional Landfill
Installing a well.
• Horizontal injection line installationExcavating:
Polk County NCLF
I. Definitions and Overview
Bioreactor Landfill Defined“……a sanitary landfill operated for the
purpose of transforming and stabilizing the readily and moderately decomposable organic waste constituents within five to ten years following closure by purposeful control to enhance microbiological processes. The bioreactor landfill significantly increases the extent of waste decomposition, conversion rates and process effectiveness over what would otherwise occur within the landfill.”
Motivation for Bioreactors
• Despite advances made in recycling, landfills are not going away
• Let’s look at example for Florida
1990 1991 1992 1993 1994 1995 WTE
Recycle
Landfill0
2
4
6
8
10
12
14
16
Tons
MSW
Man
aged
(In
Mill
ions
)Florida MSW Management
1990 1991 1992 1993 1994 1995 1996 1997 1998
WTE
Recycle
Landfill0
2
4
6
8
10
12
14
16
Tons
MSW
Man
aged
(In
Mill
ions
)Florida MSW Management
Motivation for Bioreactors
• If landfills are going to continue to be a major method of managing MSW, how do we operate these landfills better and smarter, with less long term consequences?
Benefits of a Bioreactor
• Rapid decomposition results in additional disposal capacity
Benefits of a Bioreactor
• Rapid decomposition results in additional disposal capacity
• Opportunities for liquids management
Benefits of a Bioreactor
• Rapid decomposition results in additional disposal capacity
• Opportunities for liquids management• Gas recovery is optimized
Benefits of a Bioreactor
• Rapid decomposition results in additional disposal capacity
• Opportunities for liquids management• Gas recovery is optimized• Decrease in active life of landfill may result
in dramatic savings in long-term care
Benefits of a Bioreactor
• Rapid decomposition results in additional disposal capacity
• Opportunities for liquids management• Gas recovery is optimized• Decrease in active life of landfill may result
in dramatic savings in long-term care• Better for the environment
Word of Caution
• If designed or operated poorly, a bioreactor can pose a greater risk to the environment.
Challenges
• Head on Liner• Control of Seeps• Gas Collection• Side Slope Stability• Ease of Construction; Interference with
Operations• Proper Design Procedures
Note
• What is the difference between a bioreactor and leachate recirculation?
II. What Makes a Bioreactor?
Municipal Solid Waste
• MSW contains a relatively large fraction of items that are “biodegradable”– Paper and other paper products– Food waste– Yard trash?– Slowly degradable materials
Municipal Solid Waste in United States1997: Total Weight Generated = 209.7 million
tons
Paper/Paperboard
Glass
Yard Trash
Wood
Food Waste
Metals
Plastics
Misc
9.4%
10.4%
9.9%
7.7%
Source: EPA
38.1%
13.4%5.9%5.2%
Waste Decomposition in Landfills
• Anaerobic bacteria use the biodegradable organic matter in a landfill as “food.”
• Several distinct groups of organisms act to convert large organic compounds (e.g. fats, proteins, starches) to methane and carbon dioxide
Let’s call them Bugs
Anaerobic Digestion(simplified)
Hydrolyzing Bacteria
Acidogenic Bacteria
Acetogenic Bacteria
Methanogenic Bacteria
Anaerobic Decomposition
→+ OHOHC 25106 24 33 COCH +
Creating the Right Conditions
• In a landfill bioreactor, microorganisms that degrade the waste are provided with conditions where their growth thrives.
• How do we provide the conditions that the “bugs” need?
Creating the Right Conditions
• Increase the moisture content• How?
– Recirculate the leachate– Add water– Add other liquid streams?
• Note: It is not just getting it wet, but the movement of water
Creating the Right Conditions
• Other factors– Temperature– Nutrients– pH– Bugs?
III. Rules and Regulations
Subtitle D
• The RCRA Subtitle D regulations govern the siting, design and operation of municipal solid waste landfills.
• Subtitle D promotes the operation of dry landfills
• There is specific language regarding leachate recirculation
§ 258.28 Liquids restrictions. (a) Bulk or noncontainerized liquid waste may not be
placed in MSWLF units unless: • (1) The waste is household waste other than
septic waste; • (2) The waste is leachate or gas condensate
derived from the MSWLF unit and the MSWLF unit, whether it is a new or existing MSWLF, or lateral expansion, is designed with a composite liner and leachate collection system as described in § 258.40(a)(2) of this part. The owner or operator must place the demonstration in the operating record and notify the State Director that it has been placed in the operating record; or
• (3) The MSWLF unit is a Project XL MSWLF and meets the applicable requirements of § 258.41.
Landfill Gas Issues
• New landfill gas rules specifically address bioreactors
State Rules
• States may have specific rules• Need to get a permit• What are greatest hurdles that have to be
overcome?
IV. Leachate Recirculation
Leachate Recirculation
• Leachate recirculation, sometimes known as leachate recycle.
• Several different methods can be used.• The choice of method depends on several
factors:– When you are constructing– Infrastructure at site– Degree of operator involvement desired– Design and regulatory constraints
Leachate Recirculation Methods
• Wetting working face• Surface ponds• Horizontal trenches
– Surface trenches– Buried trenches
• Vertical well– Large diameter– Small diameter
Wetting of the Working Face
Wetting the Working Face
• Advantages– Good potential for thorough moisture
distribution– Easy
• Disadvantages– Working conditions– Limiting in wet weather– Concerns over worker exposure
Infiltration Ponds
Surface Infiltration Ponds
• Advantages– Relatively easy– Good distribution underneath pond
• Disadvantages– Limited area– Floating garbage– Stormwater issues
Horizontal Trenches
Horizontal Trenches
• The most popular method currently• Two approaches:
– Buried trenches within the waste; Can be operated under pressure.
– Trenches on the surface of the landfill; Gravity infiltration only.
Buried Trench
Cover or Cap
Waste
Leachate Collection System
Surface Trench
Cover or Cap
Waste
Leachate Collection System
Construction Materials
• HDPE pipe is preferred
• PVC has been successfully used, however
Drainage Media
• Rock/gravel• Shredded tires• Other?• None?
Horizontal Trenches at ACSWL
Horizontal Injection Leachate Recycle at ACSWL
• A total of 16 injection lines were constructed from 1992 through 1994.
• Leachate recycle began in 1993.
• From February 1993 through August 1994, a total of 7,900,000 gallons of leachate were recycled to the landfill by horizontal injection.
Horizontal Trenches at Polk County NCLF
NCLF Phase II
• Leachate injection lines are installed in the waste as the landfill is filled up.
Digging
First Two Injection Lines
Surveying – “As-Built”
Shredded Tires
Placing First Line in Trench
Hands-on Training
Filling in Trench
Vertical Injection Wells
• Two major types– Large diameter wells– Small diameter wells
• Many of the early leachate recirculation attempts used large diameter wells
• Most new designs use small diameter wells
Why Use Vertical Wells?
• Can be applied to retrofit landfills, i.e., those landfills that have already been filled but still want to recirculate leachate
• Minimizes the involvement of the landfill operations crew. Allows for the entire system to be installed by an outside contractor.
Large DiameterVertical LeachateInjection Well
Potential Disadvantage of Vertical Wells
• The greatest hydraulic pressure will be at the bottom of the well
• This might result in more leachate distribution on the bottom of the landfill
• Potential method to address this: cluster wells
Top of Landfill
Top of Sand DrainageBlanket
10 ft
Vertical Injection Cluster Wells
Methods of Installation
• Auger drill rig• Push technology
Drill rig sets up and begins drilling. First well cluster: CN2.
Installing a well.
Additional pipe sections were threaded into place as the pipe was pushed into the hole. For the most part, all wells were able to be installed to the drilled hole depth.
The landfilled waste tended to expand around the pipe shortly after placement. A bentonite plug was placed in the annulus between the pipe and the waste.
The thermocouple leads were placed within the pipe and a cap was placed on the pipe. This is temporary condition.
Catch of the day – a mattress (with one of the drillers). Auger bits were changed while drilling resumed.
Injection Well Cluster
Injection Well Cluster
Compacting Soil around Injection Wells
Wells Under Liner
Location of Injection Well Under GeomembraneGeomembrane will later be cut and a boot will be installed
Solid Wasteand Daily
Cover
Soil
2-inch PVC injection wells TemporaryCaps
Thermocouple Wire
Process of Constructing EGC
over Injection Wells
VFPE Geomembrane Placed on Surface of Landfill
Process of Constructing EGC
over Injection Wells
Geomembrane Cut Around Wells
Process of Constructing EGC
over Injection Wells
Geomembrane Cut Around Wells
Process of Constructing EGC
over Injection Wells
Extrusion Weld Boots
Process of Constructing EGC
over Injection Wells
As soon as geomembraneis pulled over wells, locationis marked.
At a later time, the geomembrane is cut aroundwell.
Temporary Well Boots
Temporary Well Boots
Temporary Well Boots after Well Extension
Permanent Well Expansion Boots
Construction of Expansion Boot: 1 Note: Geomembrane used
for boot is illustratedin red for clarity.
Note: Boots are prefabricatedon site.Geomembrane Collar Around Well
Construction of Expansion Boot: 2 Note: Geomembrane used
for boot is illustratedin red for clarity.
Note: Boots are prefabricatedon site.
Boot Base Sheet
Extrusion Weld
Construction of Expansion Boot:3 Note: Geomembrane used
for boot is illustratedin red for clarity.
Note: Boots are prefabricatedon site.
Note: Boot Collar is Shownslightly expanded for clarity.
Boot Bellows
Extrusion Weld
Construction of Expansion Boot: 4 Note: Geomembrane used
for boot is illustratedin red for clarity.
Note: Boots are prefabricatedon site.
Note: Boot Collar is Shownslightly expanded for clarity.
Neoprene Gasket
Clamp
How Does Expansion Boot Work?
Initial Condition
How Does Expansion Boot Work?
Landfill Settles
How Does Expansion Boot Work?
Adjust Collar
Where Does the Leachate Go?
• While we can design and systems to recirculate leachate, we are not quite as sure where the water in the landfill goes.
• Several methods have been used to predict the distribution of leachate
Ymax
Xmax
x
y
Boundary ofSaturated
Zone
Xwell
InjectionWell
Flow System for Horizontal Injection Well
y = - infinity
maxY = q2 k kx yπ
maxX = q2 k y
qwell
yX =
4 k
Equations for a Saturated Zone Surrounding a Horizontal Injection Well
x = q2 k
[ xy
kk
]y
-1 y
xπtan
Effect of Anisotropy on Saturated ZoneSurrounding Horizontal Injection Well
InjectionWell
kk
x
y
=
kk
x
y
=
kk
x
y
=
kk
x
y
=
1
5
2
20
Numerical Modeling
• A saturated/unsaturated numerical model was developed by McCreanor
• Looked at many different scenarios
Landfill Heterogeneities
• The presence of cover soil and the natural heterogeneity of compacted MSW will result in deviations from ideal scenarios
Cover Problems
-8 -6 -4 -2 0 2 4 6 8Horizontal Co-ordinate, m
0
2
4
6
8
10
12
14
Waste
Heigh
t, m
DailyMaterialCover
How Much Water You Add?
• Need to get waste to at least field capacity.
• How do you now much of the waste is at field capacity?
V. Impact on Leachate Quality
Impact on Leachate
• Early research found that leachate recirculation had a positive impact on leachate quality
• The was primarily observed with a reduction in organic strength of the leachate (e.g. BOD, COD)
• High organic strength is a result of the acids produced by the bugs in the decomposition process
Leachate Strength
0
5
10
15
20
25
30
35
Chem
ical O
xygen
Demand
, mg/L
Thousa
nds
1983198519861987198819891990199119921993Year
Closure
Note
• There may be a time when you will see the leachate strength increase
Impact on Other Parameters
• Some parameters will tend to increase over time– Salts– Ammonia
Impact of Other Parameters
• Organic compounds and trace metals– Both of these are relatively low in leachate
regardless• Most organic trace compounds should be
biodegraded over time by organisms in the landfill
• Many heavy metals will be reduced in the anaerobic environment of the landfill
Question
• Can you recirculate leachate forever?
• Do you need other forms of leachate management?
VI. Impact on Gas Production
Gas Production
• An end product of rapid waste decomposition is gas production
• The total amount of gas produced from the landfill should be the same, but the time during which it is produced is condensed
Anaerobic Decomposition
→+ OHOHC 25106 24 33 COCH +
Year
0
5,000,000
10,000,000
15,000,000
20,000,000
25,000,000 C
ubic
met
ers
LFG
0 10 20 30 40 50
LFG Generation Curves
Half-Life = 1.35 yr
Half-Life = 3.68 yr
Half-Life = 20 yr
Gas Collection from a Bioreactor
• Because of the large amount of gas produced from a bioreactor and the wet nature of the waste, gas collection is a challenge.
• When do you collect?
• How do you collect?
When to Collect?
• It is not really a bioreactor if you are not collecting and managing the gas. TT
• Do you wait until the landfill is closed to start collecting the gas?
• How do you collect the gas as you go?
LFG Collection From Operating Landfills
HorizontalCollectors
Sub-Cap Collector
Leachate Collection System - LFG Collector Network
o
o
o
o
o
oo
0
5
10
15
20
25
30
-0.40 -0.30 -0.20 -0.10 0.00 0.10 0.20 0.30 0.40
Pressure (m water column)
Land
fill E
leva
tion
(m)
Pressure Distribution within a Landfill
VII. Operation and Monitoring
Operations
• It is important to have a good operations plan and a trained set of operators
• The systems can be the best designed in the world, but if it is not operated correctly, trouble can happen
Operations
• Think of the bioreactor as being a treatment system like a wastewater treatment plant; it needs an operator
Operations
• Operating the system– How much?– Where?– How long?
• Monitoring and inspecting• Recording information
Monitoring the Bioreactor
• Leachate production and quality• Gas production and quality• Landfill settlement• Waste quality• In-situ instrumentation
– Moisture sensors– Temperature
Leachate
Leachate Meter Manholes
pH
5.5
6
6.5
7
7.5
8
pH
Manhole
TDS
0
2000
4000
6000
8000
10000
12000
14000
MH-1 MH-2 MH-3 MH-4 MH-5 MH-6 MH-7 MH-8 MH-9
Manhole
TD
S (m
g/l)
Typical Temperature Profile
0
10
20
30
40
50
60
70
0 10 20 30 40 50 60
Dep
th fr
om th
e to
p su
rface
(ft)
5/11/01 12/18/01 4/4/02 6/25/02 7/22/02 8/13/02 10/1/02 11/18/02
Temperature ( C)
In addition to leachate/air injection wells, the researchers will also be installing instrumentation within the landfill to measure Moisture, Temperature and Gas composition. Future updates will discuss the operation of these MTGsensors in more detail. In short, these gravel-packed slotted PVC cylinders contain a device for sensing the degree of moisture present, as well as a temperature thermocouple and a tube for collecting gas samples.
-4-202468101214161820222426283032343638404244464850High Resistivity
(Low Moisture)
Low Resistivity(High Moisture)
Surface ofBioreactor
20 feet deep
60 feet deep
40 feet deep
Resistivity distribution inside NRRL Bioreactor, 12/18/02
High Temperature (degree C)
Low Temperature(degree C)
Surface ofBioreactor
20 feet deep
60 feet deep
40 feet deep
Temperature distribution inside NRRL Bioreactor, 12/18/02
25
30
35
40
45
50
55
60
65
BMP results
Methane Yield (L / g VS added)
0~0.05 0.05~0.10 0.10~0.15 0.15~0.20 0.20~0.25 0.25~0.30 0.30~0.35
Num
ber o
f sam
ples
0
2
4
6
8
10
12
14
16
VIII. Other Issues
Landfill Settlement
• Bioreactor landfills will settle more rapidly; the design must accomodate
Slope Stability
• The presence of “ponded” water within the landfill can reduce the “strength” of the waste (or the strength at the interface of waste and other materials)
• This can possible result in slope failures
Addition of Other Liquids
Aerobic Bioreactors
Aerobic Decomposition
→+ 25106 6OOHC OHCO 22 56 +
Aerobic Bioreactors
• Offers potential for very rapid degradation.• May degrade some components that are
otherwise recalcitrant under anaerobic conditions.
Aerobic Bioreactor
• Rapid stabilization of waste• Enhanced settlement• Evaporation of moisture• Degradation of organics which are
recalcitrant under anaerobic conditions• Reduction of methane emissions
Aerobic Bioreactor - Issues and Concerns
• Potential for waste combustion• Nature of air emissions• Cost• Technological feasibility in deep landfill• Waste density effects• Efficiency of air distribution
Types
• Aerobic
• Semi-aerobic
Aerobic Landfill
Permanent Well Expansion Boots
02468
10121416182022
0 5 10 15 20 25% Methane
% O
xyge
nMixtures that can
not be formed
ExplosiveRange
Not capable offorming flammablemixtures with air
Capable of forming flammablemixtures with air (contains too
much methane to be in explosive range)
Recovery of Composted Materials
IX. Closure
Closure
• When are you able to close the landfill?– 30 years?
• Can you close early if you are bioreactor?
X. Summary